| Round 5 | | Athletic Bilbao | 0 |
| | Half-time: | 0-1 | | Referee: | Bennett 6½ | | Attendance: | 39,671 | | Possession: | 49%-51% | | Total shots: | 15-10 | | MoM: | Raúl García |
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| | (4-3-3): Aranzubía 7, Torres 6, Amorebieta 7, Raúl García 8, Miquel 6½, Mané 6½, Jurado 6½, Yeste 6½, Soldado 7, Mario Suárez 6½, Vela 7 (80 Canella 6) | | Valencia | 1 | 45 Van Der Vaart |
| | (4-3-3): Reina 6½, Lahm 8, Javi Martínez 6½, Mascherano 7½, Puyol 6½, San Jose 6½, Pedro 7, Perotti 7, Hernández 6½ (47 Henríquez 6½), Van Der Vaart 7, Agüero 7 (67 Javi Manquillo 6½) | | Auxerre | 1 | 5 Menez | | Half-time: | 1-0 | | Referee: | Foy 8 | | Attendance: | 25,098 | | Possession: | 46%-54% | | Total shots: | 15-19 | | MoM: | Barrios | | TV: | live |
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| | (4-3-3): Lloris 7, Danzé 6, Cissokho 7, Capoue 7, Yanga-Mbiwa 6½, Ciani 6½ (83 Klaassen 7), Gameiro 6, Menez 7, Libertazzi 6, Briand 5½, Rémy 7 | | Bayern München | 1 | 70 Marin | | 63 Sahin | | (4-3-3): Andújar 7, Görlitz 6½, Pranjic 7, Essien 7½, Demichelis 7 (77 Palacios 6), Lovren 7, Ignjovski 7, Marin 6½, Barrios 7½, Sahin 7, Anelka 6½ | | Barcelona | 1 | 43 Skrtel | | Half-time: | 1-0 | | Referee: | Hauge 5½ | | Attendance: | 59,885 | | Possession: | 57%-43% | | Total shots: | 10-10 | | MoM: | Wijnaldum |
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| | (4-3-3): Pinto 7, Dani Alves 8, Jordi Alba 8, Xavi 6½ (64 Wijnaldum 8½), Skrtel 7½, Mexčs 6½, Isaac Cuenca 7, Iniesta 7½, Ibrahimovic 7½, Fabregas 7½, Jeffren 5½ | | Săo Paulo | 1 | 85 Michel Bastos |
| | (4-3-3): Hélton 7½, Maicon 7, Adriano 6 (86 Renato Augusto 6), Robinho 6½, Thiago 7, David Luiz 6, Ramires 7, Michel Bastos 6, Willian 5½, Diego 6½, Neymar 5½ | | Borussia Dortmund | 2 | 35 Götze, 47 Kroos | | Half-time: | 1-0 | | Referee: | Ancion 6½ | | Attendance: | 74,309 | | Possession: | 49%-51% | | Total shots: | 14-8 | | MoM: | Schmelzer | | TV: | highlights |
| | 22 Schürrle, 42 Götze | | (4-3-3): Neuer 7½, Boateng 6½, Schmelzer 8, Kroos 8, Subotic 6½, Compper 7, Müller 7, Götze 7, Gomez 7, Bender 7, Schürrle 6½ | | Tottenham Hotspur | 0 |
| | 40 Ferdinand, 45+1 Walker | | (4-3-3): Víctor Valdés 7½, Walker 6, Alaba 6½, Schweinsteiger 7, Ferdinand 7, Cáceres 7 (67 Crescenzi 6½), Foor 6, Nani 7, Torres 6, Modric 6½, Cassano 6 | | Everton | 1 | 5 Yakubu | | Half-time: | 1-1 | | Referee: | Maciorowski 5½ | | Attendance: | 35,629 | | Possession: | 51%-49% | | Total shots: | 14-12 | | MoM: | Pocognoli |
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| | (4-3-3): Howard 7, Neville 7, Zambrotta 7½, Wallace 6½, Yobo 7, Braafheid 6½, Osman 6, Bilyaletdinov 7½, Yakubu 6½, Anichebe 5½, Baxter 5½ | | Anderlecht | 2 | 18 Shaqiri, 53 Maggio |
| | (4-3-3): Malafeev 7, Maggio 7½, Pocognoli 8½, Dembélé 8, Chedjou 5½, Chyhrynskyi 7 (75 Ramis 6½), Gillet 6½, Shaqiri 7½, Kerzhakov 6½, Rolfes 6, Jonas 7 (78 Taylor 6) | | FC Schalke 04 | 1 | 25 Träsch | | Half-time: | 1-1 | | Referee: | Řvrebř 7½ | | Attendance: | 34,283 | | Possession: | 50%-50% | | Total shots: | 20-12 | | MoM: | Nocerino |
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| | (4-3-3): Bailly 6, Träsch 7½, Salcido 6½, Gündogan 6½ (80 Hugo Almeida 6), Westermann 6½, Reinartz 7, Farfán 7, Rausch 6½, De Jong 6½, Crouch 6, Sturridge 6 | | Lazio | 3 | 4 Pasqual, 60 Schelotto, 72 Brocchi |
| | (4-3-3): Stekelenburg 5½, Cappelletti 7, Pasqual 7½, Nocerino 7½, Radu 6½, Ariaudo 7, Schelotto 7½, Ilicic 7, Defoe 6, Brocchi 7 (76 Adamo 6), Di Vaio 7½ | | Feyenoord | 0 |
| | Half-time: | 0-1 | | Referee: | Arena 6½ | | Attendance: | 39,195 | | Possession: | 43%-57% | | Total shots: | 11-23 | | MoM: | Abriel | | TV: | highlights |
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| | (4-3-3): Mulder 5½, De Vrij 6½, Pieters 6½, De Guzman 7½, Vlaar 7, Dingsdag 6½, Kuyt 6, Drenthe 6, Castaignos 7, Engelaar 5½, Van Wolfswinkel 6½ | | Marseille | 3 | 38 Benzema, 72 Brandăo, 89 Sakho | | 25 Reveillčre | | (4-3-3): Hart 6½, Reveillčre 6½ (65 Abriel 8), Sakho 7, Ben Arfa 7½, Heinze 7½, Rodwell 6, González 8, Ribéry 7, Brandăo 6½, Griezmann 5½, Benzema 7 | | Liverpool | 3 | 38 Taylor, 48 Nolan, 83 Huntelaar | | Half-time: | 1-1 | | Referee: | Vorjas 6 | | Attendance: | 45,171 | | Possession: | 51%-49% | | Total shots: | 9-14 | | MoM: | Evrŕ | | TV: | live |
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| | (4-3-3): Vorm 7½, Zabaleta 6½, Johnson 6½, Touré 8, Taylor 7, Insúa 6½, Badelj 6½, Vrsaljko 6½, Huntelaar 7, Nolan 7, Németh 6½ | | Manchester United | 1 | 14 Fletcher |
| | (4-3-3): Foster 7½, Richards 7½, Evrŕ 8½, Carrick 7, Evans 7½, O'Shea 6, Fletcher 7½, Obertan 6, Berbatov 7, Anderson 7, Welbeck 6½ | | Manchester City | 2 | 7 Özil, 40 Özil | | Half-time: | 2-1 | | Referee: | Damgaard 7 | | Attendance: | 47,365 | | Possession: | 45%-55% | | Total shots: | 16-10 | | MoM: | Cardozo |
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| | (4-3-3): Buffon 7, Vidic 6½, Hazard 7½, Pirlo 7½, Piqué 6½, Marchisio 6 (65 De Jong 6), Herrmann 6½, Özil 7½, Vydra 5½, Tévez 6, Rooney 6½ | | Benfica | 1 | 44 Taddei | | 11 Cleiton Xavier | | (4-3-3): Felipe 7, Pereira 7, Eliseu 7, Carlos Martins 7, Maicon 7½, Ricardo Carvalho 7, Taddei 7½, Cleiton Xavier 7, Cardozo 8, Drogba 6½, Alex 5½ | | Real Madrid | 2 | 29 Messi, 52 Ronaldo | |
| | (4-3-3): Casillas 7½, Sergio Ramos 8½, Badstuber 8, Xabi Alonso 8, Chiellini 7½, Kompany 7, Silva 7, Sneijder 6, Van Persie 7, Ronaldo 8, Messi 7 | | Lyon | 0 |
| | 2 Belfodil, 20 Armand, 44 Coquelin | | (4-3-3): Ruffier 7½, Coquelin 7 (66 Taiwo 7), Armand 7 (52 Trezeguet 7½), Éderson 6½, Escudé 7½, Coulibaly 6, Flamini 6½, Boussoufa 7, Belfodil 5½, Sunu 5½, Henry 6 | | West Ham United | 2 | 72og Vida, 77p Bent | | Half-time: | 0-0 | | Referee: | Krondl 6½ | | Attendance: | 34,366 | | Possession: | 48%-52% | | Total shots: | 21-13 | | MoM: | Jones | | TV: | highlights |
| | 33 Beckham, 46 Gerrard, 48 Mancienne, 63 Lampard | | (4-3-3): Green 7½, Jones 7½, Baines 7½, Gerrard 7½, Terry 7, Mancienne 6, Walcott 6½, Johnson 6 (59 Parker 7), Bent 7½, Lampard 6½ (64 Oxlade-Chamberlain 6½), Beckham 5½ | | Dynamo | 0 |
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| | (4-3-3): Shovkovskyi 7½, Khacheridi 7½, Nesmachnyi 6½, Vukojevic 7, Tymoschuk 6½, Mykhalyk 6, Bystrov 7 (53 Vida 7½), Pienaar 6, Milevskyi 7½, Zyryanov 6, Yarmolenko 6½ | | Round 3 | | Real Madrid | 3 | 16 Messi, 52 Ronaldo, 68 Messi | | Half-time: | 1-1 | | Referee: | Waddel 5½ | | Attendance: | 79,953 | | Possession: | 56%-44% | | Total shots: | 19-15 | | MoM: | Van Persie |
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| | (4-3-3): Casillas 6½, Sergio Ramos 7½, Badstuber 7½, Xabi Alonso 7½, Chiellini 7, Kompany 7½, Silva 7½, Sneijder 6½, Van Persie 7½, Ronaldo 7, Messi 7 | | Benfica | 2 | 11 Cardozo, 69p Cardozo |
| | (4-3-3): Felipe 6½, Pereira 6½, Eliseu 7, Carlos Martins 7, Maicon 6, Ricardo Carvalho 6½, Taddei 6, Cleiton Xavier 6, Cardozo 6, Drogba 5½, Alex 6 | | Round 4 | | Valencia | 0 |
| | Half-time: | 0-1 | | Referee: | Young 7½ | | Attendance: | 54,237 | | Possession: | 51%-49% | | Total shots: | 7-6 | | MoM: | Bailly |
| | 33 Perotti, 46 Van Der Vaart | | (4-3-3): Reina 6½, Lahm 7 (56 Pastore 7½), Javi Martínez 6, Mascherano 7½, Puyol 7, San Jose 6½, Pedro 7, Perotti 7, Hernández 6½, Van Der Vaart 6½, Agüero 7 | | FC Schalke 04 | 1 | 6 De Jong | | 89 Crouch | | (4-3-3): Bailly 7½, Träsch 7, Salcido 7, Gündogan 7, Westermann 7, Reinartz 7, Farfán 5½, Rausch 6, De Jong 6½, Crouch 5½, Sturridge 6½ | | Round 3 | | Liverpool | 1 | 42 Huntelaar | | Half-time: | 1-1 | | Referee: | Onufer 5½ | | Attendance: | 45,355 | | Possession: | 49%-51% | | Total shots: | 12-11 | | MoM: | Touré |
| | 25 Ramsey | | (4-3-3): Vorm 7, Zabaleta 6½, Johnson 6½ (81 Sřrum 6), Touré 8, Taylor 6½, Ramsey 6½, Badelj 7, Vrsaljko 6½, Huntelaar 7, Nolan 6, Aleksic 6 | | Bayern München | 1 | 11 Diaby | | 24 Marin | | (4-3-3): Andújar 7, Görlitz 6, Pranjic 6½, Essien 7½, Demichelis 7½, Lovren 6½, Sahin 6, Marin 7, Barrios 6½, Diaby 7, Anelka 6 |
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