| Round 1 | | Ajax | 1 | 87 Sulejmani | | Half-time: | 0-1 | | Referee: | D'Urso 7½ | | Attendance: | 42,973 | | Possession: | 51%-49% | | Total shots: | 17-14 | | MoM: | Jouffre | | TV: | highlights |
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| | (4-3-3): Vermeer 6½, Oleguer 7, Atouba 6½, Sulejmani 7, Dainelli 7½, Wielaert 6, Sam 7, Emanuelson 6½, Matavz 7, Floccari 6, De Jong 6 | | Lorient | 1 | 39 Sagbo | | 40 Sagbo, 51 Mignot | | (4-3-3): Audard 7½, Congré 7, Morel 7½, Mvuemba 7, Marchal 7½, Mignot 6, Balmont 7 (58 Jouffre 8), Birsa 6½, Hoarau 6½, Amalfitano 6, Sagbo 5½ | | Bayer Leverkusen | 2 | 16 Piszczek, 90 Kadlec | | Half-time: | 1-1 | | Referee: | McCluskey 6½ | | Attendance: | 22,363 | | Possession: | 46%-54% | | Total shots: | 14-15 | | MoM: | Cahill | | TV: | live |
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| | (4-3-3): Wiese 6½, Piszczek 7, Kadlec 6½, Cambiasso 7½, Friedrich 7, Servet 6, Fritz 7, Arango 7, Kuranyi 6, Rakitic 6½, Kakuta 6 | | Celtic | 1 | 24 McGeady | | 3 Mlapa | | (4-3-3): Boruc 7½, Cherundolo 6½, José Ángel 7½, Cahill 7½, Katsouranis 7, Kolodin 6, Brown 7½, McGeady 7, Cissé 6½, Cissé 5½, Mlapa 6½ | | Cruz Azul | 5 | 10og Hunt, 19 Pereira, 24 Robben, 52 Robben, 74 Pereira | | Half-time: | 3-0 | | Referee: | Pinto Correia 7½ | | Attendance: | 35,895 | | Possession: | 62%-38% | | Total shots: | 18-12 | | MoM: | Robben |
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| | (4-3-3): Corona 6, João Pereira 7, Pereira 8, Fellaini 8, Jagielka 7, Samuel 7, De Marcos 7, Robben 8½, Jelavic 7, Di Natale 6, Suárez 7 | | SV Werder Bremen | 0 |
| | 4 Dost, 35 Hunt, 68 Adebayor | | (4-3-3): Gabulov 6½, Prödl 5½, Abdennour 7½, Bargfrede 5½, Pasanen 6½, Hunt 6½, Oar 5½, Diego Capel 6, Adebayor 6½, Niemeyer 6, Dost 6 | | Internacional | 3 | 6 Wágner, 10 Fred, 39 Fred | | Half-time: | 3-1 | | Referee: | Marriner 6½ | | Attendance: | 46,586 | | Possession: | 53%-47% | | Total shots: | 8-11 | | MoM: | Hilton |
| | 3 Jô | | (4-3-3): Rafael 6, Marcelo 7, Kléber 7, Sandro 5½ (56 Taison 7½), Hilton 8, Mariano 7, Ciro 7½, Wágner 7½, Fred 7, Giuliano 6½, Jô 6½ | | Palmeiras | 2 | 36 Lucas, 88 Higuaín | | 47 Edinho, 55 Higuaín | | (4-3-3): Júlio César 5½, Figueroa 6, Armero 7½, Lucas 7, Danilo 6, Edinho 6½, Diego Souza 6, Renato 6, Higuaín 7, Pierre 7, Ronaldinho 7 | | Juventus | 0 |
| | Half-time: | 0-0 | | Referee: | Beschin 5 | | Attendance: | 27,985 | | Possession: | 54%-46% | | Total shots: | 19-3 | | MoM: | Iaquinta |
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| | (4-3-3): Manninger 7, Corluka 7, De Ceglie 6½, Afellay 7½, Mertesacker 6½, Bassong 6½, Camoranesi 7 (54 Iaquinta 8), Candreva 7, Berg 6, Felipe Melo 6½, Nenê 6½ | | Aston Villa | 0 |
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| | (4-3-3): Guzan 8, Cuéllar 7½, Shorey 7, Sidwell 6½, Dunne 6½, Collins 6½, Milner 7½, Bannan 5½, Carew 6½, Cirigliano 6, Agbonlahor 6½ (64 Bouma 6) | | Napoli | 1 | 50 Quagliarella | | Half-time: | 0-0 | | Referee: | Sandra 7½ | | Attendance: | 48,467 | | Possession: | 48%-52% | | Total shots: | 8-16 | | MoM: | Campagnaro | | TV: | highlights |
| | 9 Keita, 46 Zaccardo | | (4-3-3): De Sanctis 7½, Campagnaro 8, Moretti 6½, Gargano 6½, Ranocchia 6½, Cannavaro 6½, Necip 7, Keita 6½, Zaccardo 6, Pazienza 6½, Quagliarella 6 | | Atlético Madrid | 0 |
| | 68 Johnson | | (4-3-3): Sergio Asenjo 7½, Johnson 7, Ismail 8, Biglia 7, Rodríguez 7 (56 Rodrigo 7), Marc Muniesa 6, Kuba 7½, Reyes 6½, Borja 6½, Lanzini 7½, Bojan 6 | | Sevilla | 1 | 19 Kiessling | | Half-time: | 1-1 | | Referee: | Waddel 6 | | Attendance: | 40,564 | | Possession: | 48%-52% | | Total shots: | 12-12 | | MoM: | Gobbi |
| | 62 Silvestre, 80 Fernando Navarro | | (4-3-3): Palop 7, Alexis 7, Fernando Navarro 6, Raul Meireles 7½, Naldo 7, Silvestre 6½, Navas 8, Makoun 6½ (71 Friedrich 6), Kiessling 7, Negredo 7, Kiko 7 | | Fiorentina | 1 | 36 Gobbi |
| | (4-3-3): Forster 6½, De Silvestri 6½, Gobbi 8, Montolivo 8, Felipe 7½, Camporese 6, Ljajic 6, Marchionni 6, Gilardino 7½, Altidore 6, Mutu 7 | | Spartak | 2 | 2 Prudnikov, 49 Semshov | | Half-time: | 1-0 | | Referee: | Braschi 6½ | | Attendance: | 43,928 | | Possession: | 51%-49% | | Total shots: | 11-10 | | MoM: | Anyukov |
| | 72 Zhirkov | | (4-3-3): Shunin 7½, Anyukov 8½, Yanbaev 7, Semshov 7, Suchý 6½, Berezutsky 7, Bazhenov 7, Dzagoev 6 (63 Torbinsky 7½), Prudnikov 6½, Zhirkov 6, Arshavin 6½ | | Zenit | 0 |
| | 70 Huszti | | (4-3-3): Gordon 7½, Matthews 7, Lombaerts 7, Guilherme 7, Fernando Meira 6, Krizanac 6½, Fayzulin 6½, Danny 7½, Kornilenko 7, Huszti 5½, Lazovic 7 | | TSG Hoffenheim | 1 | 36 Salihovic | | Half-time: | 1-1 | | Referee: | Bazzoli 8 | | Attendance: | 30,139 | | Possession: | 48%-52% | | Total shots: | 14-10 | | MoM: | Mangane |
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| | (4-3-3): Consigli 6½, Ebondo 7½, Luis Gustavo 7½, Mangane 8, Ruíz 7, Vorsah 6½, Vukcevic 7, Salihovic 7½, Ba 7, Ibisevic 6½, Sessègnon 6 | | River Plate | 1 | 13 Castillejos | | 70 Buonanotte | | (4-3-3): Marchesín 7, Ferrari 7, Orban 7½, Buonanotte 7, Cabral 7, Ferrero 6½, Mouche 7½, Rosický 7½, Víctor 7, Castillejos 6, Amrabat 5½ | | VfB Stuttgart | 2 | 2 Lewandowski, 33 Boka | | Half-time: | 2-0 | | Referee: | Korac 7 | | Attendance: | 43,553 | | Possession: | 49%-51% | | Total shots: | 13-9 | | MoM: | Seedorf |
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| | (4-3-3): Ulreich 7½, Hamit 7, Boka 7½, Kehl 7½, Osorio 7½, Niedermeier 6½, Lanig 6½, Aquilani 6½, Lewandowski 7, Orbáiz 7½, Cacau 6½ | | Milan | 0 |
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| | (4-3-3): Given 7½, Ujfalusi 7, Bocchetti 7½, Seedorf 8, Onyewu 7, Kolarov 6½, Joaquín 6, Ambrosini 6, Bendtner 7, Ireland 5½, Adiyiah 5½ | | Villarreal | 2 | 71 Eboué, 86 Stevanovic | | Half-time: | 0-2 | | Referee: | Vink 8 | | Attendance: | 22,933 | | Possession: | 42%-58% | | Total shots: | 12-20 | | MoM: | Dawson | | TV: | highlights |
| | 23 Forlán, 53 Sigurðsson | | (4-3-3): Schwarzer 5½, Eboué 6, Juan 7, Barry 7½, Dawson 7½, Marcellis 6, Gómez 6½, Stevanovic 6½, Derdiyok 6 (84 Campaña 6), Sigurðsson 7, Forlán 6 | | Hamburger SV | 3 | 25 Aogo, 41 Jansen, 54 Mathijsen |
| | (4-3-3): Turina 6, Demel 7, Aogo 7, Rincón 7½, Mathijsen 7, Rozehnal 7 (71 Jarolim 6½), Behrami 7, Jansen 6½, Pavlyuchenko 7, Guerrero 5½, Petric 6 | | Round 2 | | Aston Villa | 2 | 42 Agbonlahor, 58 Bannan | | Half-time: | 1-0 | | Referee: | Colic 6½ | | Attendance: | 42,114 | | Possession: | 48%-52% | | Total shots: | 12-11 | | MoM: | Sandro |
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| | (4-3-3): Guzan 7, Cuéllar 7½, Shorey 7, Sidwell 7, Dunne 7½, Collins 6½, Milner 7, Bannan 6½, Carew 6, Cirigliano 7, Agbonlahor 5½ | | Internacional | 1 | 51 Jô |
| | (4-3-3): Rafael 7½, Marcelo 7, Kléber 8, Sandro 8, Hilton 7, André Bahia 6½, Ciro 7, Wágner 7, Fred 7, Giuliano 6, Jô 6 | | Atlético Madrid | 1 | 70 Bojan | | Half-time: | 0-0 | | Referee: | Franceschini 7½ | | Attendance: | 37,218 | | Possession: | 55%-45% | | Total shots: | 14-15 | | MoM: | Schwarzer |
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| | (4-3-3): Sergio Asenjo 8½, Johnson 7, Ismail 7½, Biglia 8, Rodríguez 6½, Marc Muniesa 6½, Kuba 7, Reyes 6½ (68 Rochina 7), Borja 6, Lanzini 6½ (68 Camacho 6½), Bojan 6½ | | Villarreal | 0 |
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| | (4-3-3): Schwarzer 8½, Eboué 7, Juan 7, Barry 7½, Dawson 7½, Marcellis 6, Gómez 7, Stevanovic 6½, Derdiyok 7 (84 Campaña 6), Sigurðsson 6½, Forlán 6 | | Celtic | 3 | 4 Brown, 45+1 Cissé, 52 Cissé | | Half-time: | 2-1 | | Referee: | Heynemann 5 | | Attendance: | 45,649 | | Possession: | 44%-56% | | Total shots: | 12-12 | | MoM: | Anyukov |
| | 59 Mlapa, 76 José Ángel | | (4-3-3): Boruc 6½, Cherundolo 7½, José Ángel 7, Cahill 7, Katsouranis 6½, Kolodin 6, Brown 7, McGeady 7, Cissé 7, Cissé 5½ (49 Rogne 6½), Mlapa 6 | | Spartak | 1 | 44 Anyukov | | 48 Bazhenov, 55 Shunin | | (4-3-3): Shunin 6½, Anyukov 8, Yanbaev 8, Semshov 7, Suchý 6½, Berezutsky 6, Bazhenov 7, Dzagoev 7½, Prudnikov 6½, Zhirkov 5½, Arshavin 6 | | Fiorentina | 1 | 3 Montolivo | | Half-time: | 1-1 | | Referee: | Kefalas 6 | | Attendance: | 38,278 | | Possession: | 44%-56% | | Total shots: | 9-21 | | MoM: | Gobbi |
| | 56 Marchionni | | (4-3-3): Forster 7, De Silvestri 7, Gobbi 7½, Montolivo 6½, Felipe 7, Camporese 6½, Ljajic 6½, Marchionni 6, Gilardino 7½, Altidore 5½, Mutu 6 | | Bayer Leverkusen | 1 | 12 Kadlec | | 41 Servet | | (4-3-3): Wiese 7½, Piszczek 7½, Kadlec 7, Cambiasso 7, Friedrich 7, Servet 6½, Fritz 6½, Arango 7½, Kuranyi 7½, Rakitic 7, Kakuta 5½ | | Hamburger SV | 3 | 4 Behrami, 17 Aogo, 78 Petric | | Half-time: | 2-0 | | Referee: | Villarreal 5½ | | Attendance: | 46,044 | | Possession: | 50%-50% | | Total shots: | 12-7 | | MoM: | Mathijsen |
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| | (4-3-3): Turina 7, Demel 7, Aogo 7, Rincón 7, Mathijsen 8, Rozehnal 5½ (71 Jarolim 5½), Behrami 7½, Jansen 7½, Pavlyuchenko 6½, Guerrero 6, Petric 7 | | Napoli | 0 |
| | 32 Zaccardo | | (4-3-3): De Sanctis 6½, Campagnaro 7, Moretti 6½, Gargano 6, Ranocchia 7, Cannavaro 5½, Necip 6½, Keita 6½, Zaccardo 6, Pazienza 6½, Quagliarella 6½ (59 Maiello 7) | | Lorient | 2 | 2 Hoarau, 8 Balmont | | Half-time: | 2-1 | | Referee: | Jol 7½ | | Attendance: | 15,819 | | Possession: | 45%-55% | | Total shots: | 12-13 | | MoM: | Mertesacker |
| | 47 Congré | | (4-3-3): Audard 6½, Congré 6, Morel 7, Mvuemba 7½, Marchal 7½, Mignot 6, Balmont 6 (58 Jouffre 7), Birsa 6½, Hoarau 7, Amalfitano 5½, Sagbo 6 | | Juventus | 2 | 25 Felipe Melo, 65 Mertesacker |
| | (4-3-3): Manninger 6, Corluka 7, De Ceglie 7½, Afellay 7½, Mertesacker 8, Bassong 6, Camoranesi 7 (66 Iaquinta 6), Candreva 7½, Berg 7, Felipe Melo 6, Nenê 6½ | | Milan | 0 |
| | Half-time: | 0-0 | | Referee: | Vassaras 5½ | | Attendance: | 33,800 | | Possession: | 46%-54% | | Total shots: | 5-11 | | MoM: | Ruíz |
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| | (4-3-3): Given 7, Ujfalusi 7, Bocchetti 7½, Seedorf 7½, Onyewu 6½, Kolarov 7½, Joaquín 7, Ambrosini 6½, Bendtner 7, Ireland 5½, Adiyiah 5½ | | TSG Hoffenheim | 2 | 64 Luis Gustavo, 80og Seedorf | | 12 Salihovic, 15 Ebondo, 66 Mangane, 75 Sessègnon | | (4-3-3): Consigli 6½, Ebondo 8, Luis Gustavo 7½, Mangane 7½, Ruíz 8, Vorsah 6½, Vukcevic 6½, Salihovic 7½, Ba 6½, Ibisevic 7, Sessègnon 5½ | | Palmeiras | 2 | 47 Higuaín, 78 Diego Souza | | Half-time: | 0-1 | | Referee: | Khussainov 8 | | Attendance: | 28,436 | | Possession: | 47%-53% | | Total shots: | 7-12 | | MoM: | Jagielka |
| | 29 Higuaín | | (4-3-3): Júlio César 6½, Figueroa 6, Armero 7, Lucas 7, Danilo 7, Rafael Toloi 6½, Edinho 6, Renato 6½, Higuaín 6½, Diego Souza 7, Ronaldinho 7½ | | Cruz Azul | 1 | 7 Robben | | 16 Di Natale | | (4-3-3): Corona 7, João Pereira 8, Pereira 7½, Fellaini 7½, Jagielka 8, Samuel 6, De Marcos 7, Robben 7, Jelavic 6½, Di Natale 6½ (78 Suso 6), Suárez 6½ | | River Plate | 1 | 55 Orban | | Half-time: | 0-0 | | Referee: | Constantin 7 | | Attendance: | 37,810 | | Possession: | 51%-49% | | Total shots: | 12-23 | | MoM: | Buonanotte |
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| | (4-3-3): Marchesín 7, Ferrari 7½, Orban 7, Buonanotte 8, Cabral 6½, Ferrero 6½, Mouche 6½, Rosický 6½, Víctor 7½, Castillejos 6, Amrabat 6½ | | Ajax | 1 | 57 Matavz |
| | (4-3-3): Vermeer 7, Oleguer 7, Atouba 7, Sulejmani 7, Dainelli 7, Wielaert 6, Sam 6½, Emanuelson 6½, Matavz 6½, Floccari 6, De Jong 6 | | SV Werder Bremen | 1 | 49 Dost | | Half-time: | 0-1 | | Referee: | Circhetta 8 | | Attendance: | 42,487 | | Possession: | 47%-53% | | Total shots: | 11-11 | | MoM: | Ulreich |
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| | (4-3-3): Gabulov 7, Prödl 6, Abdennour 6½, Hunt 7, Pasanen 7, Bargfrede 6, Oar 6, Diego Capel 6, Dost 6½, Niemeyer 7, Adebayor 7 | | VfB Stuttgart | 1 | 35 Hamit |
| | (4-3-3): Ulreich 7½, Hamit 7½, Boka 7, Kehl 7½, Osorio 7, Niedermeier 7, Lanig 7½, Aquilani 6, Lewandowski 7, Orbáiz 6½, Cacau 6 | | Zenit | 2 | 88 Lombaerts, 90+2 Kornilenko | | Half-time: | 0-2 | | Referee: | Coué 6½ | | Attendance: | 21,861 | | Possession: | 51%-49% | | Total shots: | 8-10 | | MoM: | Fayzulin |
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| | (4-3-3): Gordon 6, Matthews 6½, Lombaerts 6½, Guilherme 7, Fernando Meira 7½, Krizanac 7, Fayzulin 7½, Danny 7, Kornilenko 7, Huszti 5½, Lazovic 6½ | | Sevilla | 3 | 12 Fernando Navarro, 43 Fernando Navarro, 90+1 Naldo | | 7 Alexis, 13 Kiessling, 21 Navas, 48 Makoun, 57 Silvestre, 58 Makoun | | (4-3-3): Palop 6½, Alexis 6½, Fernando Navarro 7½, Raul Meireles 7½, Naldo 7, Silvestre 6½ (70 Fernández 6), Navas 6½, Makoun 6½, Kiessling 6½, Negredo 6, Kiko 6 |
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