| Round 5 | | Aston Villa | 1 | 27 Berger | | Half-time: | 1-0 | | Referee: | Knight 8 | | Attendance: | 30,945 | | Possession: | 48%-52% | | Total shots: | 12-4 | | MoM: | Domínguez |
| | 72 Berger | | (4-3-3): Cerný 7½, Hibbert 7½, Stensaas 7½, Faye 7, Stubbs 8, Duberry 6½, Euell 7½, Ghaly 7½, Byfield 6, Berger 6½ (75 Cooke 6), Scannell 5½ | | Independiente | 0 |
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| | (4-3-3): Saja 7½, Ibarra 7, Domínguez 8½, Gracián 7, Contreras 7, Domínguez 6, Rosales 7, Camps 7½, Kanu 6½, França 6, Husaín 5½ | | Atlético-MG | 0 |
| | Half-time: | 0-1 | | Referee: | Krondl 7 | | Attendance: | 40,250 | | Possession: | 49%-51% | | Total shots: | 23-12 | | MoM: | Marin |
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| | (4-3-3): Ustari 6½, Apodi 7, Riise 7½, Hernanes 7, Cribari 7, Jean 6½, Farfán 7½, Hugo 7½, Alecsandro 7, Marques 6, Liédson 6½ | | Standard | 2 | 41 Goor, 80 Marin |
| | (4-3-3): Stijnen 7, Yobo 6½, Goor 7½, Simons 7, Dragutinovic 6½, Zewlakow 6½, Marin 7½, Claiton 6½, El Yamani 7 (82 Spelmann 6), Oubiña 6½, Hendrikx 5½ | | Bayern München | 2 | 15 Asamoah, 67 Jancker | | Half-time: | 1-0 | | Referee: | Ancion 7½ | | Attendance: | 41,523 | | Possession: | 46%-54% | | Total shots: | 9-14 | | MoM: | Rüstü |
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| | (4-3-3): Rüstü 7½, Zenoni 6½, Griffin 7, Fernando 7, Krstajic 6½, Manuel Pablo 6½, Asamoah 7½, Leonardo 5½, Jancker 7, Bowyer 6½, Bellion 7 | | Borussia Dortmund | 0 |
| | 25 Ganea, 30 Sarpei | | (4-3-3): Weidenfeller 7, Osorio 7½, James 7, De Man 7½, Ehlers 6½, Sarpei 7, Maltritz 7½, Tinga 6½, Ganea 6, Paulinho Jau 6½, Arvidsson 7 | | Belenenses | 2 | 32 Cardozo, 85 Nélson | | Half-time: | 1-0 | | Referee: | Van Der Ende 7 | | Attendance: | 30,718 | | Possession: | 51%-49% | | Total shots: | 11-13 | | MoM: | Caranta |
| | 49 Silas, 62 José Pedro | | (4-3-3): Caranta 8, Nélson 8, Rodrigo Arroz 7, José Pedro 7½, Boateng 7, Von Schwedler 5½, Cândido Costa 8, Silas 7, Cardozo 7½, Edson 6, Valdez 7 | | Hearts | 0 |
| | 27 Cesnauskis, 36 Jonsson | | (4-3-3): Banks 7, Neilson 7, Wallace 6½, Palazuelos 6½, Berra 7, Jonsson 6, Mikoliunas 7, Driver 6, Nadé 7½, Cesnauskis 6, Mole 5½ | | Celtic | 1 | 78 Nakamura | | Half-time: | 0-0 | | Referee: | Boggi 7½ | | Attendance: | 31,567 | | Possession: | 43%-57% | | Total shots: | 14-18 | | MoM: | Nakamura |
| | 3 McDonald, 39 McDonald | | (4-3-3): Boruc 6, Caldwell 6, Naylor 8, Donati 7, McManus 7½, Papac 5½, Hartley 6½ (55 Sno 6½), Nakamura 8, Virgo 6, Miller 6, McDonald 5½ | | Brøndby | 3 | 56 Sennels, 63 Retov, 74 Foldgast | | 16 Kamper, 67 Sennels | | (4-3-3): Christiansen 6½, Johansen 7, Sennels 7½, Lorentzen 8, Nielsen 7½, Skarbalius 6½, Jonson 7½, Retov 7½, Foldgast 7, Kamper 6, Perez 6½ | | Dynamo | 3 | 22 Årst, 38 Årst, 90+1 Radchenko | | Half-time: | 2-0 | | Referee: | Strampe 6½ | | Attendance: | 26,060 | | Possession: | 50%-50% | | Total shots: | 13-14 | | MoM: | Radchenko |
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| | (4-3-3): Shovkovskyi 7½, Gurenko 7½, Radchenko 8½, Vukojevic 8, Bordon 7½, César 6½, Yezerskyi 6, Hanstveit 6½, Årst 7½, Shatskikh 6, Demetradze 6 | | SK Sturm Graz | 1 | 77og César |
| | (4-3-3): Knezevic 7, Volz 6½, Bochtler 6½, Feldhofer 7, Bak 6½, Strafner 6½, Fleurquin 6, Rojas 7½, Viduka 8, Thiago 5½, Haas 6 | | Fenerbahçe | 1 | 4 Okan | | Half-time: | 1-0 | | Referee: | Dowd 5½ | | Attendance: | 29,965 | | Possession: | 46%-54% | | Total shots: | 10-14 | | MoM: | Costinha | | TV: | highlights |
| | 60 Bastürk | | (4-3-3): Bobadilla 7, Gökhan 8, Wome 7½, Bastürk 7, Servet 7, García Calvo 6, Hamit 7, Munitis 7½, Okan 6½, Boateng 6, Bushi 6 | | FC Porto | 0 |
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| | (4-3-3): Costinha 8, Bruno Alves 8, Ricardo Costa 7, Vidigal 8, Wörns 7, Vaschuk 6½, González 7, Edgar 6½, Suazo 6, Hugo Almeida 6, Bergougnoux 7 (65 Ricardo Sousa 6) | | Hansa Rostock | 1 | 90+1 Stranzl | | Half-time: | 0-2 | | Referee: | McCluskey 6 | | Attendance: | 28,809 | | Possession: | 46%-54% | | Total shots: | 12-13 | | MoM: | Riedl |
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| | (4-3-3): Wierzchowski 6½, Degen 7, Rodríguez 6½, Riedl 8½, Stranzl 7, Delpierre 6, Petric 7, Zé Roberto 7, Kern 6, Gaede 5½, Schroth 5½ | | Spartak | 2 | 15 Rosický, 42 Sagna | | 86 Di Natale | | (4-4-2): Hildebrand 6, Sagna 7, Barry 6½ (66 Givet 8), Ignashevich 7, Friedrich 7, Alex 7, Eboué 7, Rosický 7 (71 Keita 7), Vucinic 6½, Di Natale 5½, Modric 6½ | | Leeds United | 0 |
| | Half-time: | 0-1 | | Referee: | Vaughn 6½ | | Attendance: | 41,325 | | Possession: | 57%-43% | | Total shots: | 14-12 | | MoM: | Greening | | TV: | live |
| | 22 Harewood, 56 McFadden, 68 Danilo, 82 Cygan | | (4-3-3): Hilário 7, Jacobsen 7 (67 Jackson 7), Pogatetz 7, Greening 8, Cygan 7, Ehiogu 6½, Agbonlahor 7½, Danilo 7, Bendtner 6½, Harewood 6, McFadden 6 | | Real Oviedo | 1 | 22 Orbáiz | | 49 Angulo, 61 Karanka | | (4-3-3): Aouate 7½, Cortés 6½, Amorebieta 7, Orbáiz 7, Perea 7½, Juanito 6, Amieva 7½, Angulo 6½, Rubén 6½, Capi 7, Karanka 5½ | | Real Sociedad | 4 | 9 Etherington, 14 Etherington, 53 Etherington, 75 Portillo | | Half-time: | 2-0 | | Referee: | Sedlacek 6½ | | Attendance: | 31,853 | | Possession: | 49%-51% | | Total shots: | 14-14 | | MoM: | Toledo |
| | 41 Portillo, 73 Ansotegi, 87 Aranburu | | (4-3-3): Bravo 6½, Mikel González 6, Toledo 8½, Xabier Prieto 7½, Ansotegi 7, Aranburu 6, Davies 7, Etherington 7½, Portillo 7, Markel 7, Díaz De Cerio 6 | | Atalanta | 1 | 55 Inzaghi | | 20 Leyton, 45+1 Costinha, 83 Garics | | (1-3-3-3): Leyton 6½, Garics 7½, Bellini 8, Cigarini 7, Talamonti 6, Rivalta 6½, Ferreira Pinto 6½, Tissone 6½, Inzaghi 6½, Costinha 7 (54 Valdés 6), Floccari 6 | | Vélez Sársfield | 3 | 7 Sena, 17 Balvorín, 56 Klimowicz | | Half-time: | 2-0 | | Referee: | Riley 5½ | | Attendance: | 39,602 | | Possession: | 44%-56% | | Total shots: | 13-10 | | MoM: | Matuzalém |
| | 20 Sena, 49 Escudero, 63 Maidana, 81 Klimowicz, 82 Cabral | | (4-3-3): Montoya 6½, Maidana 6½, Lima 7½, Bustos 5½ (67 Cabral 7), Pellerano 7, Bustamante 6½, Sena 6½, Ocampo 7, Klimowicz 7, Escudero 6½, Balvorín 5½ | | Zaragoza | 2 | 65 Matuzalém, 71 Chica |
| | (4-3-3): Bernardo 6½, Chica 8, Paredes 6½, Aimar 7½, Chus 6, Cuartero 6, Matuzalém 8½, Luis García 6½, Sergio García 7, Óscar 6, Frankowski 6 | | Round 3 | | Leeds United | 0 |
| | Half-time: | 0-0 | | Referee: | Borriello 7½ | | Attendance: | 43,216 | | Possession: | 44%-56% | | Total shots: | 9-12 | | MoM: | Sagna |
| | 45 Bendtner, 66 Danilo | | (4-3-3): Hilário 6½, Jacobsen 6½, Pogatetz 7, Greening 7½, Cygan 6½, Ehiogu 7, Agbonlahor 6½, Danilo 6, Bendtner 6, Knarvik 6, McFadden 7 (51 Hassli 6½) | | Spartak | 1 | 48 Vucinic | | 77 Modric | | (4-4-2): Hildebrand 7, Sagna 7½, Barry 6½ (66 Givet 6), Ignashevich 7, Friedrich 7½, Alex 5½, Eboué 7, Rosický 7 (66 Keita 6½), Vucinic 7½, Di Natale 6, Modric 6 | | Hansa Rostock | 2 | 80 Schied, 86og De Man | | Half-time: | 0-0 | | Referee: | Ali 6 | | Attendance: | 25,440 | | Possession: | 53%-47% | | Total shots: | 11-11 | | MoM: | Petric |
| | 40 Kern | | (4-3-3): Wierzchowski 7, Degen 7, Rodríguez 7½, Riedl 8, Stranzl 8, Delpierre 6, Petric 8, Zé Roberto 7½, Kern 6½ (78 Hansen 6), Gaede 6 (75 Schied 6½), Schroth 6½ | | Borussia Dortmund | 0 |
| | 8 Paulinho Jau, 29 De Man, 32 Tinga, 42 Arvidsson, 55 Ganea, 56 James, 65 Tinga, 66 Weidenfeller | | (4-3-3): Weidenfeller 7, Osorio 7, James 6, De Man 7½, Ehlers 6½, Sarpei 6½, Maltritz 7, Tinga 7½, Ganea 6½, Paulinho Jau 7, Arvidsson 6½ | | Belenenses | 1 | 26 Cardozo | |
| | (4-3-3): Caranta 5½, Nélson 7½, Rodrigo Arroz 6, José Pedro 8, Boateng 6½, Von Schwedler 6½, Cândido Costa 7, Silas 6, Cardozo 7, Edson 5½, Valdez 5½ | | Independiente | 3 | 7 Camps, 45 Kanu, 81 Camps | | 68 França | | (4-3-3): Saja 6, Ibarra 7½, Domínguez 6½, Gracián 6½, Contreras 7½, Domínguez 6, Rosales 7½, Camps 7, Kanu 7½, França 6½, Husaín 7 |
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