| Round 5 | | Athletic Bilbao | 3 | 14 Blanco, 58 Yeste, 87 Blanco | | Half-time: | 1-1 | | Referee: | Clark 7 | | Attendance: | 36,984 | | Possession: | 51%-49% | | Total shots: | 17-11 | | MoM: | Mignot | | TV: | highlights |
| | 10 Blanco, 31 Mista | | (4-3-3): Pinto 6, Cicinho 6½, Mignot 8, Auriac 7½, Scharner 5½ (57 Alaña 6½), Riseth 6, Konstantinidis 6, Yeste 6½, Blanco 7½, Mista 6, McCarthy 6½ | | Lens | 2 | 23og Riseth, 82 Coulibaly |
| | (4-4-2): Dida 6½, Gilberto 7, Beye 6, Denílson 7, Diagne-Faye 7½, Coulibaly 6, Luís Fabiano 7½, Simão 7 (66 Dacourt 6), Appiah 6, Rothen 6½, Gakpe 6 | | Cruzeiro | 1 | 17 Maciel | | Half-time: | 1-0 | | Referee: | Barber 6 | | Attendance: | 50,592 | | Possession: | 52%-48% | | Total shots: | 13-15 | | MoM: | Seedorf | | TV: | live |
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| | (4-3-3): Rogério 6½, Rogério 6½, Kléber 7, Pedretti 6½, Thiago 6½, André Luís 6½, Gavilán 7, Maciel 7, Washington 6½, Ibson 6½, Phillips 6½ | | Barcelona | 2 | 80og André Luís, 88 Henry | | 74 Hleb | | (3-4-3): Reina 7, Metzelder 6½, Cannavaro 6½, Chivu 7, Del Piero 6, De Rossi 6½, Hleb 5½, Seedorf 7½, Keane 6½, Raúl 7, Henry 7½ | | Inter | 1 | 15og Fahrenhorst | | Half-time: | 1-0 | | Referee: | Clattenburg 6½ | | Attendance: | 60,734 | | Possession: | 53%-47% | | Total shots: | 10-11 | | MoM: | Akinfeev |
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| | (4-3-3): Akinfeev 8, Piqué 7, Puyol 6½, Chiellini 7½, Carragher 8, Pirlo 6, Totti 7, Xavi 7, Drogba 7½, Klose 6½, Cristiano Ronaldo 6½ | | VfB Stuttgart | 0 |
| | 17 Fahrenhorst, 32 Leko, 35 Schulz | | (4-3-3): Quim 7, Jerez 7½, Schulz 6½, Fahrenhorst 6½, Baumann 6½, Madlung 6½, Dindane 6, Carevic 6½, Inzaghi 6, Leko 6, Cacau 5½ | | Juventus | 0 |
| | Half-time: | 0-0 | | Referee: | Allan 7½ | | Attendance: | 63,947 | | Possession: | 73%-27% | | Total shots: | 2-11 | | MoM: | Robinho |
| | 27 Huntelaar | | (3-5-2): Van Der Sar 6, Escudé 6½, Marquez 6, Touré 6½, Hargreaves 6½, Xabi Alonso 7, Shevchenko 6½, Gourcuff 6, Huntelaar 6½, Quaresma 6, Adebayor 6 | | Liverpool | 1 | 57 Robinho |
| | (3-4-3): Casillas 6½, Ferdinand 7½, Vidic 7, Terry 6, Cambiasso 6, Gerrard 6, Messi 7½, Robinho 7½, Rooney 7½, Kaká 7, Ronaldinho 6½ (79 Alexandre Pato 6) | | Monaco | 3 | 17 Dejagah, 24og Dalmat, 45+1p Rasmussen | | Half-time: | 3-0 | | Referee: | Colic 6 | | Attendance: | 41,353 | | Possession: | 54%-46% | | Total shots: | 17-12 | | MoM: | Van Buyten |
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| | (4-3-3): Landreau 7½, Eduardo 6½, Garrido 6½, Tainio 7½, Van Buyten 8, Recoba 6½, Jenas 7½, Dejagah 7, Rasmussen 6½, Rommedahl 6½, Tuncay 6½ | | São Paulo | 0 |
| | 52 Cris, 58 Fabiano, 84 Wescley, 88 Nihat | | (4-3-3): Reva 7½, Fabiano 6½, Arruabarrena 7, Júlio Baptista 6½ (48 Elmer 6½), Cris 7, Wescley 5½, Dalmat 7½, Bruggink 6½, Kléber 6½, Valerón 6½, Nihat 6½ | | Newcastle United | 4 | 4 Robben, 13 Van Nistelrooy, 22 Wheater, 67 Robben | | Half-time: | 3-0 | | Referee: | Wieser 6 | | Attendance: | 36,738 | | Possession: | 51%-49% | | Total shots: | 15-13 | | MoM: | Van Nistelrooy | | TV: | highlights |
| | 56 Robben, 59 Edmílson | | (4-3-3): Given 7½, Gallas 7½, Jankulovski 8, Van Bommel 7, Wheater 6, Edmílson 5 (60 Emanuelson 6½), Kuijt 7½, Robben 7, Van Nistelrooy 8½, Defoe 6, Odemwingie 5½ | | Fiorentina | 0 |
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| | (4-3-3): Coutinho 6½, Panucci 7½, Beasley 6½, Donovan 7 (72 Cohen 6½), Tacchinardi 6½, Navarro 6, Walasiak 6, Esposito 6, Johnson 6½, Marcinho 6, Rivaldo 6 | | PSV | 2 | 50 Torrado, 62 Torrado | | Half-time: | 0-1 | | Referee: | Dinelli 6 | | Attendance: | 26,885 | | Possession: | 43%-57% | | Total shots: | 9-8 | | MoM: | Seitaridis |
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| | (4-3-3): Timmer 7, Tobiasen 7, Thatcher 7½, Torrado 7, Addo 7, Janssen 6, Maldonado 7 (62 Liberopoulos 7), Cocu 7, Smolarek 6 (62 Cohen 6), Lurling 6½, Chevantón 6½ | | Sevilla | 1 | 13 Riki | | 11 Kovacevic, 29 Aitor Ocio | | (4-3-3): Ricardo 6½, Seitaridis 8, Helguera 6½, Casquero 7½, Aitor Ocio 6, Javi Navarro 6½, Rivera 7, Ezquerro 6½, Riki 7½, David 5½, Kovacevic 6½ | | Paris SG | 4 | 43 Essien, 46 Eto'o, 78 Eto'o, 86 Squillaci | | Half-time: | 1-0 | | Referee: | Ansuátegui Roca 7½ | | Attendance: | 48,568 | | Possession: | 60%-40% | | Total shots: | 16-6 | | MoM: | Essien |
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| | (4-4-2): Amelia 7, Daniel 7½, Milito 7½, Essien 8, Squillaci 7½, Marchena 6, Navas 7, Ribéry 7, Silva 7, Eto'o 7, Van Der Vaart 7 | | Chelsea | 0 |
| | 12 Beto | | (4-3-3): Coppola 6½, Bates 6½, Bouma 7, Smith 6½, Beto 6, Davis 5½, Dyer 6½, Boukhari 6, Crouch 6½, Shearer 6, Larsson 5½ | | Real Madrid | 3 | 45+3 Aílton Almeida, 46 Baraja, 75 Pires | | Half-time: | 1-0 | | Referee: | Alves Azevedo 6 | | Attendance: | 63,495 | | Possession: | 48%-52% | | Total shots: | 11-12 | | MoM: | Maicon | | TV: | live |
| | 3 Pires | | (4-3-3): Stekelenburg 7½, Johnson 6, Kaladze 8½, Baraja 7½, Senderos 7½, Gabri 6½, Bentley 7, Pires 6½, Aílton Almeida 7, Wiltord 6, Etxeberria 6 | | Arsenal | 0 |
| | 51 Fernando Meira, 80 Fernando Meira | | (1-3-3-3): Ricardo 7, Maicon 8½, Abidal 7½, Albelda 7, Juan 7½, Fernando Meira 6, Schneider 7½, Tymoschuk 6½, Gilardino 7, Adriano 5½, Tévez 6½ | | Roma | 2 | 2 Iniesta, 37 Iniesta | | Half-time: | 2-0 | | Referee: | Padilla 7½ | | Attendance: | 67,001 | | Possession: | 59%-41% | | Total shots: | 17-10 | | MoM: | Iniesta |
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| | (4-3-3): Buffon 7½, Sergio Ramos 8, Evrà 8, Sneijder 7, Zaccardo 7½, Pablo 6½, Schweinsteiger 8, Iniesta 8, Benzema 7, Diarra 6, Ibrahimovic 7 | | Everton | 1 | 79 Montenegro |
| | (4-3-3): Simonsen 6, Ferdinand 6, Edman 6, Butt 7, Pavón 5½, O'Brien 5½, Osman 6, Giggs 6, Maccarone 6, Montenegro 7, Helguson 5½ | | Sampdoria | 2 | 32og Cafú, 50 Bonazzoli | | Half-time: | 1-1 | | Referee: | Lopez 5½ | | Attendance: | 37,870 | | Possession: | 44%-56% | | Total shots: | 10-14 | | MoM: | Maldini | | TV: | highlights |
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| | (4-3-3): Castellazzi 6, Oddo 6½, Maldini 7½, Palombo 7, Contini 6½, Pavan 6½, Galletti 7, Dalla Bona 7, Bonazzoli 6½, Volpi 6, Borriello 6 | | Santos | 3 | 11 Renato, 48 Deivid, 66 Renato | | 36 Renato, 40 Nasa, 75 Lugano | | (4-3-3): McGregor 6, Cafú 6½, Rool 7, Gilberto Silva 7 (49 Douglas 7), Lugano 6½, Domingos 6, Paulo César 6½, Renato 6½, Deivid 6½, Ricardinho 6½, Nasa 6 | | Round 3 | | Cruzeiro | 2 | 43 Washington, 53 Maciel | | Half-time: | 1-1 | | Referee: | Jorge Corroado 5½ | | Attendance: | 35,684 | | Possession: | 44%-56% | | Total shots: | 5-14 | | MoM: | Butt |
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| | (4-3-3): Rogério 6½, Rogério 6, Kléber 7½, Pedretti 7, Thiago 6½, André Luís 6, Gavilán 6½, Maciel 7½, Washington 6½, Ibson 6, Phillips 6½ | | Everton | 1 | 16 Osman |
| | (4-3-3): Simonsen 7½, Ferdinand 7, Edman 7½, Butt 8½, Pavón 6½, O'Brien 6, Osman 7, Giggs 7½, Maccarone 7, Montenegro 7, Helguson 6½ |
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