(1-0 Villarreal)| 11¹ | TOTTI made space on the left and touched the ball to DAWSON who clipped the ball wide. |
| 13¹ | MATA cautioned by the referee. |
| 22¹ | A wonderful save prevented BADELJ from scoring a good goal. |
| 24¹ | A fine piece of skill was ended by a good save by the oncoming Villarreal 'keeper. |
| 25¹ | HLEB was put clear by DAWSON and he pulled away from REINA but struck his shot wide. |
| 27¹ | A penalty box scramble resulted in HULK cracking a low shot over. |
| 34¹ | A poor shot from DAWSON bounced agonisingly wide. |
| 43¹ | An exceptional shot from LUCAS was dealt with by a good block from the Villarreal 'keeper. |
| 0² | TOTTI booked. |
| 1² | LUCAS booked for a cynical challenge. |
| 7² | TOTTI rattled an easy chance past the lefthand post. |
| 13² | PERROTTA drove a deadly shot just wide from thirty yards out. |
| 17² | GOAL!! A deep cross by JONES was met by MATA who charged in to score. (1-1)| 20² | DERDIYOK fired the ball through a ruck of players but the Liverpool 'keeper was a match for it as he dived to his right. | | 30² | A free-kick from SKRTEL went over the bar. | | 31² | A good ball from MARCELO on the right fell to MATA who scuffed his shot wide. | | 32² | MASCHERANO chipped the ball to MATA who touched it over the bar. | | 34² | The 'keeper dived to his left to save an accurate shot from Villarreal's HLEB. | | 38² | JONES sent off. | |