| Round 5 | | Boca Juniors | 1 | 57 Chavez | | Half-time: | 0-1 | | Referee: | Brito Arceo 6½ | | Attendance: | 35,718 | | Possession: | 53%-47% | | Total shots: | 10-20 | | MoM: | Routledge |
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| | (4-3-3): Muslera 6½, Barroso 7, Monzón 6, Moralez 6½, Burdisso 6½ (49 Routledge 8), Muñoz 6½, Chavez 7½, Bruno César 7, Funes Mori 6½, Guthrie 7½, Saviola 6 | | Baník Ostrava | 1 | 37 El Shaarawy |
| | (3-4-3): Courtois 7, Barzagli 6½, Kuba 6, Zanetti 7, El Shaarawy 6½, Busquets 6½, Giroud 6, Hubocan 7, Ruiz 6½, Totti 6½, Di Natale 7½ | | Bordeaux | 1 | 7 Plasil | | Half-time: | 1-0 | | Referee: | Sandra 6 | | Attendance: | 34,078 | | Possession: | 50%-50% | | Total shots: | 9-12 | | MoM: | Motta |
| | 47 M'Bengue | | (4-3-3): Bédénik 6, Béria 7½, Domizzi 7, Fernando 7½, M'Bengue 7, Sané 6½ (83 Bostock 6), Govou 7½, Vuckic 6, Auassar 5½, Plasil 7, Jussiê 6 | | Inter | 1 | 82 Quaresma | | 43 Diamanti, 56 Pandev | | (4-3-3): Belec 7, Donati 7, Chivu 7½, Motta 8, Stankovic 7, Diamanti 6, Pandev 6, Quaresma 7, Alibec 6, Muntari 6½, Eto'o 7 | | Boulogne | 1 | 60 Álvaro | | Half-time: | 0-0 | | Referee: | Uilenberg 6 | | Attendance: | 14,942 | | Possession: | 44%-56% | | Total shots: | 16-13 | | MoM: | García |
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| | (4-3-3): Rui Patrício 7, Tomecak 6, Ibañez 6½, Mikel 7½, Gallas 6½ (59 Davies 7), Klose 6, Santana 5½, Muniain 7, Álvaro 7½, Diarra 8, Emeghara 5½ | | Independiente | 1 | 53og Gallas |
| | (4-3-3): García 8, Tuzzio 6, Mareque 7½, Busse 7½, Galeano 7, Rodríguez 6, Fredes 6½, Mancuello 7, Gandín 6½, Silvera 5½, Suarez 6 | | Espanyol | 2 | 32 Verdú, 90p Tamudo | | Half-time: | 1-0 | | Referee: | Bazzoli 6 | | Attendance: | 40,714 | | Possession: | 61%-39% | | Total shots: | 14-11 | | MoM: | Tamudo | | TV: | highlights |
| | 76 Roncaglia | | (4-3-3): Álvarez 7½, Motta 7½, Pinto 8, Patrick 6½, Roncaglia 7, Pareja 7½, Callejón 6 (69 Toribio 6½), Verdú 7 (71 Leugers 8), Tamudo 8, Sahar 5½, Olic 6½ | | CSKA | 0 |
| | 4 Jiránek, 88 King | | (4-3-3): Moyá 7, Nababkin 6½, Schennikov 6½, Fábio Simplício 7, Sergio Sánchez 7½, Jiránek 6½, Oliseh 6½, Ayew 7, King 5½, Denisov 6½, Dzsudzsák 5½ | | FC Basel | 1 | 73 Podolski | | Half-time: | 0-0 | | Referee: | Jol 6 | | Attendance: | 38,431 | | Possession: | 46%-54% | | Total shots: | 19-15 | | MoM: | Debuchy |
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| | (4-4-2): Akinfeev 6, Lichtsteiner 7½, José Enrique 7½, Matuidi 7, Cahill 8, Dante 6½, Mkhitaryan 6, Podolski 7½, Pazzini 7½, M'Vila 7, Willian 6½ | | Nantes | 2 | 70 Koscielny, 88 Gomis |
| | (3-4-3): Mandanda 6, Kaboul 7, Théophile-Catherine 7½, Toulalan 7½, Gonalons 7, Koscielny 6½, Debuchy 8½, Payet 7½, Gomis 7, Sissoko 6, Gouffran 6 | | Galatasaray | 1 | 85 Caner | | Half-time: | 0-1 | | Referee: | Vítor Pereira 6½ | | Attendance: | 23,766 | | Possession: | 50%-50% | | Total shots: | 11-11 | | MoM: | Ugur |
| | 4 Spahic, 22 Deco, 73 Mehmet | | (4-3-3): Mondragón 6½, Neill 7, Caner 6½, Mehmet 6½, Spahic 6½ (67 Ugur 8), Semih 6, Mustafa 7, Arda 6½, Llorente 7, Deco 6, Halil 6½ | | Genoa | 2 | 43 Criscito, 69 Jankovic | | 24 Palacio | | (4-3-3): Landreau 6½, Nagatomo 7½, Criscito 7½, Kharja 6½, André Dias 7 (48 Bogliacino 7), Onuoha 6½, Rossi 7, Jankovic 7, Acquafresca 6½, Zapater 6½, Palacio 6½ | | Hajduk Split | 0 |
| | Half-time: | 0-1 | | Referee: | Dean 6 | | Attendance: | 34,989 | | Possession: | 52%-48% | | Total shots: | 12-16 | | MoM: | Cernat | | TV: | highlights |
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| | (4-3-3): Tomic 6, Oremus 7, Seric 7½, Cernat 8, Buljat 6½, Smoje 6, Andric 6, Ibricic 7, Vukusic 7½, Lakic 6, Sharbini 6½ | | Newcastle United | 3 | 4 Cavani, 68 Sánchez, 88 Vucinic |
| | (3-5-2): Cech 6½, Hummels 7½, Rami 7, Vidal 7½, Godín 7½, Papadopoulos 6, Sánchez 7, Hamsík 7½, Cavani 6½, Vucinic 6½, Bale 8 | | Lille | 1 | 17 Gervinho | | Half-time: | 1-0 | | Referee: | Strampe 6 | | Attendance: | 18,006 | | Possession: | 43%-57% | | Total shots: | 11-13 | | MoM: | Rosales | | TV: | live |
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| | (4-3-3): Baumann 6½, Rosales 7½, Tabanou 7½, Cabaye 7½, Dann 7, Jallet 6, Gaitan 6, Gervinho 6½, Doyle 6½, Polanski 7, Diego Costa 5½ | | Shakhtar | 2 | 49 Albelda, 63 Alex |
| | (4-3-3): Khudzhamov 6½, Ilsinho 7½, Shevchuk 7½, Fernandinho 6½, Hübschman 7½, Kucher 7, Hai 7 (64 Chyzhov 7), Alex 7½, Luiz Adriano 7, Albelda 6½, Piquionne 6½ | | Panathinaikos | 2 | 20 Jozefzoon, 29 Luizão | | Half-time: | 2-0 | | Referee: | Deary 6½ | | Attendance: | 40,589 | | Possession: | 49%-51% | | Total shots: | 18-10 | | MoM: | Luizão |
| | 90+1 Mancini | | (4-3-3): Benaglio 7, Mário Fernandes 7, Coentrão 8, M'Bia 8, Luizão 8, Cris 7, Jozefzoon 6½, Mancini 7, Vellios 6, Illarramendi 6 (85 Xhaka 6), Raúl 6½ | | FC Porto | 1 | 58 Babel |
| | (4-3-3): Volkan 7, Bruno Alves 6½, Bridge 6½, Zokora 8, Coda 7½, Benayoun 6, Belluschi 6½, Babel 7½, Falcao 7, Rodríguez 5½, Pepe 7 | | Udinese | 1 | 69 Isla | | Half-time: | 0-2 | | Referee: | Rodomonti 5 | | Attendance: | 30,726 | | Possession: | 48%-52% | | Total shots: | 10-17 | | MoM: | Diarra |
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| | (4-3-3): Handanovic 7, Isla 7, Lukovic 7½, Diarra 8, Perea 6, Léo 6½, Coleman 6, Asamoah 7½, Alex Geijo 6½, Lodi 6½, Dindane 5½ | | AZ | 2 | 6 Mavuba, 22 Duff | | 42 Deola, 62 Jones | | (4-3-3): Deola 6, Husev 7½, Tiendalli 6½, Mavuba 8, Moreno 7½, Heitinga 7, Janssen 6½, Duff 7½, Jones 6½ (85 N'Zogbia 6), Brama 6½, Guðmundsson 5½ | | VfL Wolfsburg | 6 | 8 Grafite, 19 Gentner, 34 Gentner, 50 Misimovic, 68 Salpigidis, 74 Geromel | | Half-time: | 3-1 | | Referee: | López Nieto 7 | | Attendance: | 29,912 | | Possession: | 59%-41% | | Total shots: | 14-7 | | MoM: | Grafite |
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| | (4-3-3): Roef 5, Riether 7, Schäfer 6½, Misimovic 7, Geromel 7, Madlung 6½, Hasebe 7, Gentner 7, Grafite 7½, Santana 4 (79 Johnson 6), Salpigidis 7 | | Roma | 3 | 11og Schäfer, 47 Kagawa, 57p Løvenkrands | | 15 Rossi, 70 Coloccini | | (4-3-3): Barli 5½, Kalas 6½, Riise 6 (71 Noboa 6), Gago 7, Coloccini 6½, Coates 6, Kranjcar 6½, Kagawa 6, Løvenkrands 6, Pizarro 6, Rossi 6 | | Round 3 | | Hajduk Split | 1 | 31 Ibricic | | Half-time: | 1-0 | | Referee: | Boggi 7 | | Attendance: | 34,572 | | Possession: | 51%-49% | | Total shots: | 13-18 | | MoM: | Seric |
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| | (4-3-3): Tomic 5½, Oremus 7½, Seric 7½, Cernat 7, Buljat 7, Smoje 6½, Andric 7, Ibricic 7, Vukusic 7½, Lakic 6½, Sharbini 6 | | AZ | 3 | 61 Husev, 69 Tiendalli, 74 Duff |
| | (4-3-3): Deola 6, Husev 7½, Tiendalli 7½, Mavuba 7, Moreno 6½, Heitinga 6½, Janssen 6½, Duff 7, Jones 6½ (85 N'Zogbia 6), Brama 7, Guðmundsson 6 |
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