| Round 3 | | Aston Villa | 0 |
| | Half-time: | 0-0 | | Referee: | Quiniou 6 | | Attendance: | 33,898 | | Possession: | 45%-55% | | Total shots: | 9-6 | | MoM: | Stijnen |
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| | (4-3-3): Cerný 7½, Hibbert 7, Stensaas 7½, Faye 8, Stubbs 7, Duberry 7½, Euell 6½, Ghaly 7½, Byfield 6, Berger 6, Scannell 6 | | Standard | 0 |
| | 33 Yobo, 64 Mutavdzic | | (4-3-3): Stijnen 8, Yobo 7, Goor 7½, Simons 7½, Dragutinovic 7½, Zewlakow 6, Marin 7½, Claiton 7, El Yamani 6½, Oubiña 6, Mutavdzic 5½ | | Dynamo | 0 |
| | Half-time: | 0-0 | | Referee: | Vad 5 | | Attendance: | 33,737 | | Possession: | 43%-57% | | Total shots: | 9-13 | | MoM: | Gurenko |
| | 15 Årst | | (4-3-3): Shovkovskyi 6½, Gurenko 7½, Radchenko 7½, Vukojevic 7 (67 Venhlinskyi 7½), Bordon 7, César 6½, Yezerskyi 6½, Hanstveit 6½, Årst 6½, Shatskikh 6, Demetradze 7 | | Zaragoza | 1 | 50 Ricardo Oliveira |
| | (4-3-3): Bernardo 7, Cuartero 7½, Drenthe 7, Óscar 7½, Sergio 7½, Chus 7, Matuzalém 6½, Luis García 7, Ricardo Oliveira 7½, D'Alessandro 7, Frankowski 6½ | | Vélez Sársfield | 2 | 31 Klimowicz, 33 Klimowicz | | Half-time: | 2-1 | | Referee: | Grabher 6 | | Attendance: | 43,247 | | Possession: | 48%-52% | | Total shots: | 9-8 | | MoM: | Amorebieta |
| | 25 Maidana, 56 Klimowicz, 77 Pellerano | | (4-3-3): Montoya 5½, Maidana 6 (80 Cabral 6), Lima 7, Bustos 6 (67 Bustamante 7), Pellerano 6½, Ponce 6½, Sena 7, Ocampo 7½, Klimowicz 6½, Escudero 6½, Balvorín 7 | | Real Oviedo | 3 | 16 Angulo, 46 Rubén, 89 Amorebieta | | 23 Capi, 68 Karanka | | (4-3-3): Aouate 6, Cortés 6½ (77 Fábio Pinto 6), Amorebieta 8, Capi 7, Perea 7, Juanito 6½, Amieva 7, Angulo 7½, Rubén 6, Orbáiz 6½, Karanka 5½ | | Round 4 | | Atalanta | 1 | 28 Inzaghi | | Half-time: | 1-3 | | Referee: | Wieser 7½ | | Attendance: | 26,707 | | Possession: | 55%-45% | | Total shots: | 13-9 | | MoM: | Costinha |
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| | (4-3-3): Leyton 5½, Belleri 6½, Bellini 6½, Costinha 8, Talamonti 7, Rivalta 5½, Garics 7½, Padoin 6½, Inzaghi 7½, Cigarini 6½, Floccari 6 | | Leeds United | 3 | 2 Bendtner, 33 Bendtner, 37 Cygan | | 6 Agbonlahor, 41 Danilo | | (4-3-3): Hilário 5½, Helveg 6, Murphy 6½, Greening 7, Cygan 6, Ehiogu 5½, Agbonlahor 7½, Danilo 7½, Bendtner 7, Harewood 6, McFadden 6½ | | Borussia Dortmund | 1 | 18 Sarpei | | Half-time: | 1-2 | | Referee: | Barry 7½ | | Attendance: | 37,089 | | Possession: | 57%-43% | | Total shots: | 17-15 | | MoM: | De Man |
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| | (4-3-3): Weidenfeller 6½, Osorio 7, James 6, De Man 8, Ehlers 6½, Sarpei 8, Maltritz 7, Tinga 7, Ganea 7½, Paulinho Jau 7, Arvidsson 7 | | Belenenses | 2 | 9 Cardozo, 26 Cardozo |
| | (4-3-3): Caranta 7, Nélson 7, Rodrigo Arroz 6, José Pedro 7, Boateng 7, Von Schwedler 6, Cândido Costa 7, Silas 6, Cardozo 7, Edson 6, Valdez 6½ | | Brøndby | 3 | 6 Foldgast, 27 Foldgast, 56 Lorentzen | | Half-time: | 2-0 | | Referee: | Heilbron 7 | | Attendance: | 31,434 | | Possession: | 60%-40% | | Total shots: | 18-11 | | MoM: | Sennels |
| | 46 Foldgast | | (4-3-3): Christiansen 6½, Johansen 7½, Sennels 8½, Lorentzen 8, Nielsen 8, Vragel 7, Jonson 8, Retov 7½, Foldgast 7½, Kamper 6½, Perez 6 | | Aston Villa | 1 | 71 Duberry | | 73 Scannell | | (4-3-3): Cerný 7, Hibbert 7½, Stensaas 7, Faye 6½, Stubbs 6½, Duberry 6½, Euell 6, Ghaly 6½, Byfield 6, Berger 6, Scannell 5½ | | FC Porto | 1 | 19og McManus | | Half-time: | 1-0 | | Referee: | Riley 8 | | Attendance: | 39,175 | | Possession: | 48%-52% | | Total shots: | 8-14 | | MoM: | González | | TV: | highlights |
| | 11 Carlos Martins, 54 Suazo | | (4-3-3): Costinha 7½, Bruno Alves 6½, Vaschuk 5½, Carlos Martins 7, Wörns 6½ (75 Ricardo Sousa 6), Ricardo Costa 6, González 7½, Edgar 6, Hugo Almeida 6, Suazo 5½, Bergougnoux 6½ | | Celtic | 0 |
| | 7 Hartley, 13 Donati, 28 Zurawski, 30 Jarosík, 38 Boruc, 68 Virgo, 69 Nakamura | | (4-3-3): Boruc 7, Caldwell 6½, Naylor 7, Donati 7, McManus 7½, Papac 7, Hartley 6½, Nakamura 7, Virgo 6½, Jarosík 7, Zurawski 6 | | Hearts | 1 | 7 Mole | | Half-time: | 1-1 | | Referee: | Ancion 7 | | Attendance: | 17,639 | | Possession: | 46%-54% | | Total shots: | 13-14 | | MoM: | Agirretxe |
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| | (4-3-3): Banks 5½, Neilson 7½, Wallace 7, Palazuelos 6, Berra 7, Jonsson 6, Mikoliunas 6½, Driver 6½, Nadé 6½, Cesnauskis 6, Mole 5½ | | Real Sociedad | 3 | 4 Etherington, 60 Davies, 81 Agirretxe |
| | (4-3-3): Bravo 6, Mikel González 7½, Toledo 8, Xabier Prieto 7, Ansotegi 6, Aranburu 6½, Davies 7 (61 Agirretxe 8), Etherington 8, Portillo 6½, Elustondo 6½, Díaz De Cerio 6½ | | Independiente | 2 | 64 Domínguez, 75 Camps | | Half-time: | 0-1 | | Referee: | Cervantes 6 | | Attendance: | 44,352 | | Possession: | 48%-52% | | Total shots: | 10-16 | | MoM: | Domínguez | | TV: | live |
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| | (4-3-3): Saja 6½, Ibarra 7, Domínguez 8, Gracián 7½, Contreras 6½, Domínguez 7, Rosales 7½, Camps 6½, Kanu 7, França 6, Husaín 5½ | | Vélez Sársfield | 1 | 7 Bustos | | 14 Ponce, 41 Ponce, 71 Escudero | | (4-3-3): Montoya 6½, Maidana 7, Lima 6½, Bustos 7, Pellerano 7, Ponce 6, Sena 6½, Ocampo 6½, Klimowicz 7, Escudero 6, Balvorín 7 | | Real Oviedo | 2 | 15 Angulo, 84 Angulo | | Half-time: | 1-0 | | Referee: | Amendolia 7½ | | Attendance: | 23,323 | | Possession: | 42%-58% | | Total shots: | 15-13 | | MoM: | Amorebieta |
| | 7 Capi, 58 Orbáiz, 64 Karanka | | (4-3-3): Aouate 7, Cortés 7, Amorebieta 8, Orbáiz 7½, Perea 7, Juanito 6, Amieva 7½, Angulo 7½, Karanka 5½, Capi 6½, Rubén 5½ | | Dynamo | 0 |
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| | (4-3-3): Shovkovskyi 7, Gurenko 7, Radchenko 8, Vukojevic 6½ (67 Venhlinskyi 7), Bordon 8, César 6, Yezerskyi 6, Hanstveit 6½, Årst 7½, Shatskikh 6, Demetradze 6½ | | SK Sturm Graz | 3 | 2 Viduka, 36p Viduka, 55 Rojas | | Half-time: | 2-1 | | Referee: | Arena 6 | | Attendance: | 15,814 | | Possession: | 44%-56% | | Total shots: | 8-12 | | MoM: | Bochtler |
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| | (4-3-3): Knezevic 7, Volz 6½, Bochtler 8½, Feldhofer 7, Bak 6½, Strafner 6½, Fleurquin 6, Rojas 7, Viduka 7, Thiago 6, Haas 7 | | Hansa Rostock | 1 | 15 Kern | | 20 Schied | | (4-3-3): Wierzchowski 6½, Rytter 7½, Rodríguez 6½, Riedl 7½, Stranzl 7, Delpierre 6½, Petric 7, Rydlewicz 6½, Kern 6½, Schied 5½, Agostino 6½ | | Spartak | 2 | 19 Vucinic, 66 Modric | | Half-time: | 1-1 | | Referee: | Baldas 7 | | Attendance: | 46,734 | | Possession: | 44%-56% | | Total shots: | 14-12 | | MoM: | Farfán |
| | 67 Eboué | | (4-3-3): Hildebrand 6½, Sagna 7½, Barry 6½, Ignashevich 7, Friedrich 6 (53 Rafinha 8), Alex 5½, Eboué 7½, Modric 6½, Vucinic 7, Di Natale 5½, Kalou 6½ | | Atlético-MG | 1 | 43 Hernanes |
| | (4-3-3): Ustari 7, Apodi 8, Riise 7, Hernanes 7½, Cribari 6½, Jean 6½, Farfán 8, Hugo 7, Alecsandro 7, Marques 6, Liédson 6 | | Standard | 1 | 36 Oubiña | | Half-time: | 1-0 | | Referee: | Beschin 6 | | Attendance: | 29,967 | | Possession: | 42%-58% | | Total shots: | 13-13 | | MoM: | Marin |
| | 27 Yobo | | (4-3-3): Stijnen 6½, Yobo 6, Goor 6, Simons 7, Dragutinovic 7, Zewlakow 6½, Marin 7½, Claiton 6½, El Yamani 6½, Oubiña 6½, Hendrikx 5½ | | Bayern München | 1 | 88 Bellion | | 22 Rüstü | | (4-3-3): Rüstü 7, Zenoni 7, Griffin 6½, Fernando 7 (88 Parnaby 6), Krstajic 7, Manuel Pablo 5½, Asamoah 6, Leonardo 7, Jancker 6, Bowyer 6, Bellion 6½ | | Zaragoza | 2 | 9 Ricardo Oliveira, 54og Bastürk | | Half-time: | 1-0 | | Referee: | Delacour 6½ | | Attendance: | 34,501 | | Possession: | 52%-48% | | Total shots: | 14-18 | | MoM: | Óscar |
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| | (4-3-3): Bernardo 6½, Cuartero 7, Paredes 6, Óscar 7½, Sergio 6 (67 De La Peña 7½), Chus 6½, Matuzalém 7½, Luis García 7, Ricardo Oliveira 6½, D'Alessandro 6, Frankowski 5½ | | Fenerbahçe | 2 | 47 Boateng, 67 Munitis |
| | (4-3-3): Bobadilla 6½, Gökhan 7, Wome 6½ (55 Lennon 7½), Bastürk 7 (55 Gulliver 6½), Servet 7, García Calvo 7, Hamit 6½, Munitis 6½, Okan 6½, Boateng 7, Bushi 6 |
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