| Round 3 | | Athletic Bilbao | 2 | 22 Amorebieta, 90p Soldado | | Half-time: | 1-1 | | Referee: | Rennie 8 | | Attendance: | 39,466 | | Possession: | 50%-50% | | Total shots: | 12-9 | | MoM: | Ramires |
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| | (4-3-3): Aranzubía 7, Torres 7, Amorebieta 6½, Raúl García 7½, Miquel 6½, Mané 7, Jurado 7, Yeste 7½, Soldado 7, Mario Suárez 5½, Vela 5½ | | São Paulo | 1 | 40 Michel Bastos |
| | (4-3-3): Hélton 6, Maicon 6½, Adriano 7 (58 Renato Augusto 6½), Robinho 6½, Thiago 7, David Luiz 6, Ramires 8, Michel Bastos 7, Willian 6, Diego 7, Neymar 6½ | | Auxerre | 1 | 64 Capoue | | Half-time: | 0-0 | | Referee: | Avendaño 7½ | | Attendance: | 25,107 | | Possession: | 55%-45% | | Total shots: | 20-9 | | MoM: | Menez |
| | 86 Briand | | (4-3-3): Lloris 7½, Fanni 7½, Cissokho 7½, Capoue 7, Yanga-Mbiwa 7½, Ciani 7½, Menez 8, Briand 6½, Libertazzi 5½, Gameiro 7½, Rémy 6½ | | Lazio | 0 |
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| | (4-3-3): Stekelenburg 8, Cappelletti 6, Radu 6½, Nocerino 6½, Ariaudo 6½, Pasqual 7, Schelotto 7, Ilicic 6½, Defoe 7, Antonelli 6, Di Vaio 6½ | | Borussia Dortmund | 2 | 30 Gomez, 44 Khedira | | Half-time: | 2-0 | | Referee: | Cinciripini 5½ | | Attendance: | 65,595 | | Possession: | 57%-43% | | Total shots: | 14-12 | | MoM: | Gomez |
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| | (4-3-3): Neuer 7½, Schwaab 7, Schmelzer 8, Khedira 7½, Subotic 8, Compper 7, Müller 8, Götze 6½, Gomez 8, Kroos 7, Schürrle 6½ | | Lyon | 0 |
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| | (4-3-3): Ruffier 6½, Coquelin 7, Armand 7, Marveaux 6½, Escudé 6½, Coulibaly 6, Éderson 6, Boussoufa 6, Belfodil 6½ (61 Tafer 6½), Flamini 5½, Henry 6½ | | Everton | 1 | 10 Yobo | | Half-time: | 1-0 | | Referee: | Fraser 7 | | Attendance: | 40,426 | | Possession: | 44%-56% | | Total shots: | 10-13 | | MoM: | Mascherano |
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| | (4-3-3): Howard 6½, Neville 7, Zambrotta 7½, Wallace 6½, Yobo 7½, Braafheid 7½, Osman 6½, Bilyaletdinov 6½ (84 Jutkiewicz 6), Yakubu 7, Anichebe 5½, Baxter 6 | | Valencia | 2 | 50 Mascherano, 77 Van Der Vaart | | 40 Javi Martínez | | (4-3-3): Reina 6½, Lahm 6½, Javi Martínez 8, Mascherano 8½, Puyol 6½, San Jose 6½, Pedro 7½, Perotti 6, Hernández 7 (77 Henríquez 6), Van Der Vaart 6½, Agüero 7 (77 Javi Manquillo 6) | | FC Schalke 04 | 0 |
| | Half-time: | 0-2 | | Referee: | Hauge 6 | | Attendance: | 44,527 | | Possession: | 49%-51% | | Total shots: | 9-13 | | MoM: | Ben Arfa | | TV: | live |
| | 60 Westermann | | (4-3-3): Bailly 6½, Träsch 6½, Salcido 7½, Gündogan 7 (80 Hugo Almeida 6), Westermann 6½, Reinartz 6½, Farfán 7, Rausch 7, De Jong 7, Crouch 5½, Sturridge 6½ | | Marseille | 2 | 17 Ben Arfa, 26 Ribéry | | 31 Ribéry | | (4-3-3): Hart 6½, Reveillère 7 (65 Abriel 8), Sakho 7½, Ben Arfa 8, Heinze 7, Rodwell 6, González 7½, Ribéry 7, Brandão 7, Griezmann 6, Benzema 6 | | Feyenoord | 1 | 42 Castaignos | | Half-time: | 1-0 | | Referee: | Beeby 6½ | | Attendance: | 33,734 | | Possession: | 59%-41% | | Total shots: | 18-6 | | MoM: | Bystrov |
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| | (4-3-3): Mulder 5½, De Vrij 7, Pieters 6½, De Guzman 7, Vlaar 7, Dingsdag 7½, Kuyt 7, Drenthe 7, Castaignos 7, Babovic 6½, Van Wolfswinkel 7 | | Dynamo | 2 | 52 Vukojevic, 76og Kuyt |
| | (4-3-3): Carrasso 6½, Mykhalyk 6, Nesmachnyi 7½, Vukojevic 6, Tymoschuk 6½, Diakhaté 6, Bystrov 8, Pienaar 6, Milevskyi 6, Granero 6½, Yarmolenko 6 | | Manchester City | 1 | 28 Özil | | Half-time: | 1-0 | | Referee: | Chalaskiewicz 8 | | Attendance: | 47,440 | | Possession: | 44%-56% | | Total shots: | 9-15 | | MoM: | Malafeev | | TV: | highlights |
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| | (4-3-3): Buffon 7, Vidic 6, Marchisio 7½, Pirlo 7, Piqué 7½, Song 5½, Herrmann 7½, Özil 6½, Vydra 6, Hazard 7, Tévez 6 | | Anderlecht | 0 |
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| | (4-3-3): Malafeev 8, Maggio 7½, Pocognoli 7½, Dembélé 7½, Chedjou 6½, Chyhrynskyi 7, Gillet 8, Shaqiri 7, Kerzhakov 7½, Rolfes 6, Jonas 7 | | Round 4 | | Anderlecht | 2 | 25 Kerzhakov, 85 Gillet | | Half-time: | 1-1 | | Referee: | Rosetti 6 | | Attendance: | 27,952 | | Possession: | 44%-56% | | Total shots: | 9-10 | | MoM: | Wijnaldum | | TV: | highlights |
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| | (4-3-3): Malafeev 7, Maggio 6, Pocognoli 7, Dembélé 7, Chedjou 6½, Chyhrynskyi 6, Gillet 7½, Shaqiri 7, Kerzhakov 6, Rolfes 6, Jonas 6 | | Barcelona | 2 | 24 Iniesta, 65 Ibrahimovic |
| | (4-3-3): Pinto 6½, Dani Alves 6½, Jordi Alba 7, Xavi 7 (66 Wijnaldum 7½), Skrtel 7½, Mexès 6½, Isaac Cuenca 6, Iniesta 7½, Ibrahimovic 7½, Fabregas 6, Jeffren 6½ | | Bayern München | 1 | 1 Klose | | Half-time: | 1-0 | | Referee: | Borriello 7½ | | Attendance: | 54,643 | | Possession: | 51%-49% | | Total shots: | 12-11 | | MoM: | Neville | | TV: | live |
| | 3 Ignjovski, 37 Barrios | | (4-3-3): Andújar 7½, Görlitz 6½, Lovren 7½, Essien 7½, Demichelis 6½, Forlin 7, Ignjovski 7½, Marin 6½ (80 Pogba 6), Klose 7½, Barrios 5½, Anelka 6½ | | Everton | 0 |
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| | (4-3-3): Howard 7, Neville 8, Zambrotta 7½, Wallace 6½, Yobo 6, Braafheid 6, Osman 7, Bilyaletdinov 7½, Yakubu 7½, Anichebe 5½, Baxter 5½ | | Benfica | 2 | 3 Taddei, 24 Cardozo | | Half-time: | 2-0 | | Referee: | D'Urso 6½ | | Attendance: | 41,896 | | Possession: | 49%-51% | | Total shots: | 14-21 | | MoM: | Parker |
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| | (4-3-3): Felipe 6½, Pereira 7, Eliseu 7½, Carlos Martins 6½ (76 Bosingwa 7½), Maicon 6, Ricardo Carvalho 7, Taddei 8, Cleiton Xavier 7, Cardozo 6 (54 Rafa 7), Drogba 6, Alex 6 | | West Ham United | 2 | 50 Lampard, 52 Bent | | 42 Lampard, 48 Terry, 89 Beckham | | (4-3-3): Green 6½, Jones 6½, Baines 6, Gerrard 7 (49 Parker 8), Terry 7, Mancienne 6½, Walcott 6, Johnson 7, Bent 6½, Lampard 7, Beckham 5½ | | Lazio | 1 | 79og Taylor | | Half-time: | 0-1 | | Referee: | Braamhaar 8 | | Attendance: | 36,562 | | Possession: | 51%-49% | | Total shots: | 21-10 | | MoM: | Nocerino | | TV: | highlights |
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| | (4-3-3): Stekelenburg 6½, Cappelletti 6, Pasqual 7½, Nocerino 8, Radu 7, Ariaudo 8, Schelotto 6½, Ilicic 7, Defoe 7, Brocchi 6½ (57 Obi 7), Di Vaio 7½ | | Liverpool | 1 | 9 Huntelaar |
| | (4-3-3): Vorm 7, Zabaleta 6½, Johnson 7 (48 Saric 6½), Touré 7, Taylor 6, Insúa 7, Badelj 7, Vrsaljko 6½, Huntelaar 7½, Ramsey 6, Németh 5½ | | Lyon | 1 | 38 Flamini | | Half-time: | 1-0 | | Referee: | Ceccarini 7 | | Attendance: | 40,392 | | Possession: | 54%-46% | | Total shots: | 14-9 | | MoM: | Tafer |
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| | (4-3-3): Ruffier 7½, Coquelin 6½ (66 Tafer 7½), Armand 6, Marveaux 7½, Escudé 7, Coulibaly 6½, Éderson 6½, Boussoufa 7, Belfodil 6½ (70 Sunu 6½), Flamini 7, Henry 6 | | Auxerre | 0 |
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| | (4-3-3): Lloris 7½, Fanni 6, Cissokho 6½, Capoue 7 (81 Özyakup 6), Yanga-Mbiwa 7½, Ciani 6½, Menez 7, Briand 6½, Libertazzi 6½, Gameiro 6, Rémy 6½ | | Manchester United | 3 | 60 Berbatov, 66 Evrà, 72 Welbeck | | Half-time: | 0-1 | | Referee: | Van Vliet 6½ | | Attendance: | 45,104 | | Possession: | 56%-44% | | Total shots: | 17-13 | | MoM: | Evrà |
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| | (4-3-3): Foster 7, Richards 8, Evrà 8½, Carrick 5½ (61 Diouf 8), Evans 6½, O'Shea 7½, Fletcher 8, Obertan 7½, Berbatov 7½, Anderson 6½, Welbeck 6 | | Feyenoord | 1 | 31 Drenthe |
| | (4-3-3): Mulder 7½, De Vrij 7, Pieters 7½, De Guzman 7, Vlaar 6½, Dingsdag 6½, Kuyt 6½, Drenthe 6, Castaignos 7 (66 Van La Parra 6), Biseswar 5½, Van Wolfswinkel 5½ | | São Paulo | 1 | 81 Robinho | | Half-time: | 0-2 | | Referee: | Karlsson 6½ | | Attendance: | 53,095 | | Possession: | 52%-48% | | Total shots: | 14-14 | | MoM: | Xabi Alonso |
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| | (4-3-3): Hélton 6½, Maicon 6½, Adriano 5½, Robinho 8, Thiago 6½, David Luiz 6, Ramires 6½, Michel Bastos 7, Willian 6, Diego 6½, Neymar 6 | | Real Madrid | 2 | 35 Messi, 45 Van Persie |
| | (4-3-3): Casillas 6, Sergio Ramos 8, Badstuber 6½, Xabi Alonso 8, Chiellini 7, Kompany 6½, Silva 7, Sneijder 6½, Van Persie 6½, Ronaldo 7½, Messi 6 | | Tottenham Hotspur | 1 | 75 Modric | | Half-time: | 0-0 | | Referee: | Bazzoli 7½ | | Attendance: | 36,074 | | Possession: | 44%-56% | | Total shots: | 9-12 | | MoM: | Raúl García |
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| | (4-3-3): Víctor Valdés 7½, Walker 7, Alaba 7, Schweinsteiger 7½, Ferdinand 6½, Cáceres 6, Foor 6, Nani 5½, Torres 6, Modric 7, Cassano 6½ | | Athletic Bilbao | 0 |
| | 56 Yeste, 63 Mario Suárez | | (4-3-3): Aranzubía 8, Torres 7, Amorebieta 7, Raúl García 8, Miquel 7, Mané 6½, Jurado 7, Yeste 6½, Soldado 6½, Mario Suárez 7, Vela 6½ (80 Canella 6) |
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