| Round 1 | | Atlético Madrid | 3 | 14 Varela, 61 Nuñez, 72 Edú | | Half-time: | 1-0 | | Referee: | Brych 5½ | | Attendance: | 44,080 | | Possession: | 49%-51% | | Total shots: | 15-10 | | MoM: | Kovac | | TV: | live |
| | 89 Dorado | | (4-3-3): Toño 6½, Varela 6½, Dorado 5, Zapater 7, Diogo 8, Gaspar 6½ (80 Gustavo 6), Javi García 7½, Nuñez 5½ (71 Maínz 7), Fábio Júnior 6½, Rossato 6½, Edú 7½ | | Kaiserslautern | 1 | 53 Kruska | | 1 Reuter | | (1-3-4-2): Lehmann 6½, Owomoyela 7½, Müller 6, Kruska 7½, Yelen 6½, Ümit 6½, Kovac 8, Pimenov 7, Pettersson 6, Reuter 5½, Yakin 7 | | Bayer Leverkusen | 2 | 2 Kiessling, 4 Barnetta | | Half-time: | 2-1 | | Referee: | Durkin 5 | | Attendance: | 22,394 | | Possession: | 56%-44% | | Total shots: | 19-8 | | MoM: | Schwegler |
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| | (4-3-3): Bossio 6½, Castro 6½, Gresko 6½, Rolfes 7, Haggui 6½, Sinkiewicz 5½, Frings 8, Barnetta 7½, Kiessling 8, Schwegler 8, Bulykin 6½ | | Lyon | 2 | 24 Piquionne, 54 Oruma | | 43 Idangar | | (4-3-3): Vercoutre 6, Clerc 7, Cesar 7, Cana 7, Modesto 6½, Faty 6, Oruma 7, Idangar 5½, Piquionne 6½, Maoulida 5½, Giménez 7½ | | Blackburn Rovers | 0 |
| | Half-time: | 0-1 | | Referee: | Raquet 5 | | Attendance: | 31,259 | | Possession: | 47%-53% | | Total shots: | 11-10 | | MoM: | Savage | | TV: | highlights |
| | 30 Nelsen | | (4-3-3): Friedel 6½, Emerton 7, Taylor 8, Savage 8½, Samba 7, Nelsen 6, Reid 6½, Peter 7, Roberts 7, Mokoena 6½, Derbyshire 5½ | | Galatasaray | 1 | 10 Gökdeniz |
| | (4-3-3): Berti 7, Alvarez 7, Ergün 7, Mladenov 7, Randrup 6½, Emrah 6½, Okan 7½, Gökdeniz 6½, Semih 7 (58 Sergen 6½), Delporte 5½, Niyazi Serhat 5½ | | Bordeaux | 1 | 42 Ledesma | | Half-time: | 1-1 | | Referee: | Winkler 8 | | Attendance: | 38,199 | | Possession: | 47%-53% | | Total shots: | 15-8 | | MoM: | Stendardo |
| | 45 Zapata, 81 Lachor | | (4-3-3): Richert 6½, Fanni 6½ (72 Lachor 7½), Cufré 7½, Zapata 7½, Planus 6½, Maietta 6, Black 6½, Ledesma 7, Ferri 6, Legwinski 7, Batllès 7 | | Napoli | 1 | 15 Warley |
| | (4-3-3): Cudicini 6½, Manfredini 6½, Bertotto 7, Locatelli 7½, Stendardo 8, Zamboni 6½, Fábio Simplício 7, Bisgaard 7½, Sosa 6½, Liverani 6, Warley 6 | | Lazio | 1 | 53 Bellamy | | Half-time: | 0-1 | | Referee: | Piraux 6½ | | Attendance: | 40,143 | | Possession: | 56%-44% | | Total shots: | 11-11 | | MoM: | Grosso | | TV: | highlights |
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| | (4-3-3): Mondragón 6½, Leonardo Moura 7½, Grosso 8, Zanetti 7½, Luizão 7, Vranjes 6, Almirón 7, Felipe 7, Bellamy 7½, Paro 6½, Frei 5½ | | FC Schalke 04 | 1 | 15p Charisteas |
| | (4-3-3): Schober 7½, Fritz 7, Simunic 7½, Lincoln 7½, Van Kerckhoven 6½, Alex 6, Gentner 7, Hajnal 7, Charisteas 7, Lokvenc 6, Halil 6½ | | Metz | 3 | 6 Keita, 30 Keita, 34p Jestrovic | | Half-time: | 3-1 | | Referee: | Merk 7 | | Attendance: | 27,923 | | Possession: | 51%-49% | | Total shots: | 13-8 | | MoM: | Jestrovic |
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| | (4-3-3): Levitskyi 6, Pichot 7, Wendell 7½, Proment 7½, Rozehnal 7, Grichting 6, Bastien 7, Keita 7, Jestrovic 8, Aliadière 5½, Baros 7 | | FK Austria | 2 | 10 Janocko, 62 Dospel |
| | (4-3-3): Didulica 6½, Dospel 6½, Troyanski 7, Kiesenebner 6½, Antonsson 6½ (77 Vachousek 6), Hill 6, Sionko 6½, Mila 6, Linz 7, Janocko 7, Rushfeldt 7 (83 Lasnik 6) | | Panathinaikos | 3 | 24 Karagounis, 49 Iarley, 54 Llorente | | Half-time: | 1-0 | | Referee: | Dallas 6 | | Attendance: | 43,800 | | Possession: | 46%-54% | | Total shots: | 14-11 | | MoM: | Belletti |
| | 20 Basinas, 37 Llorente, 73 Domizzi | | (4-3-3): Nikopolidis 6, Serrizuela 6, Domizzi 7, Karagounis 7½, Goumas 6½, Van Boxel 5½, Belluschi 6½, Basinas 7½, Llorente 6, Iarley 7, Villa 5½ | | Flamengo | 2 | 70 Braaten, 89 Belletti |
| | (4-3-3): Vermeer 6, Belletti 8, Fathi 7, Edu 8, Ânderson Polga 7½, Sala 6½, Watson 7, Marcelinho 7, Braaten 7½, Júnior 5½, Adúriz 6 | | Racing Santander | 2 | 6 Iriney, 75 Iriney | | Half-time: | 1-2 | | Referee: | Vad 5½ | | Attendance: | 22,084 | | Possession: | 48%-52% | | Total shots: | 12-15 | | MoM: | Barton |
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| | (4-3-3): Itandje 6, Pinillos 6½, Neru 7, Felipe Melo 6½, Oriol 6½, Rubén 6, Balboa 8, Iriney 6, Zigic 7, Colsa 7, Rubén 6 | | Trabzonspor | 2 | 31 Loskov, 39 Alex |
| | (4-3-3): Fevzi 6½, Ali Eren 7, Fábio Aurélio 7½, Barton 8, Ufuk 6½, Gustavo Nery Sá 6, Ayhan 7, Alex 6½ (53 Yasin 6½), Necati 7½, Loskov 7, Ereros 6 | | Real Betis | 1 | 50 Gutiérrez | | Half-time: | 0-2 | | Referee: | Wieser 7½ | | Attendance: | 41,831 | | Possession: | 44%-56% | | Total shots: | 9-20 | | MoM: | Bystrov |
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| | (4-3-3): Prats 6½, Kvarme 7½, Pasqual 5½, Karhan 7½, Marc Torrejón 6, Lequi 6, Husev 7, Gutiérrez 6½, Robert 7, Nenê 5½, Salva 6 | | Lokomotiv | 2 | 13og Karhan, 42 Bystrov | | 43 Jiránek, 48 Bikey, 63 Aydin, 66 Sennikov | | (4-3-3): Gabulov 6, Jiránek 7½, Spahic 7½, Kalynychenko 7½, Bikey 6, Sennikov 7, Bystrov 8, Aydin 6½, Sychev 7, Kingston 6, Lebedenko 6 | | Roda JC | 2 | 43 Sergio, 76 Meeuwis | | Half-time: | 1-1 | | Referee: | Barry 7 | | Attendance: | 19,971 | | Possession: | 59%-41% | | Total shots: | 18-11 | | MoM: | Sergio |
| | 87 Nygaard | | (4-3-3): Volkan 7, Sonkaya 8, Lachambre 7½, Sergio 8½, Stefanovic 8, Vicelich 6, Berglund 6½, Meeuwis 7½, Nygaard 7, Sikora 6 (76 Maury 6), Hornos 6½ | | Deportivo | 1 | 7 Xisco | | 27 Giannichedda, 68 Valdo | | (4-3-3): Katergiannakis 6½, Iraola 8, José Enrique 8, Fiore 7, Ricardo Rocha 7 (76 Gurpegui 6), Prieto 6½, Marney 7, Xisco 6½, Ngalula Mbuyi 5½, Giannichedda 5½, Valdo 7 (69 Canobbio 6) | | Valencia | 0 |
| | | 3 Doni, 45 Oleguer | | (4-3-3): Palop 7½, Faubert 7, Scardina 7 (72 Morrison 7½), Fernando 7½, Oleguer 7½, Yahia 7, Gerardo 7, Doni 7½, Gekas 7½, Batista 7, Weston 5 | | Grêmio | 0 |
| | 84 Piatti | | (4-3-3): Ochoa 8, Bosingwa 6½, Roberto Carlos 8, Raul Meireles 7, Miguel Veloso 7½, Ivanovic 6½, Giovani 7, Sánchez 7½, Hladkyi 6, Marcos Assunçao 6½, Piatti 5½ | | Round 2 | | Deportivo | 1 | 62 José Enrique | | Half-time: | 0-1 | | Referee: | Riley 7 | | Attendance: | 36,795 | | Possession: | 51%-49% | | Total shots: | 13-16 | | MoM: | Iraola |
| | 46 Giannichedda | | (4-3-3): Katergiannakis 6½, Iraola 8, José Enrique 7½, Fiore 7½, Ricardo Rocha 6½ (76 Gurpegui 6), Prieto 6, Marney 6½, Xisco 7, Ngalula Mbuyi 6, Giannichedda 7, Valdo 6½ (69 Canobbio 6½) | | Racing Santander | 1 | 40 Zigic |
| | (4-3-3): Itandje 6½, Pinillos 7, Neru 7½, Felipe Melo 7, Oriol 6½, Rubén 6, Balboa 7, Iriney 6½, Zigic 7, Colsa 6, Rubén 6 | | FC Schalke 04 | 2 | 31 Charisteas, 52 Halil | |
| | (4-3-3): Schober 7, Fritz 7½, Simunic 7, Lincoln 7, Van Kerckhoven 7½, Alex 6, Gentner 7, Hajnal 8, Charisteas 6½, Lokvenc 6, Halil 7½ | | Bordeaux | 0 |
| | 25 Zapata | | (4-3-3): Richert 7½, Fanni 7½, Cufré 7, Zapata 7½, Planus 6½, Maietta 6½, Black 6, Ledesma 6, Legwinski 6, Álvarez 5½, Batllès 7 | | FK Austria | 0 |
| | Half-time: | 0-0 | | Referee: | Sedlacek 6½ | | Attendance: | 11,763 | | Possession: | 48%-52% | | Total shots: | 10-10 | | MoM: | Emerton |
| | 56 Hill | | (4-3-3): Didulica 8, Dospel 6, Troyanski 5½, Kiesenebner 7, Antonsson 6½, Hill 5½, Sionko 7, Mila 6, Linz 6½, Janocko 6½, Rushfeldt 7 | | Blackburn Rovers | 0 |
| | 61 Peter | | (4-3-3): Friedel 7½, Emerton 9, Taylor 6½, Savage 7, Samba 6, Nelsen 6, Reid 7½, Peter 6, Roberts 7½, Mokoena 6½, Derbyshire 5½ | | Flamengo | 1 | 90+2 Marcelinho | | Half-time: | 0-2 | | Referee: | Ancion 7½ | | Attendance: | 47,984 | | Possession: | 43%-57% | | Total shots: | 12-12 | | MoM: | Rolfes |
| | 13 Marcelinho, 63 Sala, 72 Edu | | (4-3-3): Vermeer 6, Belletti 8, Fathi 6, Edu 7½, Ânderson Polga 6½, Sala 7, Watson 7, Marcelinho 6½, Braaten 7, Júnior 6, Adúriz 6½ | | Bayer Leverkusen | 3 | 31og Sala, 42 Sinkiewicz, 49 Barnetta |
| | (4-3-3): Bossio 5½, Castro 6, Gresko 7½, Rolfes 8, Haggui 7, Sinkiewicz 6½, Frings 7½, Barnetta 7½, Kiessling 6½, Schwegler 6, Bulykin 7½ | | Galatasaray | 1 | 48 Semih | | Half-time: | 0-2 | | Referee: | Goethals 7 | | Attendance: | 39,858 | | Possession: | 42%-58% | | Total shots: | 12-17 | | MoM: | Luizão |
| | 59 Delporte | | (4-3-3): Berti 6½, Alvarez 7½, Ergün 6½, Mladenov 6½, Randrup 6½, Emrah 6½, Okan 7, Gökdeniz 6½, Semih 6½, Delporte 5½, Niyazi Serhat 6½ | | Lazio | 2 | 5 Almirón, 29 Grosso |
| | (4-3-3): Mondragón 6½, Leonardo Moura 6½ (71 Bayly 7½), Grosso 7½, Zanetti 7, Luizão 7½, Vranjes 7 (76 Lustenberger 6), Almirón 7½, Felipe 6½, Bellamy 7, Paro 6, Frei 6 | | Grêmio | 1 | 59 Piatti | | Half-time: | 0-1 | | Referee: | Deaconu 7 | | Attendance: | 44,607 | | Possession: | 47%-53% | | Total shots: | 16-9 | | MoM: | Roberto Carlos |
| | 71 Roberto Carlos | | (4-3-3): Ochoa 6½, Bosingwa 6½, Roberto Carlos 7½, Raul Meireles 7½, Miguel Veloso 6½, Ivanovic 6½, Giovani 6½, Sánchez 6½, Hladkyi 6, Marcos Assunçao 7, Piatti 6 | | Real Betis | 1 | 8 Gutiérrez | | 66 Lequi, 69 Salva | | (4-3-3): Prats 7, Kvarme 7½, Pasqual 7½, Karhan 7, Marc Torrejón 7½, Lequi 6, Husev 7, Gutiérrez 6½ (58 Krznar 7), Robert 6½, Nenê 6, Salva 6½ | | Kaiserslautern | 3 | 18 Yelen, 57 Yelen, 85 Pimenov | | Half-time: | 1-0 | | Referee: | Dinelli 7 | | Attendance: | 38,980 | | Possession: | 55%-45% | | Total shots: | 16-11 | | MoM: | Filipovic |
| | 39 Yakin, 49 Floro Flores | | (1-3-3-3): Lehmann 7½, Owomoyela 6½, Müller 7½, Kruska 5½ (60 Stark 8), Baránek 7, Ümit 7, Kovac 7, Pimenov 7, Floro Flores 6, Yelen 6, Yakin 6 | | Roda JC | 0 |
| | 38 Lachambre | | (4-3-3): Volkan 7½, Sonkaya 7, Filipovic 8, Sergio 7½, Stefanovic 6, Lachambre 7, Berglund 7, Meeuwis 7, Torma 6½, Sikora 5½, Cristiano 6 | | Lokomotiv | 4 | 32 Spahic, 58 Bystrov, 65 Sychev, 85p Sychev | | Half-time: | 1-0 | | Referee: | Franceschini 8 | | Attendance: | 29,872 | | Possession: | 64%-36% | | Total shots: | 16-6 | | MoM: | Spahic |
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| | (4-3-3): Gabulov 7½, Jiránek 8, Spahic 8½, Kalynychenko 8½, Bikey 6½, Sennikov 8, Bystrov 7, Bilyaletdinov 8, Sychev 6½, Kingston 7½, Lebedenko 7 | | Valencia | 0 |
| | 17 Leca, 21 Weston, 27 Faubert, 62 Scardina, 73 Zanchi, 83 Yahia | | (4-3-3): Palop 6½, Oleguer 6, Scardina 5½, Leca 6½, Yahia 6½, Zanchi 5½, Faubert 6½, Doni 6½, Gekas 7, Gerardo 5½, Weston 6 | | Lyon | 1 | 68 Piquionne | | Half-time: | 0-1 | | Referee: | Penton 7½ | | Attendance: | 41,023 | | Possession: | 50%-50% | | Total shots: | 8-6 | | MoM: | Cana |
| | 47 Modesto | | (4-3-3): Vercoutre 6½, Clerc 8, Cesar 7, Cana 8½, Modesto 7½, Méité 7, Oruma 6½, Idangar 6, Piquionne 7½, Maoulida 6½, Giménez 6½ | | Metz | 2 | 45 Jestrovic, 47 Keita |
| | (4-3-3): Levitskyi 6, Pichot 7½, Wendell 6½, Proment 7, Rozehnal 7, Grichting 7, Bastien 7½, Keita 7, Jestrovic 6½, Aliadière 6, Baros 6 | | Napoli | 2 | 16 Sosa, 38 Warley | | Half-time: | 2-0 | | Referee: | Stafoggia 6½ | | Attendance: | 41,811 | | Possession: | 46%-54% | | Total shots: | 12-19 | | MoM: | Locatelli |
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| | (4-3-3): Cudicini 6, Manfredini 7, Bertotto 7½, Locatelli 8, Stendardo 6½, Zamboni 6½, Fábio Simplício 6½, Bisgaard 6 (68 Alberto 7), Sosa 6½, Liverani 6½, Warley 5½ | | Panathinaikos | 2 | 52 Basinas, 85 Goumas | | 37 Villa | | (4-3-3): Nikopolidis 6½, Serrizuela 7, Domizzi 7½, Karagounis 8, Goumas 7, Van Boxel 6½, Belluschi 8, Basinas 7, Llorente 6½, Iarley 6, Villa 5½ | | Trabzonspor | 0 |
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| | (4-3-3): Fevzi 7, Ali Eren 7½, Fábio Aurélio 8, Barton 8, Ufuk 7, Gustavo Nery Sá 7, Ayhan 7½, Alex 7½, Necati 6½, Loskov 6½, Ereros 5½ | | Atlético Madrid | 1 | 81 Javi García | | 7 Varela, 60 Dorado, 86 Pilipauskas | | (4-3-3): Toño 6½, Varela 7½, Dorado 7½, Zapater 7½, Diogo 6½, Gaspar 7, Pilipauskas 7, Nuñez 6½ (56 Maínz 7), Fábio Júnior 6, Javi García 6, Edú 6½ |
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