| Round 1 | | Aston Villa | 0 |
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| | (4-3-3): Cerný 6½, Hibbert 6½, Stensaas 7, Faye 7½, Stubbs 6, Duberry 6½, Euell 6, Ghaly 7, Byfield 6½, Van Diemen 5½, Berger 5½ | | FC Porto | 1 | 18 Hugo Almeida | | 1 Vidigal, 5 Hugo Almeida, 8 Vaschuk, 37 Wörns, 76 Bruno Alves | | (4-3-3): Costinha 7, Bruno Alves 7, Tierney 7, Carlos Martins 8, Wörns 7, Vaschuk 6½ (73 Ricardo Costa 6), Jociválter 6½, Edgar 8, Hugo Almeida 6½, Vidigal 7½, Bergougnoux 6 | | Atlético-MG | 3 | 15 Alecsandro, 42 Liédson, 74 Hugo | | Half-time: | 2-0 | | Referee: | Racalbuto 6 | | Attendance: | 40,946 | | Possession: | 52%-48% | | Total shots: | 18-4 | | MoM: | Farfán |
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| | (4-3-3): Ustari 7, Apodi 7½, Riise 7, Hernanes 6½, Cribari 5½ (85 Cleison 6), Jean 7, Farfán 8, Hugo 7, Alecsandro 7½, Marques 5½, Liédson 8 | | Brøndby | 1 | 46 Olesen | | 14 Kamper, 51 Zimling, 78 Christiansen | | (4-3-3): Christiansen 6½, Johansen 7½, Sennels 7½, Lorentzen 7, Nielsen 6½, Vragel 6½, Jonson 7½, Kamper 6, Olesen 6½, Zimling 6, Michaelsen 6 | | Bayern München | 1 | 47 Jancker | | Half-time: | 0-1 | | Referee: | Rodomonti 7½ | | Attendance: | 45,543 | | Possession: | 46%-54% | | Total shots: | 11-8 | | MoM: | Rosales | | TV: | live |
| | 8 Fernando, 72 Bellion, 90 Asamoah | | (4-3-3): Rüstü 5½, Zenoni 6½, Griffin 7½, Fernando 6½, Krstajic 7, Mendy 6½, Asamoah 6, Bowyer 6, Jancker 7½, Miller 5½, Bellion 6½ | | Independiente | 2 | 14 Camps, 53 Camps |
| | (4-3-3): Saja 6½, Ibarra 7, Domínguez 6½, Gracián 7½, Contreras 6½ (78 Deflandre 6), Ríos 6, Rosales 8, Camps 7, Kanu 6½, França 6, Husaín 6½ | | Belenenses | 0 |
| | Half-time: | 0-1 | | Referee: | Rosica 5½ | | Attendance: | 39,883 | | Possession: | 39%-61% | | Total shots: | 7-10 | | MoM: | Marin |
| | 54 Cardozo, 70 Von Schwedler | | (4-3-3): Caranta 6½, Nélson 6½, Rodrigo Arroz 6½, Silas 6½, Boateng 6, Von Schwedler 6, José Pedro 7 (59 Edmilson 6½), Cândido Costa 5, Cardozo 6½, Edson 5½, Valdez 6 | | Standard | 1 | 4 Makukula |
| | (4-3-3): Stijnen 7, Yobo 6½, Goor 5, Simons 6½, Dragutinovic 6½, Zewlakow 6½, Marin 8, Claiton 6½ (66 Patsatzoglou 6), Makukula 8, Oubiña 6½, Hendrikx 6½ | | Celtic | 4 | 17 Nakamura, 22 Zurawski, 45+1 Donati, 79 Virgo | | Half-time: | 3-0 | | Referee: | Benkö 7 | | Attendance: | 32,518 | | Possession: | 50%-50% | | Total shots: | 23-7 | | MoM: | Naylor |
| | 12 Miller, 33 Donati, 49 Zurawski | | (4-3-3): Boruc 7½, Caldwell 7, Naylor 8, Donati 7½, McManus 7½, Pressley 6½, Hartley 6, Nakamura 7½, Virgo 6½, Miller 5½, Zurawski 6 | | Hearts | 0 |
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| | (4-3-3): Banks 7, Neilson 7, Wallace 7 (85 Bruno Aguiar 6), Jonsson 7½, Berra 6½, Zaliukas 6, Mikoliunas 6½, Driver 7, Nadé 6, Stewart 5½, Mole 6 (61 Thomson 5½) | | Dynamo | 1 | 58 Årst | | Half-time: | 0-3 | | Referee: | Blareau 6 | | Attendance: | 37,131 | | Possession: | 43%-57% | | Total shots: | 8-10 | | MoM: | Ferreira Pinto |
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| | (4-3-3): Shovkovskyi 5½, Gurenko 7½, Radchenko 6½, Vukojevic 6½ (67 Venhlinskyi 7), Bordon 7, César 6, Yezerskyi 6, Hanstveit 7, Årst 7½, Shatskikh 5½, Demetradze 6½ | | Atalanta | 3 | 16 Ferreira Pinto, 25 Padoin, 41 Padoin |
| | (1-3-3-3): Ivan 6, Garics 6½, Bellini 8, Cigarini 7½, Talamonti 6½, Rivalta 6½, Ferreira Pinto 8, Padoin 7, Inzaghi 6½, Costinha 7, Floccari 5½ | | Fenerbahçe | 1 | 61 Munitis | | Half-time: | 0-0 | | Referee: | Angelov 7½ | | Attendance: | 29,841 | | Possession: | 39%-61% | | Total shots: | 15-1 | | MoM: | Weidenfeller |
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| | (4-3-3): Bobadilla 7½, Gökhan 6½, Wome 7, Bastürk 7½, García Calvo 7½, Labaka 7, Hamit 6½, Munitis 6½ (79 Gulliver 6), Okan 7½, Boateng 7, José Mari 7 | | Borussia Dortmund | 0 |
| | 13 Tinga, 15 Tinga, 48 De Man | | (4-3-3): Weidenfeller 8, Osorio 7½, James 5½, De Man 7, Ehlers 6½ (62 Toedtli 6½), Sarpei 6, Paulinho Jau 5½, Tinga 6½, Arvidsson 6, Maltritz 7, Ganea 5½ | | Hansa Rostock | 1 | 8 Agostino | | Half-time: | 1-1 | | Referee: | Sars 6 | | Attendance: | 28,817 | | Possession: | 43%-57% | | Total shots: | 8-10 | | MoM: | Rodríguez | | TV: | highlights |
| | 44 Agostino | | (4-3-3): Wierzchowski 6½, Rytter 7½, Rodríguez 8, Riedl 8, Stranzl 7, Delpierre 7, Petric 7, Rydlewicz 7, Kern 7½, Schied 6, Agostino 6½ | | Real Oviedo | 2 | 6 Angulo, 65 Angulo | | 63 Juanito | | (4-3-3): Aouate 6½, Cortés 7½, Amorebieta 8, Orbáiz 7, Juanito 7, Sarriegi 7, Capi 7½, Angulo 7, Víctor 6½, Fábio Pinto 5½, Karanka 5½ | | Leeds United | 2 | 4 Bendtner, 35 Bendtner | | Half-time: | 2-0 | | Referee: | Veiga Trigo 6½ | | Attendance: | 37,287 | | Possession: | 45%-55% | | Total shots: | 7-15 | | MoM: | Agbonlahor |
| | 2 Danilo, 9 Greening | | (4-3-3): Hilário 7½, Helveg 7, Murphy 6, Greening 7½, Cygan 7, Ehiogu 6½, Agbonlahor 8, Danilo 7, Bendtner 7, Harewood 6, McFadden 5½ | | Zaragoza | 0 |
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| | (4-3-3): Bernardo 7, Chica 6½, Paredes 6, Óscar 7, Sergio 7½, Chus 6, Matuzalém 7, Luis García 6, Ricardo Oliveira 7, D'Alessandro 6½, Frankowski 6 | | Real Sociedad | 2 | 10 Portillo, 25p Portillo | | Half-time: | 2-3 | | Referee: | Sundell 5½ | | Attendance: | 31,842 | | Possession: | 58%-42% | | Total shots: | 10-15 | | MoM: | Portillo |
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| | (4-3-3): Nuno 5, Mikel González 6, Toledo 7, Xabier Prieto 6 (75 Agirretxe 6½), Ansotegi 7, Aranburu 6, Davies 7, Etherington 7, Portillo 7½, Markel 7, Díaz De Cerio 7 | | Spartak | 4 | 3 Vucinic, 26 Vucinic, 43 Kalou, 89 Vucinic | | 48 Vucinic | | (4-3-3): Hildebrand 5½, Sagna 6½, Barry 6½, Sissoko 6½ (66 Senderos 7), Friedrich 7, Alex 6, Eboué 7½, Modric 7 (71 Karyaka 6), Vucinic 7, Di Natale 6, Kalou 7 | | Vélez Sársfield | 4 | 13 Klimowicz, 23 Balvorín, 49 Vella, 74 Klimowicz | | Half-time: | 2-0 | | Referee: | Meese 6½ | | Attendance: | 35,488 | | Possession: | 51%-49% | | Total shots: | 27-17 | | MoM: | Viduka |
| | 24 Uglessich, 90 Klimowicz | | (4-3-3): Montoya 7½, Uglessich 7, Lima 7, Bustos 7½, Pellerano 6½, Ponce 6½, Sena 6½, Escudero 7, Klimowicz 7, Vella 6½, Balvorín 6 | | SK Sturm Graz | 0 |
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| | (4-3-3): Knezevic 7, Volz 6½, Bochtler 6, Feldhofer 6½, Bak 7½, Strafner 6, Windass 6, Rojas 6½, Viduka 7½, Haas 6, Vastic 6½ | | Round 2 | | Atalanta | 2 | 20 Padoin, 43p Inzaghi | | Half-time: | 2-0 | | Referee: | Finzinger 7 | | Attendance: | 26,538 | | Possession: | 51%-49% | | Total shots: | 12-13 | | MoM: | Hugo |
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| | (4-3-3): Ivan 7, Belleri 6, Bellini 8, Costinha 7, Talamonti 7, Rivalta 6½, Ferreira Pinto 7, Padoin 7½, Inzaghi 6½, Cigarini 7, Floccari 6 | | Atlético-MG | 1 | 89 Hugo |
| | (4-3-3): Ustari 6½, Apodi 6½, Riise 6, Hernanes 7, Cribari 7, Jean 6, Farfán 7½, Hugo 8, Alecsandro 6½, Marques 5½, Liédson 6 | | Borussia Dortmund | 1 | 65p Ganea | | Half-time: | 0-0 | | Referee: | Sandra 8 | | Attendance: | 38,498 | | Possession: | 44%-56% | | Total shots: | 9-18 | | MoM: | Donati |
| | 69 Ehlers | | (4-3-3): Weidenfeller 7, Osorio 7½, James 5½, De Man 7, Ehlers 6½, Sarpei 7½, Maltritz 6½, Tinga 6, Ganea 5½, Paulinho Jau 6½, Arvidsson 6 | | Celtic | 0 |
| | 12 Nakamura | | (4-3-3): Boruc 7½, Caldwell 7, Naylor 7½, Donati 8, McManus 6½, Papac 6½, Hartley 7, Nakamura 7½, Virgo 6, Jarosík 6, Zurawski 6 | | Brøndby | 1 | 6 Perez | | | 33 Vragel, 55 Foldgast | | (4-3-3): Christiansen 7½, Johansen 7, Sennels 7½, Lorentzen 7, Nielsen 7, Vragel 6½, Jonson 8, Kamper 6½ (83 Zimling 6), Foldgast 7½, Michaelsen 6, Perez 6 | | Fenerbahçe | 0 |
| | 8 Boateng | | (4-3-3): Bobadilla 7½, Gökhan 7, Wome 7½, Bastürk 6½, García Calvo 6½, Labaka 6, Hamit 7 (78 Gulliver 6), Munitis 6½, Okan 7, Boateng 6½, José Mari 7 | | FC Porto | 0 |
| | Half-time: | 0-0 | | Referee: | Bogdanov 6½ | | Attendance: | 40,341 | | Possession: | 55%-45% | | Total shots: | 20-11 | | MoM: | Wörns |
| | 53 Edgar, 89 Carlos Martins | | (4-3-3): Costinha 7½, Bruno Alves 7, Tierney 7½, Carlos Martins 6½, Wörns 7½, Vaschuk 7, Jociválter 7, Edgar 7, Hugo Almeida 6½, Vidigal 6½, Bergougnoux 6 | | Dynamo | 0 |
| | 34 Bordon, 55 Hanstveit | | (4-3-3): Shovkovskyi 7, Gurenko 6½, Radchenko 7½, Vukojevic 7½, Bordon 7, César 5½, Yezerskyi 6, Hanstveit 6½, Årst 7, Shatskikh 6, Demetradze 6 | | Hearts | 0 |
| | Half-time: | 0-0 | | Referee: | Momirov 6 | | Attendance: | 17,690 | | Possession: | 44%-56% | | Total shots: | 9-18 | | MoM: | Helveg |
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| | (4-3-3): Banks 7½, Neilson 7 (49 Elliot 7), Wallace 6, Jonsson 6½, Berra 6½ (79 Templeton 6), Zaliukas 6, Mikoliunas 6, Driver 6½, Nadé 6, Stewart 5½, Mole 6½ | | Leeds United | 0 |
| | 18 Agbonlahor | | (4-3-3): Hilário 7, Helveg 8, Murphy 7, Greening 6½, Cygan 7½, Ehiogu 6½, Agbonlahor 6½, Danilo 7½, Bendtner 7, Harewood 6½, McFadden 6 | | Independiente | 2 | 2 Kanu, 13 Camps | | Half-time: | 2-2 | | Referee: | Christensen 6 | | Attendance: | 41,709 | | Possession: | 46%-54% | | Total shots: | 16-8 | | MoM: | Contreras |
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| | (4-3-3): Saja 6½, Ibarra 7, Domínguez 7, Gracián 7, Contreras 8, Domínguez 6½, Rosales 7, Camps 6½, Kanu 7, França 6½, Husaín 5½ | | Real Sociedad | 2 | 19 Portillo, 23 Etherington | | 12 Davies, 28 Aranburu, 31 Etherington, 72 Xabier Prieto | | (4-3-3): Nuno 6½, Mikel González 6½, Toledo 7½, Xabier Prieto 7, Ansotegi 7, Aranburu 6, Davies 6½, Etherington 7, Portillo 6½, Elustondo 5½, Díaz De Cerio 6 | | Real Oviedo | 2 | 57 Angulo, 82 Angulo | | Half-time: | 0-0 | | Referee: | Damgaard 6½ | | Attendance: | 23,343 | | Possession: | 54%-46% | | Total shots: | 19-11 | | MoM: | Orbáiz |
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| | (4-3-3): Aouate 7½, Cortés 7, Amorebieta 7, Orbáiz 8½, Juanito 7½, Sarriegi 7, Capi 7½, Angulo 7½, Víctor 6, Fábio Pinto 5½, Karanka 6 | | Belenenses | 1 | 47 Cardozo |
| | (4-3-3): Caranta 7, Nélson 6½, Rodrigo Arroz 6½, José Pedro 7½, Boateng 7, Von Schwedler 6, Cândido Costa 7 (68 Djaló 6), Silas 7, Cardozo 7, Edson 5½, Valdez 6 | | SK Sturm Graz | 0 |
| | Half-time: | 0-1 | | Referee: | Nielsen 6½ | | Attendance: | 15,942 | | Possession: | 50%-50% | | Total shots: | 10-14 | | MoM: | Zenoni |
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| | (4-3-3): Knezevic 6½, Volz 6½, Bochtler 7, Feldhofer 7½, Bak 7, Strafner 6, Windass 6½, Rojas 7, Viduka 7, Haas 6, Vastic 7½ | | Bayern München | 1 | 10 Jancker | | 1 Bowyer, 87 Leonardo | | (4-3-3): Rüstü 7, Zenoni 8½, Griffin 7½, Fernando 8, Krstajic 7, Manuel Pablo 5½, Asamoah 7, Leonardo 6½, Jancker 6½, Bowyer 6½, Bellion 6 | | Spartak | 0 |
| | Half-time: | 0-0 | | Referee: | Leduc 6 | | Attendance: | 47,834 | | Possession: | 49%-51% | | Total shots: | 16-15 | | MoM: | Bustos |
| | 9 Eboué, 31 Hildebrand, 78 Modric | | (4-3-3): Hildebrand 6½, Sagna 7, Barry 7, Sissoko 7½, Friedrich 7, Alex 6, Eboué 7 (51 Wright-Phillips 7), Modric 6, Vucinic 7, Di Natale 6½, Kalou 6½ | | Vélez Sársfield | 1 | 47 Klimowicz | | 81 Lima | | (4-3-3): Montoya 7½, Uglessich 7, Lima 6½, Bustos 7½, Pellerano 7, Ponce 6½, Sena 7, Escudero 6½, Klimowicz 7½, Vella 6, Balvorín 6½ | | Standard | 0 |
| | Half-time: | 0-0 | | Referee: | Pauchard 6 | | Attendance: | 29,858 | | Possession: | 47%-53% | | Total shots: | 16-11 | | MoM: | Simons |
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| | (4-3-3): Stijnen 6½, Yobo 7, Goor 7, Simons 8, Dragutinovic 6½, Zewlakow 6, Marin 7, Hendrikx 7, Makukula 7, Oubiña 7 (51 El Yamani 6), Claiton 6½ (68 Mutavdzic 5½) | | Hansa Rostock | 1 | 85 Riedl | | 1 Rytter, 2 Agostino | | (4-3-3): Wierzchowski 6½, Rytter 7, Rodríguez 5½, Riedl 7½, Stranzl 7½, Delpierre 6, Petric 6½, Rydlewicz 7, Kern 6½ (86 Gaede 6), Schied 5½, Agostino 6 | | Zaragoza | 1 | 11 Paredes | | Half-time: | 1-0 | | Referee: | Ramos 5½ | | Attendance: | 34,473 | | Possession: | 57%-43% | | Total shots: | 26-6 | | MoM: | Óscar |
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| | (4-3-3): Bernardo 7, Chica 6, Paredes 7½, Óscar 8, Sergio 6½ (82 Núnez 6), Chus 6½, Matuzalém 7, Luis García 7½, Ricardo Oliveira 7, Gabi 7½, Frankowski 6½ | | Aston Villa | 1 | 78 Euell |
| | (4-3-3): Cerný 7½, Hibbert 7, Stensaas 6½, Faye 7, Stubbs 6½, Duberry 6½, Euell 6½, Ghaly 6½, Byfield 6, Berger 6, Scannell 5½ |
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