| Round 1 | | Arsenal | 0 |
| | Half-time: | 0-1 | | Referee: | Penicka 7 | | Attendance: | 46,356 | | Possession: | 48%-52% | | Total shots: | 10-14 | | MoM: | Van Damme | | TV: | live |
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| | (4-3-3): Mannone 6, Sagna 7, Clichy 7 (58 Abidal 7½), Tiago 7½, Vermaelen 7, Papastathopoulos 5, Feghouli 8, Senkerík 7½, Djourou 6, Pjanic 6½, Fran Mérida 5½ | | Rangers | 3 | 27 Van Damme, 69 Son, 89 Son |
| | (4-3-3): McGregor 6, Hutton 7, Van Damme 8½, Davis 8, Bougherra 7, Wilson 6, Morrison 7, Naismith 6½, Son 7, Oriol Romeu 6½ (77 McCulloch 6), McFadden 6 | | Ayr United | 1 | 75 Brahimi | | Half-time: | 0-2 | | Referee: | Reijgwart 6½ | | Attendance: | 10,145 | | Possession: | 31%-69% | | Total shots: | 6-18 | | MoM: | Shirokov |
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| | (4-3-3): Smith 6½, Darmian 7, McCann 7, Marrone 7½, Robertson 6½, Twaddle 6, Mak 6½, Brahimi 6½, Weimann 6½, McStay 6, Winters 5½ | | Rosenborg | 2 | 5 Toprak, 11 Prica |
| | (4-3-3): Begovic 6½, Smalling 7½, Mathieu 7½, Shirokov 8, Toprak 7, Nilsson 8, Skjelbred 7½, Holm 7½, Prica 7½, Chantôme 7½, Floro Flores 7½ | | Bursaspor | 2 | 3 Chrétien, 48 Ibrahim | | Half-time: | 1-0 | | Referee: | Foy 5½ | | Attendance: | 18,475 | | Possession: | 63%-37% | | Total shots: | 18-13 | | MoM: | Batalla |
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| | (4-3-3): Carson 7½, Chrétien 6½, André Santos 6½, Batalla 8, Ibrahim 8, Ömer 6½, Ismail Haktan 7, Riera 7½, Pinto 7½, Adem 6½, Sesták 7½ | | Palermo | 0 |
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| | (4-3-3): Benussi 6½, Cassani 6½, Balzaretti 7, Meyler 7, Bovo 5½, Goian 6½ (70 Ameobi 6), Krasic 7, Bertolo 6, Hernández 6, Amauri 5½, Watt 5½ | | Club Brugge | 4 | 4 Stenman, 23 Stenman, 33 Vleminckx, 57 Hoefkens | | Half-time: | 3-0 | | Referee: | Wieser 6 | | Attendance: | 28,993 | | Possession: | 55%-45% | | Total shots: | 13-9 | | MoM: | Odjidja-Ofoe |
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| | (4-3-3): Jorgacevic 6½, Vezalov 6½, Stenman 7, Odjidja-Ofoe 8½, Hoefkens 7½, Donk 6½, Refaelov 6, Vargas 7½, Vleminckx 7, Akpala 6, Víctor Vázquez 6½ | | Chelsea | 0 |
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| | (4-3-3): Taylor 7, Rafinha 7½, Van Aanholt 7, Arteta 8, Van Buyten 7, Maza 7, Rodríguez 7½, Gattuso 6, Bridcutt 5½, Källström 6½, Borini 5½ | | Deportivo | 6 | 5 Nouioui, 8 Nouioui, 19 Guardado, 44 Diamé, 51 Juanfran, 70 Renato Silva | | Half-time: | 4-0 | | Referee: | Constantin 8 | | Attendance: | 32,418 | | Possession: | 60%-40% | | Total shots: | 27-6 | | MoM: | Diamé |
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| | (4-3-3): Guilherme 7½, Juanfran 7½, Guardado 7½, Diamé 8½, Renato Silva 8, José Castro 7½, Pablo Álvarez 7½, Juan Domínguez 4 (78 Laure 6), Nouioui 7½, Valerón 7, Adrián 7½ | | Accrington Stanley | 0 |
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| | (4-4-2): Dunbavin 7, Murphy 6½, Molyneux 7, Hatfield 6½, Aldred 7, Winnard 5½, Chippendale 6, Jeffers 6, Amond 6½, Joyce 6, Wilson 5½ | | Exeter City | 0 |
| | Half-time: | 0-2 | | Referee: | Alves Azevedo 6 | | Attendance: | 8,730 | | Possession: | 31%-69% | | Total shots: | 4-13 | | MoM: | Park |
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| | (4-4-2): Evans 5½, Tully 6½, Woodman 6½, Doherty 6½, Coles 6½, Baldwin 6½, Davies 5½, Gow 6½, Sercombe 6½, Oakley 6, Cureton 6½ | | Brřndby | 3 | 14 Ansaldi, 27 Park, 60 Park |
| | (4-3-3): Třrnes 6½, Pisano 8, Ansaldi 8½, Thygesen 8½, Stenderup 7½, Goodson 7, Labyad 6, Park 8½, Gehrt 6½ (83 Belhadj 6), Jřrgensen 8, McGrath 6½ | | Helsingborg | 2 | 21 Eriksen, 67 Abdellaoue | | Half-time: | 1-1 | | Referee: | José Pratas 7 | | Attendance: | 25,722 | | Possession: | 39%-61% | | Total shots: | 6-12 | | MoM: | Bruno |
| | 45 Giovinco | | (4-3-3): Marchetti 7, Abate 6½, Santon 6½, Olsson 7, Agger 7½, Elm 6½, Balotelli 5½, Larsson 7, Abdellaoue 7, Eriksen 6 (81 Nordtveit 6), Giovinco 6½ | | Flamengo | 1 | 45+1 Willians |
| | (4-3-3): Bruno 7½, Leo Moura 7½, Juan 7, Willians 7½, Xandăo 7, Welinton 6, Marlos 6½, Alex Teixeira 6½ (65 Marques 8), Vágner Love 7, Erick Flores 5½, Emerson 6½ | | PSV | 1 | 62 Paolucci | | Half-time: | 0-2 | | Referee: | López Nieto 6 | | Attendance: | 34,909 | | Possession: | 49%-51% | | Total shots: | 12-14 | | MoM: | Wellington |
| | 41 El Ahmadi | | (4-3-3): Wiland 6½, Manolev 6½, Molinaro 7½, Poulsen 7½, Biava 6½, Olfers 7, Vukovic 6½, El Ahmadi 6½ (80 Nilis 6), Koevermans 7½, Nijland 5½, Paolucci 6½ | | FC Twente | 2 | 32 Stoch, 45 Bony |
| | (4-3-3): Aouate 7, Levels 7 (53 Wellington 8), Givet 6, Witsel 7, Douglas 5½, Rajkovic 6½, Tioté 6½, Stoch 6½, Bony 6½, Ojo 6, Cavadov 6 | | Rubin | 2 | 45 Hasan Salih, 63 Ari | | Half-time: | 1-0 | | Referee: | Trentalange 5 | | Attendance: | 24,910 | | Possession: | 55%-45% | | Total shots: | 14-11 | | MoM: | Mehmet | | TV: | highlights |
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| | (4-3-3): Zoet 7, Kvirkvelia 7, Kuzmin 7½, Murawski 7, César Navas 6½, Salukvadze 6½, Ryazantsev 6½, Gökdeniz 7, Hasan Salih 7, Semak 7, Ari 6½ | | Fenerbahçe | 0 |
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| | (4-3-3): Onur Recep 7, Gökhan 6½, Bekir 6½, Cristian 7½, Egemen 6½, Remzi Giray 6, Mehmet 8, Cech 6½, Sow 6½, Semih 6, Burak 7 | | Sampdoria | 5 | 2 Pozzi, 18 Pozzi, 21 Mannini, 42 Pablo, 84 Pozzi | | Half-time: | 4-0 | | Referee: | Sedlacek 8 | | Attendance: | 30,787 | | Possession: | 57%-43% | | Total shots: | 20-8 | | MoM: | Tissone |
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| | (4-3-3): Castellazzi 7½, Lucchini 7½, Accardi 8, Tissone 8, Gastaldello 7, Diakité 6½, Pablo 4½ (48 Semioli 7), Mannini 8, Pozzi 8, Poli 6½, Testardi 6½ | | Newport County | 0 |
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| | (3-1-4-2): Pidgeley 6½, Porter 6½, Jolley 6, Minshull 6½, James 6, Yakubu 6, Thomson 6½, Sandell 6, O'Connor 7 (66 Crow 6½), Flynn 5½, Donnelly 6 | | Sporting | 1 | 51 Hélder Postiga | | Half-time: | 0-1 | | Referee: | Ancion 6 | | Attendance: | 41,343 | | Possession: | 53%-47% | | Total shots: | 15-21 | | MoM: | Izmailov |
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| | (4-3-3): Ricardo Batista 7, Cédric 7, Miguel Veloso 7, Daniel Carrico 7½, Edcarlos 7, Cervantes 6, Izmailov 8, Fernández 6½, Hélder Postiga 7, Sinama-Pongolle 6, Djaló 5½ | | Grasshoppers | 1 | 9 Simons |
| | (4-3-3): Abbiati 7, Van Der Wiel 8, Zábavník 7½, Anita 7, Alderweireld 7, Schiemer 6, Cofie 7½, Kiyotake 7, Janko 6½, Simons 7½, Bakenga 5½ | | Round 2 | | Accrington Stanley | 0 |
| | Half-time: | 0-2 | | Referee: | Bazzoli 6½ | | Attendance: | 4,917 | | Possession: | 49%-51% | | Total shots: | 16-9 | | MoM: | Molyneux |
| | 12 Amond | | (4-4-2): Dunbavin 6, Murphy 6½, Molyneux 8, Hatfield 6½, Aldred 6½, Winnard 7, Chippendale 6½, Jeffers 6½, Amond 7½, Joyce 7, Wilson 6½ | | Exeter City | 2 | 20og Winnard, 26 Davies |
| | (4-4-2): Evans 6½, Tully 7, Woodman 7, Doherty 7½, Coles 7½, Baldwin 6½, Davies 6½, Gow 6½, Sercombe 7, Oakley 7½, Cureton 6 | | Brřndby | 2 | 3 Ansaldi, 13 Ansaldi | | Half-time: | 2-3 | | Referee: | Styles 6½ | | Attendance: | 28,892 | | Possession: | 51%-49% | | Total shots: | 6-15 | | MoM: | Pisano |
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| | (4-3-3): Třrnes 5½, Pisano 8, Ansaldi 7½, Thygesen 7, Stenderup 7, Goodson 6, Labyad 6½, Park 7, Gehrt 6, Jřrgensen 7, McGrath 6 | | Rubin | 4 | 21 Hasan Salih, 43 Hasan Salih, 45 Hasan Salih, 69 Ari | | 87 Salukvadze | | (4-3-3): Zoet 5½, Kvirkvelia 7½, Kuzmin 6½, Murawski 7½, César Navas 7, Salukvadze 5½, Ryazantsev 7½, Gökdeniz 7, Hasan Salih 7½, Semak 6½, Ari 6 | | Chelsea | 0 |
| | Half-time: | 0-3 | | Referee: | Oji 8½ | | Attendance: | 42,895 | | Possession: | 46%-54% | | Total shots: | 9-19 | | MoM: | Riera |
| | 14 Bridcutt | | (4-3-3): Taylor 5, Rafinha 5½, Van Aanholt 6, Arteta 7, Van Buyten 6, Maza 7, Rodríguez 7, Gattuso 7, Bridcutt 6, Källström 7, Borini 5½ | | Bursaspor | 3 | 5 Riera, 38 Sesták, 41 Adem |
| | (4-3-3): Carson 5½, Chrétien 7, André Santos 6½, Batalla 7, Ibrahim 7, Ömer 7, Ismail Haktan 6, Riera 8, Pinto 6½, Adem 7, Sesták 6½ | | FC Twente | 3 | 1 Bony, 29 Bony, 75 Bony | | Half-time: | 2-0 | | Referee: | Bettin 6 | | Attendance: | 39,945 | | Possession: | 38%-62% | | Total shots: | 11-13 | | MoM: | Caneira |
| | 20 Cavadov, 57 Bony | | (4-3-3): Aouate 7½, Levels 5½ (53 Wellington 6), Givet 6½, Witsel 7½, Douglas 6½, Rajkovic 6, Tioté 6, Stoch 6½, Bony 7, Ojo 6, Cavadov 5½ | | Sporting | 0 |
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| | (4-3-3): Ricardo Batista 8, Caneira 8, Miguel Veloso 7½, Daniel Carrico 6½ (56 Cervantes 7), Edcarlos 6½, Ânderson Polga 6½, Izmailov 6½, Fernández 7½, Hélder Postiga 7½, Riveros 7 (65 Mexer 6), Djaló 6 | | Fenerbahçe | 0 |
| | Half-time: | 0-0 | | Referee: | Beeby 5½ | | Attendance: | 41,790 | | Possession: | 51%-49% | | Total shots: | 9-14 | | MoM: | Egemen |
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| | (4-3-3): Onur Recep 6½, Gökhan 6½, Bekir 7½, Cristian 7, Egemen 8, Remzi Giray 6, Mehmet 6½, Cech 7, Sow 7½, Semih 6, Burak 6½ | | Club Brugge | 1 | 53 Vargas |
| | (4-3-3): Jorgacevic 7, Vezalov 7½, Stenman 6½, Odjidja-Ofoe 7, Hoefkens 6½, Donk 6, Refaelov 7, Vargas 6, Vleminckx 7, Akpala 6, Víctor Vázquez 6 | | Flamengo | 2 | 52 Vágner Love, 69 Vágner Love | | Half-time: | 0-0 | | Referee: | Pyanikh 5 | | Attendance: | 39,567 | | Possession: | 40%-60% | | Total shots: | 8-14 | | MoM: | Guardado |
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| | (4-3-3): Bruno 6, Leo Moura 7, Juan 7, Willians 7½, Xandăo 6, Welinton 6½, Marlos 6 (63 Marques 6), Alex Teixeira 7½, Vágner Love 6½, Erick Flores 6, Emerson 7 (78 Fabrício 6) | | Deportivo | 2 | 81 Juan Domínguez, 90+4 Diamé |
| | (4-3-3): Guilherme 6½, Juanfran 8, Guardado 8, Diamé 7, Renato Silva 7, José Castro 7, Pablo Álvarez 7½, Juan Domínguez 7½, Nouioui 6½, Valerón 6½, Adrián 6½ | | Grasshoppers | 1 | 17 Janko | | Half-time: | 1-0 | | Referee: | Larsen 6 | | Attendance: | 17,616 | | Possession: | 61%-39% | | Total shots: | 17-8 | | MoM: | Molinaro |
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| | (4-3-3): Abbiati 7½, Van Der Wiel 8, Zábavník 7, Anita 7½, Alderweireld 7½, Schiemer 7½, Cofie 6½, Kiyotake 7½, Janko 7, Simons 7, Bakenga 7 | | PSV | 0 |
| | 19 Vukovic | | (4-3-3): Wiland 7½, Manolev 7½, Molinaro 8, Poulsen 6, Biava 7, Olfers 6, Vukovic 6, El Ahmadi 7 (80 Nilis 6), Koevermans 6, Nijland 6, Paolucci 5½ | | Newport County | 0 |
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| | (3-1-4-2): Pidgeley 5, Porter 6½, Jolley 5½, Minshull 5½, James 6, Yakubu 6½, Thomson 6, Sandell 6½, O'Connor 7 (66 Crow 6), Flynn 5½, Donnelly 5½ | | Arsenal | 3 | 5 Senkerík, 78 Djourou, 84 Vermaelen |
| | (4-3-3): Mannone 6½, Sagna 8, Vermaelen 7½, Tiago 8½, Papastathopoulos 8½, Abidal 8½, Feghouli 8½, Senkerík 8½, Djourou 7½, Pjanic 8, Fran Mérida 7 | | Palermo | 1 | 37 Meyler | | Half-time: | 1-1 | | Referee: | Díaz Vega 7 | | Attendance: | 38,800 | | Possession: | 50%-50% | | Total shots: | 12-21 | | MoM: | Olsson |
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| | (4-3-3): Benussi 6½, Cassani 7, Balzaretti 7½, Meyler 7½, Bovo 6, Goian 6½ (70 Ameobi 6), Krasic 7, Bertolo 7½, Hernández 7, Amauri 6, Watt 6 | | Helsingborg | 3 | 29 Giovinco, 51 Giovinco, 85 Abdellaoue | | 87 Agger | | (4-3-3): Marchetti 6, Abate 7½, Santon 6½, Olsson 8, Agger 7½, Elm 6½, Balotelli 6½, Larsson 7½, Abdellaoue 6, Eriksen 6½ (81 Nordtveit 6), Giovinco 7 | | Rangers | 3 | 5 McFadden, 10p Son, 90+1 Van Damme | | Half-time: | 2-0 | | Referee: | Damgaard 6 | | Attendance: | 33,572 | | Possession: | 62%-38% | | Total shots: | 34-5 | | MoM: | Morrison |
| | 54 Davis | | (4-3-3): McGregor 7½, Hutton 8, Van Damme 8, Davis 7½, Bougherra 8, Wilson 7, Morrison 8½, Naismith 7½, Son 7½, Oriol Romeu 5½ (77 McCulloch 6), McFadden 6½ | | Ayr United | 0 |
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| | (4-3-3): Smith 7, Darmian 7, McCann 6½, Marrone 7, Robertson 6½, Twaddle 6, Mak 6½, Brahimi 7, Weimann 7, McStay 6½, Winters 6 | | Rosenborg | 1 | 32 Skjelbred | | Half-time: | 1-0 | | Referee: | Krondl 7 | | Attendance: | 21,149 | | Possession: | 42%-58% | | Total shots: | 9-16 | | MoM: | Accardi |
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| | (4-3-3): Begovic 7½, Smalling 6½, Mathieu 6½, Shirokov 7, Toprak 7, Nilsson 6½, Skjelbred 7½, Holm 6½, Prica 7, Chantôme 6, Floro Flores 6½ | | Sampdoria | 0 |
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| | (4-3-3): Castellazzi 7, Lucchini 6½, Accardi 7½, Tissone 7½, Gastaldello 7½, Diakité 6½, Pablo 7½, Mannini 7½, Pozzi 7½, Poli 7, Testardi 6½ |
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