| Round 5 | | Ajax | 1 | 60 Emanuelson | | Half-time: | 0-1 | | Referee: | Wiley 7 | | Attendance: | 37,668 | | Possession: | 48%-52% | | Total shots: | 11-14 | | MoM: | Atouba |
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| | (4-3-3): Mirante 6½, Ogararu 6½ (70 Lestienne 6), Atouba 7½, De Zeeuw 6½, Dainelli 6½, Wielaert 6, Sam 7½, Emanuelson 6½, Matavz 7½, Floccari 6, De Jong 7½ | | Fiorentina | 1 | 6 Marchionni |
| | (4-3-3): Forster 6½, De Silvestri 6½, Gobbi 7½, Montolivo 6 (81 Altidore 6), Camporese 6½ (61 Rodríguez 6½), Comotto 6½, Marchionni 7, Rômulo 6½, Gilardino 7, Cana 6, Ljajic 6½ | | Bayer Leverkusen | 1 | 11og Cuéllar | | Half-time: | 1-0 | | Referee: | Dowd 6 | | Attendance: | 22,336 | | Possession: | 51%-49% | | Total shots: | 8-16 | | MoM: | Cambiasso |
| | 19 Fritz, 38 Schulz | | (4-3-3): Wiese 7, Piszczek 6½, Schulz 7, Cambiasso 8½, Díaz 7, Friedrich 8, Fritz 6½ (56 Servet 6½), Arango 7, Kuranyi 7½, Elano 7, Kakuta 5½ | | Aston Villa | 1 | 77 Shorey |
| | (4-3-3): Guzan 7½, Cuéllar 6½, Shorey 7, Sidwell 7, Bouma 6, Clark 7½, Milner 7½, Petrov 7, Heskey 6½, Bannan 6, Agbonlahor 6 | | Cruz Azul | 1 | 34 Robben | | Half-time: | 1-0 | | Referee: | Levnikov 6 | | Attendance: | 35,767 | | Possession: | 51%-49% | | Total shots: | 14-6 | | MoM: | João Pereira |
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| | (4-3-3): Corona 7, João Pereira 8, Pereira 7, Fellaini 7½, Jagielka 6½, Nesta 6½, Torrado 6½ (81 Insigne 6), Robben 7½, Jelavic 7½, De Marcos 6½, Suárez 6½ | | Lorient | 0 |
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| | (4-3-3): Audard 7, Congré 7½, Morel 6½, Mvuemba 7, Marchal 7, Mignot 5½, Amalfitano 7½, Birsa 6½, Hoarau 6½, Pied 6, Sagbo 6½ | | Internacional | 2 | 15 Wágner, 61 Fred | | Half-time: | 1-1 | | Referee: | Hill 7 | | Attendance: | 46,579 | | Possession: | 61%-39% | | Total shots: | 21-8 | | MoM: | Sandro |
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| | (4-3-3): Rafael 7½, Marcelo 8, Kléber 7, Sandro 8½, Hilton 8, André Bahia 6½, Giuliano 7, Wágner 6 (82 Mariano 6), Fred 7½, Walter 7, Jô 6 | | Atlético Madrid | 1 | 39 Schaars |
| | (4-3-3): Sergio Asenjo 7, Johnson 6½, Marcos Alonso 6½, Biglia 7, Marc Muniesa 6½ (62 Bojan 7), Perisic 6½, Banega 6½, Tadic 7, Borja 6, Schaars 6½, Rodrigo 5½ | | Juventus | 3 | 1 Berg, 39 Camoranesi, 49 Nenê | | Half-time: | 2-1 | | Referee: | Franceschini 7 | | Attendance: | 26,025 | | Possession: | 49%-51% | | Total shots: | 17-11 | | MoM: | Afellay |
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| | (4-3-3): Manninger 7½, Corluka 7½, De Ceglie 7½, Afellay 8½, Mertesacker 7½, Bassong 6, Camoranesi 6½, Candreva 7, Berg 6½, Felipe Melo 6½, Nenê 6 | | Zenit | 1 | 22 Danny | | 11 Lazovic, 14 Huszti, 27 Fayzulin, 85 Fernando Meira | | (4-3-3): Gordon 7, Tomovic 6½, Lombaerts 8, Guilherme 7, Fernando Meira 7½, Semberas 6½, Fayzulin 5½, Danny 6, Kornilenko 7, Huszti 6, Lazovic 5½ | | Napoli | 1 | 72 Zaccardo | | Half-time: | 0-0 | | Referee: | Gumienny 5½ | | Attendance: | 41,955 | | Possession: | 52%-48% | | Total shots: | 11-10 | | MoM: | Pazienza |
| | 25 Zaccardo | | (4-3-3): De Sanctis 7, Campagnaro 7½, Moretti 7, Gargano 7½, Ranocchia 6½, Cannavaro 7, Necip 6½, Keita 6, Zaccardo 7, Pazienza 8, Quagliarella 5½ | | Milan | 1 | 83 Distin |
| | (4-3-3): Given 6½, Kolarov 7, Bocchetti 7½, Seedorf 7½, Distin 7½, Onyewu 7 (61 Beretta 5½), Joaquín 7½, Ambrosini 6, Bendtner 7, Ireland 7, Adiyiah 6½ | | Sevilla | 2 | 24 Fernando Navarro, 83 Navas | | Half-time: | 1-1 | | Referee: | Borriello 6 | | Attendance: | 44,849 | | Possession: | 57%-43% | | Total shots: | 17-13 | | MoM: | Navas | | TV: | highlights |
| | 77 Makoun | | (4-3-3): Palop 6½, Alexis 7, Fernando Navarro 8, Raul Meireles 8, Naldo 6½, Fernández 7, Navas 8, Makoun 7, Negredo 7½, Kiessling 6 (83 Filipe Luis 6), Kiko 6 | | SV Werder Bremen | 1 | 18 Dost |
| | (4-3-3): Gabulov 7½, Prödl 7½, Abdennour 6 (85 Smith 6), Hunt 6½, Pasanen 6, Bargfrede 5½, Vranjes 6½, Diego Capel 6½, Dost 6½, Niemeyer 6, Wagner 6½ | | Spartak | 3 | 2 Mamaev, 33 Mamaev, 69 Yanbaev | | Half-time: | 2-0 | | Referee: | Elton 5½ | | Attendance: | 51,326 | | Possession: | 54%-46% | | Total shots: | 21-9 | | MoM: | Bazhenov |
| | 34 Pogrebnyak | | (4-3-3): Ryzhikov 7½, Anyukov 6½, Yanbaev 7, Semshov 8, Berezutsky 6½, Suchý 6, Bazhenov 8, Zhirkov 7, Pogrebnyak 6, Mamaev 7, Arshavin 5½ | | River Plate | 0 |
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| | (4-3-3): Ospina 7, Ferrari 7, Rojo 6 (79 Buonanotte 6), Prediguer 6½, Cicinho 6½, Díaz 6½, Mouche 6½, Rosický 7, Castillejos 7½, López 6, Amrabat 5½ | | TSG Hoffenheim | 3 | 4 Ba, 58og Aogo, 75 Salihovic | | Half-time: | 1-3 | | Referee: | Pinto Correia 5 | | Attendance: | 29,982 | | Possession: | 55%-45% | | Total shots: | 15-11 | | MoM: | Demel | | TV: | live |
| | 44 Simunic, 77 Ebondo | | (4-3-3): Consigli 6, Ebondo 7, Simunic 6, Maicosuel 6½ (76 Carlos Eduardo 6), Mangane 6½, Vorsah 6, Vukcevic 5½ (76 Owomoyela 6), Salihovic 7, Ba 7, Ibisevic 6, Sessègnon 7 | | Hamburger SV | 3 | 21 Jansen, 27 Jansen, 33 Pavlyuchenko |
| | (4-3-3): Turina 6, Demel 8, Aogo 6½, Trochowski 6½, Mathijsen 7, Rozehnal 6, Behrami 7, Jansen 6½ (69 Cichero 6½), Pavlyuchenko 7, Guerrero 5½, Petric 6½ | | VfB Stuttgart | 0 |
| | Half-time: | 0-1 | | Referee: | Jorge Corroado 6½ | | Attendance: | 48,379 | | Possession: | 53%-47% | | Total shots: | 7-10 | | MoM: | Danilo | | TV: | highlights |
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| | (4-3-3): Ulreich 7, Hamit 7½, Boka 7, Kehl 7½, Osorio 7, Niedermeier 7½, Lanig 7½, Aquilani 6, Lewandowski 7½, Orbáiz 6½, Cacau 6½ | | Palmeiras | 1 | 38 Ronaldinho | | 83 Toró | | (4-3-3): Júlio César 7, Figueroa 6½ (63 Ewerthon 7½), Armero 7, Lucas 7, Danilo 8, Rafael Toloi 6, Diego Souza 6, Toró 6, Robert 6½, Edinho 6½, Ronaldinho 7½ | | Villarreal | 2 | 2p Derdiyok, 30 Sigurðsson | | Half-time: | 2-0 | | Referee: | Rennie 7 | | Attendance: | 22,961 | | Possession: | 45%-55% | | Total shots: | 11-11 | | MoM: | Schwarzer | | TV: | highlights |
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| | (4-3-3): Schwarzer 8, Eboué 6½, Marcellis 5½, Barry 7, Dawson 6½, Juan 6½, Gómez 7, Hleb 7, Derdiyok 6½, Sigurðsson 7, Forlán 6½ | | Celtic | 0 |
| | 2 Katsouranis, 14 Cahill | | (4-3-3): Jääskeläinen 7½, Cherundolo 7, José Ángel 6 (80 Izaguirre 6), Defour 7, Katsouranis 7½, Kolodin 7 (83 Brown 6), Henderson 7, McGeady 6½, Cissé 7, Cahill 6½, Mlapa 6½ | | Round 3 | | Sevilla | 0 |
| | Half-time: | 0-1 | | Referee: | Hansson 7 | | Attendance: | 44,811 | | Possession: | 44%-56% | | Total shots: | 8-14 | | MoM: | Ninis |
| | 16 Alexis, 56 Friedrich | | (4-3-3): Palop 7½, Alexis 6½, Fernando Navarro 7½, Raul Meireles 7 (69 Wisgerhof 7), Naldo 6½, Friedrich 6, Navas 7½, Renato 6½, Kiessling 7, Negredo 6, Kiko 7 | | Milan | 1 | 35 Ireland |
| | (4-3-3): Given 7, Kolarov 5½, Bocchetti 6½ (61 Ninis 7½), Seedorf 7½, Distin 7½, Onyewu 6½, Joaquín 7½, Ambrosini 6½, Bendtner 7½, Ireland 7, Adiyiah 6 |
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