| Round 5 | | Atlético Madrid | 2 | 28 Edú, 65 Edú | | Half-time: | 1-1 | | Referee: | Atkinson 5½ | | Attendance: | 45,061 | | Possession: | 44%-56% | | Total shots: | 18-12 | | MoM: | Piquionne |
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| | (4-3-3): Tońo 6, Diogo 7, Dorado 6, Javi García 7½, Gaspar 6, Maínz 6½, Varela 7½, Rossato 6, Fábio Júnior 7, Caggiano 6, Edú 7½ | | Lyon | 2 | 18 Cana, 81p Piquionne | | 5 Oruma, 89 Keogh | | (4-3-3): Vercoutre 6½, Clerc 7, Cesar 6½, Cana 8, Méité 8, Modesto 6½, Oruma 7, Faty 7 (84 Keogh 6), Piquionne 8, Maoulida 6½, Giménez 6½ | | Bayer Leverkusen | 0 |
| | Half-time: | 0-0 | | Referee: | Andersen 6 | | Attendance: | 22,439 | | Possession: | 48%-52% | | Total shots: | 6-12 | | MoM: | Jiránek | | TV: | live |
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| | (4-3-3): Adler 6, Castro 7½, Gresko 6½, Rolfes 7½, Sinkiewicz 6, Vidal 6, Frings 6½, Barnetta 6½, Kiessling 7, Schwegler 6½, Bulykin 6 | | Lokomotiv | 3 | 61 Spahic, 63 Sychev, 73 Spahic | | 62 Sarkisyan, 84 Bystrov | | (4-3-3): Gabulov 5½, Jiránek 7½, Spahic 7, Kalynychenko 7, Sennikov 6½, Had 7 (62 Kingston 6½), Bystrov 7, Bilyaletdinov 7 (62 Sarkisyan 6½), Sychev 7½, O'Connor 6½, Lebedenko 6 | | Blackburn Rovers | 2 | 27 Reid, 74 Derbyshire | | Half-time: | 1-0 | | Referee: | Chiesa 7 | | Attendance: | 31,314 | | Possession: | 49%-51% | | Total shots: | 11-7 | | MoM: | Nelsen | | TV: | highlights |
| | 33 Derbyshire | | (4-3-3): Friedel 7½, Emerton 6½, Taylor 6½, Savage 7½, Nelsen 8, Young 6, Reid 6 (54 Gray 8), Peter 6½, Mido 7, Roberts 7, Derbyshire 6 | | Kaiserslautern | 0 |
| | 29 Floro Flores | | (1-3-3-3): Lehmann 7½, Owomoyela 6½, Müller 6½, Kruska 7, Baránek 6, Ümit 7, Kovac 7, Pimenov 6½, Floro Flores 6½, Yelen 6, Yakin 6½ (56 Reuter 6) | | Bordeaux | 1 | 25 Zapata | | Half-time: | 1-0 | | Referee: | Tanner 7 | | Attendance: | 33,245 | | Possession: | 44%-56% | | Total shots: | 7-14 | | MoM: | Cufré |
| | 26 Álvarez, 90+1 Black | | (4-3-3): Richert 7½, Fanni 7, Cufré 8, Zapata 8, Planus 7½, Maietta 6½, Black 7, Ledesma 7, Bugnet 6½ (58 Ferri 6), Álvarez 5½, Batllčs 6 | | FK Austria | 0 |
| | 21 Blanchard, 64 Antonsson | | (4-3-3): Didulica 7½, Dospel 7, Troyanski 6½, Blanchard 7½, Antonsson 6½, Kiesenebner 6½, Sionko 7½, Janocko 7½, Linz 7, Vachousek 6, Rushfeldt 7 | | Lazio | 1 | 45+1 Bellamy | | Half-time: | 1-0 | | Referee: | Hauge 6½ | | Attendance: | 46,187 | | Possession: | 54%-46% | | Total shots: | 19-7 | | MoM: | Grosso |
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| | (4-3-3): Mondragón 7½, Leonardo Moura 6½ (71 Bayly 6), Grosso 8, Zanetti 7½, Luizăo 6, Vranjes 7 (76 Lustenberger 6), Almirón 7½, Felipe 7, Bellamy 7, Paro 6½, Frei 6½ | | Gręmio | 0 |
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| | (4-3-3): Ochoa 7½, Bosingwa 6½, Roberto Carlos 7, Raul Meireles 6½ (69 Jovetic 7½), Miguel Veloso 6½, Ivanovic 6, Giovani 7, Sánchez 7, Hladkyi 6, Marcos Assunçao 7, Piatti 6 | | Metz | 0 |
| | Half-time: | 0-0 | | Referee: | Collina 7½ | | Attendance: | 27,890 | | Possession: | 46%-54% | | Total shots: | 18-8 | | MoM: | José Enrique |
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| | (4-3-3): Levitskyi 7½, Pichot 7, Wendell 7, Proment 7 (72 Paisley 6), Rozehnal 7½, Grichting 5½, Bastien 6½, Karyaka 7, Jestrovic 6½, Aliadičre 5½, Baros 6½ | | Deportivo | 0 |
| | 59 Sanogo, 68 Xisco | | (4-3-3): Katergiannakis 7, Iraola 7½, José Enrique 7½, Fiore 7, Ricardo Rocha 7, Parfonov 5½, Marney 7 (51 Canobbio 6½), Xisco 7, Sanogo 6½, Valdo 5½, Giannichedda 6½ | | Panathinaikos | 1 | 20 Iarley | | Half-time: | 1-0 | | Referee: | D'Urso 6½ | | Attendance: | 43,944 | | Possession: | 54%-46% | | Total shots: | 20-8 | | MoM: | Karagounis | | TV: | highlights |
| | 49 Goumas, 52 Nikopolidis | | (4-3-3): Nikopolidis 6½, Serrizuela 6½, Domizzi 7½, Karagounis 8, Goumas 6½, Van Boxel 7, Belluschi 7, Basinas 7, Llorente 7, Iarley 7, Radzinski 5½ | | FC Schalke 04 | 1 | 63 Van Kerckhoven |
| | (4-3-3): Gentenaar 7, Fritz 7½, Simunic 8, Lincoln 7, Van Kerckhoven 7, Hajnal 6, Menseguez 5½, Gentner 6½ (64 Szollar 7), Charisteas 6½, Lokvenc 6½, Halil 6½ | | Racing Santander | 3 | 16og Drpic, 19 Felipe Melo, 45+1 Colsa | | Half-time: | 3-0 | | Referee: | Dondarini 8 | | Attendance: | 22,245 | | Possession: | 49%-51% | | Total shots: | 15-9 | | MoM: | Gökdeniz |
| | 31 Aganzo | | (4-3-3): Itandje 7½, Pinillos 7½, Neru 7, Colsa 7, Rubén 7, Moratón 6, Álvarez 6, Iriney 7, Zigic 7, Felipe Melo 6½, Aganzo 5½ | | Galatasaray | 1 | 59 Sergen |
| | (4-3-3): Fromlowitz 7½, Alvarez 7, Ergün 7, Ilic 7, Drpic 7, Emrah 6½, Okan 7½, Gökdeniz 7½, Sergen 6, Delporte 5½, Niyazi Serhat 6 | | Real Betis | 1 | 55 Gutiérrez | | Half-time: | 0-1 | | Referee: | Dunn 8 | | Attendance: | 44,600 | | Possession: | 51%-49% | | Total shots: | 11-12 | | MoM: | Fábio Aurélio |
| | 16 Robert, 76 Marc Torrejón | | (4-3-3): Contreras 6½, Kvarme 6½, Pasqual 7, Karhan 7, Marc Torrejón 6½, Lequi 5½, Husev 6½, Gutiérrez 7½, Robert 7, Nenę 6, Salva 6 | | Trabzonspor | 1 | 45+4 Alex |
| | (4-3-3): Fevzi 6½, Ali Eren 6½, Fábio Aurélio 8, Barton 6½, Ufuk 7, Gustavo Nery Sá 6, Ayhan 6½, Alex 7 (53 Yasin 7½), Necati 7½, Loskov 7, Ereros 6 | | Roda JC | 0 |
| | Half-time: | 0-0 | | Referee: | Nielsen 6 | | Attendance: | 19,809 | | Possession: | 46%-54% | | Total shots: | 7-10 | | MoM: | Sonkaya |
| | 2 Sikora, 23 Vicelich, 77 Stefanovic | | (4-3-3): Jevric 7, Sonkaya 7½, Lachambre 6½, Sergio 7½, Stefanovic 7, Vicelich 6½, Berglund 7, Meeuwis 6½, Torma 7, Sikora 6, Cristiano 6 | | Napoli | 1 | 63 Bisgaard |
| | (4-3-3): Cudicini 7½, Manfredini 7½, Bertotto 7, Locatelli 7½, Stendardo 7, Zamboni 6½, Fábio Simplício 7½, Bisgaard 6½ (68 Alberto 6½), Sosa 7, Liverani 7, Warley 6 | | Valencia | 2 | 46 Gekas, 90 Gekas | | Half-time: | 0-0 | | Referee: | Peternac 8½ | | Attendance: | 40,517 | | Possession: | 43%-57% | | Total shots: | 16-16 | | MoM: | Fathi |
| | 53 Doni, 59 Scardina | | (4-3-3): César 7, Faubert 7, Scardina 6½, Leca 7, Oleguer 7, Yahia 6½, Gerardo 6½, Doni 6½, Gekas 6½, Batista 5½, Weston 5½ | | Flamengo | 0 |
| | 72 Júnior | | (4-3-3): Vermeer 8, Belletti 8, Fathi 8½, Edu 8, Ânderson Polga 7, Cadú 7 (81 Gil 6), Donnet 7, Marcelinho 7½, Braaten 7, Júnior 6, Adúriz 6 |
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