| Round 1 | | Anderlecht | 2 | 60 Vlcek, 83 Ambrosini | | Half-time: | 0-0 | | Referee: | Brignoccoli 6½ | | Attendance: | 28,992 | | Possession: | 53%-47% | | Total shots: | 18-6 | | MoM: | Hélton | | TV: | live |
| | 36 Vlcek | | (4-3-3): Niemi 7½, Smith 7½, Vermaelen 7, Sirieix 8, Ignashevich 7, Dheedene 6½, Vlcek 7½, Ambrosini 6½, Lange 6 (60 Mansouri 7), Farías 6½, Luis García 7 | | Boca Juniors | 0 |
| | 23 Ravenhill, 34 Ponzio | | (4-3-3): Hélton 8, Salihamidzic 7½, Léo 7½, Ravenhill 6½, Quiroga 6½, Méndez 7½, Ponzio 6½, Romeo 6, Cruz 7 (85 Momentè 6), Delgado 6, López 7 | | Benfica | 0 |
| | Half-time: | 0-0 | | Referee: | Cardona 6½ | | Attendance: | 39,722 | | Possession: | 50%-50% | | Total shots: | 8-10 | | MoM: | Antzas |
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| | (4-3-3): Cavallero 6½, Caneira 7, Sorín 7½, Titov 7, Tonel 7 (56 César Prates 6½), Ronaldo 6, Scaloni 6½, Tello 7, Urzaiz 6½, Petre 6½ (80 Aduobe 6), Cafú 5½ | | Olympiakos | 2 | 47 Palermo, 83 Djordjevic | | 37 Palermo, 45+1 Gitas, 70 Ephraim | | (4-3-3): Tochouroglou 6, Torosidis 7 (62 Choutos 7), Seric 6½, Gitas 7, Antzas 8, Kostoulas 7, Giannakopoulos 6½, Djordjevic 7½, Palermo 6½, Nuñez 6, Ephraim 6 | | Bologna | 3 | 8 Diana, 10 Pandev, 86 Pandev | | Half-time: | 2-0 | | Referee: | Ceccarini 6 | | Attendance: | 40,397 | | Possession: | 59%-41% | | Total shots: | 11-10 | | MoM: | Pandev |
| | 42 Diana | | (4-3-3): Roma 7, Diana 7 (84 Marcinho 6), Tonetto 7, Faé 5½ (69 Falcone 8), Gamberini 7, Paganin 6½, Luciano 7, Pandev 8, Lodi 6½, Firmani 6½, Pacheco 5½ | | Hertha BSC Berlin | 1 | 73 Queudrue | | 31 Trochowski, 45 Kuffour, 76 Rafael, 84 Balitsch | | (4-3-3): Moreira 6½, O'Shea 6½, Queudrue 7½, Makélélé 7½, Callsen-Bracker 6, Kuffour 6½, Balitsch 7, Trochowski 6½, Rafael 6, Sergio 6, López 5½ | | Club Brugge | 1 | 85 Meert | | Half-time: | 0-2 | | Referee: | Díaz Vega 5½ | | Attendance: | 18,151 | | Possession: | 46%-54% | | Total shots: | 12-13 | | MoM: | Lichtsteiner | | TV: | highlights |
| | 34 Jorginho, 41 Polák, 76 Clement | | (4-3-3): Postulka 6, Hoefkens 6½, Lembi 6½ (79 El Said 6), Jorginho 6½, Clement 7½, Tarozzi 6, Polák 7, Meert 6½, Sonck 7, Buffel 6, Brogno 6 | | Auxerre | 2 | 21 Kapo, 38 Luyindula |
| | (4-3-3): Butelle 6, Lichtsteiner 7½, Song 7, Ibagaza 7, Dellas 7½, Medjani 7 (64 Soetaers 6), Smertin 7, Kapo 7, Luyindula 7, Berson 7, Frau 6 | | Dinamo Zagreb | 0 |
| | Half-time: | 0-1 | | Referee: | Valkmar 6½ | | Attendance: | 39,435 | | Possession: | 51%-49% | | Total shots: | 11-20 | | MoM: | King | | TV: | highlights |
| | 13 Tokic, 36 Akalé | | (4-3-3): Vasilj 7, Sedloski 7½, Cale 7, Townsley 6½, Tomas 7½, Tokic 7, Mikic 7, Akalé 6½, Giovanni 7½, Gondzic 5½, Seol 6 | | West Ham United | 1 | 9 Kepa | | 3 King, 4 Kepa, 54 Ambrose, 70 Jarque | | (4-3-3): Ramé 7, Taylor 6½, Maxwell 6 (84 Kluivert 6), King 8, Jarque 7, Ooijer 6, Galásek 6½, Ambrose 6, Kepa 7, Daugaard 6½, Youla 6½ | | Mallorca | 2 | 35 Iachtchouk, 87 Iachtchouk | | Half-time: | 1-1 | | Referee: | Stafoggia 6 | | Attendance: | 24,923 | | Possession: | 45%-55% | | Total shots: | 12-16 | | MoM: | Nesmachnyi |
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| | (4-3-3): Leo Franco 6, Vintra 6½ (83 Amaya 6), Capdevila 7, Arzu 7, Hüseyin 6½, Josemi 6½, Joaquín 7, Vicente 6 (83 Murat 6), Iachtchouk 7, Serrano 6, Tchite 6 | | Feyenoord | 3 | 35 Giménez, 83 Castelen, 89 Cissé |
| | (4-3-3): Penneteau 6½, Boulahrouz 8, Nesmachnyi 8½, Källström 7½, Boumsong 6½, Kruiswijk 5, Castelen 7, Giménez 7, Cissé 7, Tomasson 7 (83 Rafael Sobis 6), Farnerud 6 | | Manchester United | 2 | 9 Saha, 69 Saha | | Half-time: | 1-0 | | Referee: | Quartuccio 6 | | Attendance: | 49,441 | | Possession: | 50%-50% | | Total shots: | 12-9 | | MoM: | Guti |
| | 75 Bozovic | | (4-3-3): Bozovic 6, Neville 8½, Bridge 7, Ernst 8, Bassong 6, Michel Salgado 6, Anita 6, Petrov 6½, Saha 7½, Cavenaghi 6½, Johnson 6½ | | Celta Vigo | 1 | 51 Adem |
| | (4-3-3): Almunia 6½, Neville 7½, Fernando 7, Guti 8½, Murillo 6½, Contra 5½, Víctor 6½, Adem 6, Morientes 7, Tamudo 5½, Hasan 6½ (69 Marcos 6½) | | Middlesbrough | 3 | 3 Park, 24 Bellucci, 76 Renan | |
| | (4-3-3): Carson 6½, Brown 8, Higginbotham 7, Jônatas 7½, Marcelo Mattos 8, Mulgrew 7, Bratu 7½, Park 7, Bellucci 7, Renan 6, Giménez 6 | | SV Werder Bremen | 2 | 22 Klasnic, 89 Amanatidis | | 47 Friedrich, 52 Magnin | | (4-3-3): Walke 6, Stalteri 7, Magnin 7½, Manuel Fernandes 7, Friedrich 7 (71 Säumel 7), Dogan 6, Varela 6½ (49 Blank 6½), Cani 7, Amanatidis 6, Gomez 6½, Klasnic 6½ | | Milan | 2 | 36 Woodgate, 85 Emre | | Half-time: | 1-2 | | Referee: | Rodomonti 6½ | | Attendance: | 53,472 | | Possession: | 47%-53% | | Total shots: | 9-12 | | MoM: | Emre |
| | 19 Emre, 90+1 Rodríguez | | (4-3-3): Howard 6, Rodríguez 7, Del Horno 6, Kovac 7, Materazzi 7½, Woodgate 6½, Izmailov 6, Emre 7½, Kuranyi 6 (61 Mpenza 7), Pandiani 7 (75 Hofland 6), Kezman 6½ | | Borussia Mönchengladbach | 3 | 24 Misimovic, 28 Róbson Ponte, 59 Róbson Ponte | | 85 Fukal | | (4-3-3): Pröll 6, Fukal 6, Pander 7½, De Ascentis 7½, Svensson 6½, Strasser 7, Róbson Ponte 7½, Misimovic 7, Kahê 6½, Kluge 6, Neuville 5½ | | Rosenborg | 2 | 14og Warnock, 20 Carew | | Half-time: | 2-0 | | Referee: | Rosica 7½ | | Attendance: | 39,891 | | Possession: | 44%-56% | | Total shots: | 9-11 | | MoM: | Laursen | | TV: | highlights |
| | 55 Hangeland | | (4-3-3): Sørensen 7½, Krøldrup 6 (67 Albrechtsen 7), Cagara 7½, Poulsen 7½, Laursen 8, Hangeland 6½, Nilsson 6, Jørgensen 7, Carew 7, Elmander 7, Pedersen 5½ | | Bolton Wanderers | 0 |
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| | (4-3-3): Green 8, Hunt 7½, Warnock 7, Nolan 7, Silvestre 7, Cahill 6, Benayoun 7½, Downing 7 (57 Pischorn 6½), Borgetti 6½, Gardner 6, Townson 5½ | | Sporting | 2 | 11 Alessandro, 82 Nuno Gomes | | Half-time: | 1-1 | | Referee: | Trentalange 7 | | Attendance: | 46,386 | | Possession: | 44%-56% | | Total shots: | 15-16 | | MoM: | Torres |
| | 34 Mantorras, 45+1 Verón, 47 Parker | | (4-3-3): Ten Rouwelaar 6, Alessandro 7½, Matteo 6 (60 O'Hara 7), Verón 7½, Bernardi 6½, Parker 5½, Arteta 6½, Óscar Pérez 6½, Nuno Gomes 6, Hélder Postiga 6, Mantorras 6 | | Ajax | 2 | 36 Sávio, 85 Makaay |
| | (4-3-3): Wapenaar 6, Torres 8, Van Bronckhorst 7½, Van Der Gun 7, Lacruz 7½, Valgaeren 6½ (69 Yakubu 6), Norris 7, Sávio 7, Arizmendi 6½, Wéldon 6, Makaay 8 | | Round 2 | | Ajax | 3 | 1 Arizmendi, 20 Arizmendi, 80 Arizmendi | | Half-time: | 2-1 | | Referee: | Benkö 7½ | | Attendance: | 41,541 | | Possession: | 55%-45% | | Total shots: | 12-12 | | MoM: | Van Bronckhorst |
| | 9 Makaay, 27 Wéldon | | (4-3-3): Wapenaar 5½, Torres 7½, Van Bronckhorst 8, Van Der Gun 7, Lacruz 6½, Valgaeren 5½ (71 Yakubu 6), Norris 7, Sávio 7, Arizmendi 7½, Wéldon 5½, Makaay 7 | | Dinamo Zagreb | 2 | 14og Valgaeren, 70 Seol | | 29 Seol | | (1-3-3-3): Vasilj 6, Sedloski 7, Cale 6 (80 Giovanni 7½), Townsley 6½, Tomas 7, Tokic 7, Mikic 7, Seol 7, Socrier 6, Gondzic 5½, Akalé 6 | | Auxerre | 1 | 55 Luyindula | | Half-time: | 0-1 | | Referee: | Blareau 7 | | Attendance: | 40,375 | | Possession: | 56%-44% | | Total shots: | 11-11 | | MoM: | Ibagaza |
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| | (4-3-3): Butelle 7½, Lichtsteiner 7½, Song 7½, Ibagaza 8, Dellas 7½, Medjani 6½, Smertin 6½ (55 Dja Djedje 7½), Kapo 7½, Luyindula 7, Berson 6½, Frau 7 | | Middlesbrough | 1 | 19 Park | | 79 Park | | (4-3-3): Carson 7½, Brown 6½, Higginbotham 7½, Jônatas 7, Marcelo Mattos 7, Mulgrew 6, Bratu 6½, Park 7, Bellucci 6½, Renan 6, Giménez 6 | | Borussia Mönchengladbach | 1 | 33 Róbson Ponte | | Half-time: | 1-0 | | Referee: | Angelov 7½ | | Attendance: | 45,760 | | Possession: | 51%-49% | | Total shots: | 17-20 | | MoM: | Poulsen |
| | 77 Kahê | | (4-3-3): Pröll 6, Fukal 6½, Pander 7, De Ascentis 7, Svensson 7, Strasser 7, Róbson Ponte 7½, Misimovic 7, Kahê 5½, Kluge 6½, Neuville 6 | | Rosenborg | 1 | 49 Jørgensen |
| | (4-3-3): Sørensen 7, Krøldrup 7½, Cagara 6½, Poulsen 8, Laursen 7, Hangeland 6½, Nilsson 7, Jørgensen 7, Carew 6, Elmander 6½, Pedersen 6 | | Boca Juniors | 2 | 5 Quiroga, 67 Cruz | | Half-time: | 1-0 | | Referee: | Sars 5 | | Attendance: | 38,262 | | Possession: | 43%-57% | | Total shots: | 8-15 | | MoM: | Nuno Gomes |
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| | (4-3-3): Hélton 6½, Salihamidzic 7, Léo 6½, Ravenhill 6 (74 Muzzi 6), Quiroga 6, Méndez 7, Ponzio 7½, Romeo 5½, Cruz 7, Delgado 6½, López 6½ (84 Rooney 6) | | Sporting | 0 |
| | 51 Hélder Postiga | | (4-3-3): Ten Rouwelaar 8, Alessandro 7½, Matteo 6, Verón 7, Bernardi 7, Parker 6, Arteta 7½, Óscar Pérez 6, Nuno Gomes 8, Hélder Postiga 7, Mantorras 7 | | Bolton Wanderers | 2 | 25 Downing, 72 Downing | | Half-time: | 1-0 | | Referee: | Veiga Trigo 8 | | Attendance: | 27,694 | | Possession: | 43%-57% | | Total shots: | 10-17 | | MoM: | Bridge |
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| | (4-3-3): Green 8, Hunt 7, Warnock 6½, Nolan 8, Silvestre 7½, Cahill 6, Benayoun 7, Downing 7, Borgetti 6 (62 Walters 6), Gardner 5½, Townson 5½ | | Manchester United | 0 |
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| | (4-3-3): Bozovic 8, Neville 7, Bridge 8, Ernst 8, Bassong 7, Michel Salgado 6½, Anita 7, Petrov 7, Saha 7, Pizarro 5½, Johnson 6½ | | Celta Vigo | 1 | 20 Morientes | | Half-time: | 1-1 | | Referee: | Sundell 5 | | Attendance: | 32,687 | | Possession: | 54%-46% | | Total shots: | 11-10 | | MoM: | Fernando |
| | 73 Almunia | | (4-3-3): Almunia 6½, Neville 6, Fernando 8, Guti 7½, Murillo 7, Contra 6½, Víctor 7, Adem 6½, Morientes 7½, Tamudo 6, Hasan 7 | | Bologna | 1 | 36 Pandev |
| | (4-3-3): Roma 6½, Diana 7½, Tonetto 6½, Faé 6½, Gamberini 7½, Paganin 6½, Luciano 7, Pandev 7½, Lodi 7, Firmani 6½ (71 Dal Canto 7), Pacheco 6 | | Feyenoord | 4 | 11 Cissé, 54 Boulahrouz, 70 Giménez, 79 Cissé | | Half-time: | 1-0 | | Referee: | Meese 6½ | | Attendance: | 48,346 | | Possession: | 54%-46% | | Total shots: | 15-13 | | MoM: | Titov |
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| | (4-3-3): Penneteau 7½, Boulahrouz 7½, Nesmachnyi 8, Källström 8, Boumsong 6, Kruiswijk 6½, Castelen 7, Giménez 7½, Cissé 7, Tomasson 5 (74 Rafael Sobis 6), Farnerud 7 | | Benfica | 0 |
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| | (4-3-3): Cavallero 7, Caneira 6, Sorín 7½, Titov 8, Tonel 6½ (56 César Prates 6½), Ronaldo 6, Scaloni 6½, Tello 6½, Urzaiz 7, Petre 7 (80 Aduobe 6), Cafú 5½ | | Hertha BSC Berlin | 0 |
| | Half-time: | 0-0 | | Referee: | Piraux 7 | | Attendance: | 43,019 | | Possession: | 56%-44% | | Total shots: | 16-13 | | MoM: | O'Shea |
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| | (4-3-3): Moreira 7½, O'Shea 8, Queudrue 7, Makélélé 7½, Callsen-Bracker 6½, Kuffour 5½, Balitsch 7½, Trochowski 6½, Hanke 6, Sergio 7, Vorobyei 7 | | Mallorca | 0 |
| | 90 Iachtchouk | | (4-3-3): Leo Franco 7, Vintra 7, Capdevila 7½, Arzu 7, Hüseyin 6½, Josemi 5½, Joaquín 7, Vicente 7, Iachtchouk 6½, Serrano 5½, Tchite 6 | | Olympiakos | 1 | 39 Gitas | | Half-time: | 1-2 | | Referee: | Sandra 6 | | Attendance: | 33,996 | | Possession: | 44%-56% | | Total shots: | 12-22 | | MoM: | Torosidis |
| | 15 Gitas, 45 Ephraim, 45+2 Palermo, 52 Kostoulas | | (4-3-3): Tochouroglou 6, Torosidis 8½, Seric 6½, Gitas 6, Antzas 6½, Kostoulas 6, Giannakopoulos 6, Djordjevic 7, Palermo 7, Nuñez 5, Ephraim 5½ | | Milan | 2 | 2 Del Horno, 43 Emre | | 10 Kovac, 21 Kuranyi | | (4-3-3): Howard 7, Rodríguez 8, Del Horno 8, Kovac 7½, Materazzi 7, Woodgate 7, Izmailov 6½, Emre 6½ (66 Cannavaro 7), Kuranyi 6, Pandiani 6½, Kezman 6 | | SV Werder Bremen | 0 |
| | Half-time: | 0-1 | | Referee: | Bogdanov 7½ | | Attendance: | 35,111 | | Possession: | 49%-51% | | Total shots: | 14-12 | | MoM: | Jorginho |
| | 77 Dogan, 88 Klasnic | | (4-3-3): Walke 7, Stalteri 7½, Magnin 7½, Manuel Fernandes 8, Friedrich 6½, Dogan 6, Varela 6½, Cani 6½, Amanatidis 7, Gomez 7 (65 Säumel 6), Klasnic 6 | | Club Brugge | 1 | 29 Buffel |
| | (4-3-3): Postulka 6½, Hoefkens 6½, Vandooren 6½, Jorginho 8, Clement 7½, Lembi 6½, Polák 6½, Meert 7, Sonck 7, Buffel 6½, Brogno 5½ | | West Ham United | 1 | 31 Maxwell | | Half-time: | 1-0 | | Referee: | Momirov 6 | | Attendance: | 25,924 | | Possession: | 42%-58% | | Total shots: | 17-13 | | MoM: | Maxwell |
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| | (4-3-3): Ramé 6½, Taylor 6½ (72 Rodriguez 6), Maxwell 8, King 7½, Jarque 6½, Ooijer 6, Galásek 6½, Ambrose 7, Kepa 6, Daugaard 6½ (65 Kluivert 6), Youla 6½ | | Anderlecht | 2 | 58p Peeters, 90+2 Ambrosini |
| | (4-3-3): Niemi 6½, Smith 7½, Vermaelen 7, Sirieix 7 (52 Mansouri 8½), Ignashevich 6½, Dheedene 7, Vlcek 7½, Ambrosini 6½, Lange 6½ (51 Peeters 6½), Farías 7, Luis García 6 |
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