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| Round 1 (22) Ajax - Roma Bayern München - Sassuolo Benfica - Napoli Celta Vigo - TSG Hoffenheim Flamengo - Barcelona Inter - FC Utrecht Kaiserslautern - Milan Manchester City - Independiente Real Madrid - Aston Villa Shakhtar - Palmeiras Torino - Fiorentina | Round 2 (23) Aston Villa - Inter Barcelona - Shakhtar FC Utrecht - Celta Vigo Fiorentina - Benfica Independiente - Ajax Milan - Real Madrid Napoli - Bayern München Palmeiras - Kaiserslautern Roma - Manchester City Sassuolo - Torino TSG Hoffenheim - Flamengo |
| Round 3 (24) Ajax - TSG Hoffenheim Bayern München - FC Utrecht Benfica - Barcelona Celta Vigo - Aston Villa Flamengo - Fiorentina Inter - Milan Kaiserslautern - Independiente Manchester City - Napoli Real Madrid - Palmeiras Shakhtar - Sassuolo Torino - Roma | Round 4 (25) Aston Villa - Shakhtar Barcelona - Bayern München FC Utrecht - Kaiserslautern Fiorentina - Ajax Independiente - Benfica Milan - Flamengo Napoli - Torino Palmeiras - Celta Vigo Roma - Real Madrid Sassuolo - Inter TSG Hoffenheim - Manchester City |
| Round 5 (26) Ajax - Sassuolo Bayern München - Aston Villa Benfica - TSG Hoffenheim Celta Vigo - Milan Flamengo - FC Utrecht Inter - Independiente Kaiserslautern - Napoli Manchester City - Barcelona Real Madrid - Fiorentina Shakhtar - Roma Torino - Palmeiras | Round 6 (27) Ajax - Benfica Aston Villa - Palmeiras Barcelona - Sassuolo Bayern München - Celta Vigo Inter - Real Madrid Kaiserslautern - Roma Milan - FC Utrecht Napoli - Independiente Shakhtar - Flamengo TSG Hoffenheim - Fiorentina Torino - Manchester City |
| Round 7 (28) Benfica - Torino Celta Vigo - Shakhtar FC Utrecht - Aston Villa Fiorentina - Kaiserslautern Flamengo - Inter Independiente - Barcelona Manchester City - Ajax Palmeiras - Milan Real Madrid - Bayern München Roma - Napoli Sassuolo - TSG Hoffenheim | Round 8 (29) Ajax - Torino Fiorentina - Sassuolo Flamengo - Bayern München Independiente - Roma Kaiserslautern - Real Madrid Manchester City - Celta Vigo Milan - Aston Villa Napoli - FC Utrecht Palmeiras - Benfica Shakhtar - Inter TSG Hoffenheim - Barcelona |
| Round 9 (30) Aston Villa - Napoli Barcelona - Fiorentina Bayern München - Shakhtar Benfica - Manchester City Celta Vigo - Flamengo FC Utrecht - Palmeiras Inter - Kaiserslautern Real Madrid - Ajax Roma - Milan Sassuolo - Independiente Torino - TSG Hoffenheim | Round 10 (31) Ajax - Flamengo Barcelona - Real Madrid Benfica - Shakhtar Fiorentina - Palmeiras Independiente - Aston Villa Manchester City - Inter Napoli - Milan Roma - Celta Vigo Sassuolo - FC Utrecht TSG Hoffenheim - Kaiserslautern Torino - Bayern München |
| Round 11 (32) Aston Villa - Sassuolo Bayern München - Benfica Celta Vigo - Torino FC Utrecht - Barcelona Flamengo - Roma Inter - Fiorentina Kaiserslautern - Manchester City Milan - Ajax Palmeiras - Independiente Real Madrid - TSG Hoffenheim Shakhtar - Napoli | Round 12 (33) Aston Villa - Fiorentina Bayern München - Ajax Celta Vigo - Benfica FC Utrecht - TSG Hoffenheim Flamengo - Independiente Inter - Roma Kaiserslautern - Barcelona Milan - Manchester City Palmeiras - Sassuolo Real Madrid - Napoli Shakhtar - Torino |
| Round 13 (34) Ajax - Celta Vigo Barcelona - Milan Benfica - Kaiserslautern Fiorentina - FC Utrecht Independiente - Bayern München Manchester City - Shakhtar Napoli - Flamengo Roma - Palmeiras Sassuolo - Real Madrid TSG Hoffenheim - Aston Villa Torino - Inter | Round 14 (35) Aston Villa - Roma Bayern München - Fiorentina Celta Vigo - Napoli FC Utrecht - Manchester City Flamengo - Benfica Inter - Barcelona Kaiserslautern - Ajax Milan - Sassuolo Palmeiras - TSG Hoffenheim Real Madrid - Torino Shakhtar - Independiente |
| Round 15 (36) Ajax - Shakhtar Barcelona - Aston Villa Benfica - Real Madrid Fiorentina - Milan Independiente - Celta Vigo Manchester City - Bayern München Napoli - Palmeiras Roma - FC Utrecht Sassuolo - Kaiserslautern TSG Hoffenheim - Inter Torino - Flamengo | Round 16 (37) Aston Villa - Ajax Bayern München - Roma Celta Vigo - Sassuolo FC Utrecht - Benfica Flamengo - Manchester City Inter - Napoli Kaiserslautern - Torino Milan - TSG Hoffenheim Palmeiras - Barcelona Real Madrid - Independiente Shakhtar - Fiorentina |
| Round 17 (38) Ajax - Napoli Bayern München - Milan Benfica - Roma Celta Vigo - Barcelona Flamengo - Sassuolo Inter - Palmeiras Kaiserslautern - Aston Villa Manchester City - Fiorentina Real Madrid - FC Utrecht Shakhtar - TSG Hoffenheim Torino - Independiente | Round 18 (39) Ajax - Inter Bayern München - Kaiserslautern Benfica - Sassuolo Celta Vigo - Fiorentina Flamengo - Palmeiras Independiente - Milan Manchester City - Real Madrid Napoli - Barcelona Roma - TSG Hoffenheim Shakhtar - FC Utrecht Torino - Aston Villa |
| Round 19 (40) Aston Villa - Flamengo Barcelona - Roma FC Utrecht - Independiente Fiorentina - Napoli Inter - Benfica Kaiserslautern - Shakhtar Milan - Torino Palmeiras - Ajax Real Madrid - Celta Vigo Sassuolo - Manchester City TSG Hoffenheim - Bayern München | Round 20 (41) Ajax - FC Utrecht Bayern München - Inter Benfica - Aston Villa Celta Vigo - Kaiserslautern Flamengo - Real Madrid Independiente - TSG Hoffenheim Manchester City - Palmeiras Napoli - Sassuolo Roma - Fiorentina Shakhtar - Milan Torino - Barcelona |
| Round 21 (42) Aston Villa - Manchester City Barcelona - Ajax FC Utrecht - Torino Fiorentina - Independiente Inter - Celta Vigo Kaiserslautern - Flamengo Milan - Benfica Palmeiras - Bayern München Real Madrid - Shakhtar Sassuolo - Roma TSG Hoffenheim - Napoli | |
| League rounds 22-42 (in brackets) are the respective return ties of rounds 1-21 above, i.e. round 42 is Ajax - Barcelona, Bayern München - Palmeiras etc. | |