| Round 3 | | FC Porto | 4 | 6 Rafa, 13 João Mário, 22 Carrillo, 89 João Mário | | Half-time: | 3-0 | | Referee: | Huzu 7 | | Attendance: | 42,243 | | Possession: | 51%-49% | | Total shots: | 23-12 | | MoM: | Stephen Eustáquio |
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| | (4-3-3): Marcelo 6½, João Mário 7½, Alex Telles 6½, Stephen Eustáquio 8, Carraça 6, Uribe 6½, Carrillo 7½, Rafa 7, Aboubakar 7, Galeno 5½, Taremi 6 | | Everton | 1 | 54 Maupay | | 72 Keane, 85 Rondón, 90+2 McNeil | | (4-3-3): Begovic 6, Tomiyasu 7, Mykolenko 6½, Doucouré 7½, Tarkowski 6½, Keane 6, McNeil 7½, Bellegarde 6½, Rondón 7, Allan 7, Maupay 6½ | | Leicester City | 2 | 20 Praet, 37 Castagne | | Half-time: | 2-0 | | Referee: | Young 6 | | Attendance: | 32,304 | | Possession: | 56%-44% | | Total shots: | 16-9 | | MoM: | Castagne |
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| | (4-3-3): Ward 7½, Aguilar 6½, Castagne 8½, Gueye 8, Amartey 7½, Phillips 7½, Mendy 7, Ayoze 8, Iheanacho 7, Praet 6½, Gray 6 | | Wolves | 0 |
| | 16 He, 34 Jiménez, 49 Davies, 57 Patric, 82 Saiss | | (4-3-3): José Sá 7½, Patric 6½, Davies 8, João Gomes 7, Kilman 7, Boly 6, Saiss 6½, Hwang 7½, Jiménez 7 (52 Hodge 6½), Campbell 5½, He 6 | | Real Madrid | 0 |
| | Half-time: | 0-1 | | Referee: | Brito Arceo 7½ | | Attendance: | 51,202 | | Possession: | 57%-43% | | Total shots: | 17-9 | | MoM: | Nuno Tavares | | TV: | live |
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| | (4-3-3): Lunin 6½, Nacho 7, Marcelo 6½, Vecino 6, Jesús Vallejo 7½, Rafa 6½, Weiser 7½, Djuricic 7½, Mariano 7, Ramsey 7, Giovinco 7 | | Marseille | 2 | 21 Sánchez, 72 Gerson |
| | (4-3-3): Mandanda 6½, Sarr 6, Nuno Tavares 7½, Gerson 7, Gigot 6½ (72 Ben Seghir 6), Payet 6, Strootman 6, Sánchez 6½, N'Jie 6½, Sanson 6½, Dieng 6½ | | Round 4 | | Ajax | 2 | 6 Promes, 18 Wendel | | Half-time: | 2-0 | | Referee: | Díaz Vega 6½ | | Attendance: | 40,367 | | Possession: | 54%-46% | | Total shots: | 18-11 | | MoM: | Cuadrado |
| | 13 Fofana, 23 Promes, 36 Wendel | | (4-3-3): Trapp 6½, Cuadrado 8, Denswil 6½, Wendel 7½, Veltman 7½, Fofana 7, Chiquinho 6½, Promes 7, Sierhuis 7, Danilo 6, Furuhashi 5½ | | Valencia | 1 | 69 Nani | | 50 Ilaix, 67 Nani | | (4-3-3): Romero 7½, De Marcos 7, Samuel Lino 7½, Parejo 7½, Pepe 7½, Gabriel Paulista 6½, Coquelin 6½, Nani 6, Maranhão 7, Ilaix 6, Hugo Duro 7½ | | Anderlecht | 4 | 6 Guendouzi, 13 Trossard, 26 Immobile, 50 Trossard | | Half-time: | 3-0 | | Referee: | Remme Berge 10 | | Attendance: | 27,934 | | Possession: | 55%-45% | | Total shots: | 21-9 | | MoM: | Geertruida |
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| | (4-3-3): Meret 7½, Geertruida 8, Raum 8, Fofana 7, Le Normand 7½, Maguire 7½, Guendouzi 7, Koopmeiners 7, Immobile 7, Gakpo 7½, Trossard 7 | | Real Madrid | 1 | 68 Djuricic |
| | (4-3-3): Lunin 7, Nacho 6, Marcelo 6, Vecino 6½, Jesús Vallejo 6, Rafa 5½, Weiser 7, Djuricic 7, Mariano 6, Ramsey 6½, Giovinco 6 | | Borussia Dortmund | 2 | 38 Herrmann, 79 Lázaro | | Half-time: | 1-1 | | Referee: | Onufer 6 | | Attendance: | 33,481 | | Possession: | 60%-40% | | Total shots: | 22-3 | | MoM: | Weigl | | TV: | highlights |
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| | (4-3-3): Bürki 7, Toljan 6½, Ito 7½, Weigl 8, Lindelöf 7, Maloney 6½, Knauff 7½, Herrmann 6 (80 Klimowicz 6), Lázaro 7, Elneny 7½, Azmoun 6½ | | Atlético-MG | 1 | 25og Weigl |
| | (4-3-3): Ustari 7, Guga 7½, Henrique 6½, Soriano 7, Murilo Cerqueira 7½, Maicon 5½, Róger 7, Éverton Ribeiro 6½, Dodds 6, Renato Augusto 6½ (80 Réver 6), Rony 6½ | | Everton | 1 | 29 Rondón | | Half-time: | 1-2 | | Referee: | Piller 7½ | | Attendance: | 39,429 | | Possession: | 51%-49% | | Total shots: | 14-12 | | MoM: | Maupay |
| | 43 Bellegarde | | (4-3-3): Begovic 6, Tomiyasu 7½, Mykolenko 6½, Doucouré 7½, Tarkowski 7½, Keane 6, McNeil 6, Bellegarde 6, Rondón 7, Allan 7, Maupay 7½ | | Leicester City | 2 | 5 Gueye, 23 Iheanacho |
| | (4-3-3): Ward 5½, Aguilar 7½, Castagne 6½, Gueye 7½, Amartey 6½, Vestergaard 6, Mendy 7, Ayoze 7 (46 Phillips 6), Iheanacho 7, Choudhury 6, Gray 5½ | | Independiente | 3 | 12 Benedetto, 40 Cervi, 44 Benedetto | | Half-time: | 3-1 | | Referee: | Braamhaar 5½ | | Attendance: | 39,102 | | Possession: | 45%-55% | | Total shots: | 19-5 | | MoM: | Dubois | | TV: | highlights |
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| | (4-3-3): Campaña 7, Rosier 7½, Alonso 7, Sottil 7, Martínez Quarta 6, Rojo 7, Vecchio 7, Cervi 6½, Benedetto 6½, Meza 6, Pavón 6 | | Lyon | 1 | 10 Cornet | | 77 Caqueret | | (4-3-3): Turati 6½, Dubois 8, Chilwell 6½, Caqueret 7½, Danilo 6½, Chambers 6, Tousart 6½ (69 Scarlett 6), Cornet 7, Diallo 7½, Vanaken 6½, Marcos Leonardo 6½ | | Lokomotiv | 0 |
| | Half-time: | 0-1 | | Referee: | Vassaras 6 | | Attendance: | 29,824 | | Possession: | 43%-57% | | Total shots: | 11-15 | | MoM: | Mahrez |
| | 8 Isidor, 26 Denisov, 58 Guilherme | | (4-3-3): Guilherme 6½, Jedvaj 6½, Denisov 7 (68 Lebedenko 5½), Miranchuk 7, Bijol 7½, Magkeev 6½, Isidor 6½, Golovin 6½, Smolov 7, Éder 6, Lysov 6 | | Boca Juniors | 1 | 19 Mahrez |
| | (4-3-3): Rossi 7½, Zambrano 7½, Pelmard 7, Varela 7, Laporte 7½, Figal 6½, Mahrez 8, Moi Gómez 6½ (61 Weigandt 7), Gigliotti 6, Romero 6½, Villa 7 (67 Fernández 6½) | | Marseille | 1 | 75 Sanson | |
| | (4-3-3): Mandanda 7½, Sarr 6½, Nuno Tavares 7½, Gerson 6½, Gigot 6½ (76 Ben Seghir 6), Payet 6, Strootman 6½, Sánchez 7½, N'Jie 7, Sanson 6, Dieng 6 | | Athletic Bilbao | 0 |
| | 23 Vesga, 33 Taylor, 50 Muniain | | (4-3-3): Agirrezabala 8, Lekue 7½, Matviyenko 7, Vesga 7½, Núñez 7, Yeray 6, Feghouli 6, Muniain 7, Guruzeta 7½, Taylor 6½, Villalibre 5½ | | Milan | 4 | 14 Zaccagni, 43 Origi, 48 Origi, 88 Santamaría | | Half-time: | 2-1 | | Referee: | Larsen 6½ | | Attendance: | 46,149 | | Possession: | 55%-45% | | Total shots: | 17-6 | | MoM: | Aina | | TV: | highlights |
| | 5 Santamaría, 34 Zaccagni, 41 Kjær, 49 Origi | | (4-3-3): Diego López 6½, Ricardo Pereira 7, Aina 8, Bennacer 5 (47 Thauvin 7½), Kjær 7, Umtiti 6½, Suso 6½, Zaccagni 7½, Origi 6½, Santamaría 6½, Niang 6½ | | FC Porto | 2 | 33 Rafa, 62 Taremi | | 22 Stephen Eustáquio | | (4-3-3): Marcelo 6½, João Mário 7½, Alex Telles 7, Stephen Eustáquio 7, Carraça 6½, Uribe 6, Carrillo 6½, Rafa 6½, Aboubakar 6½, Galeno 6, Taremi 6 | | Monaco | 0 |
| | Half-time: | 0-1 | | Referee: | Circhetta 7 | | Attendance: | 41,826 | | Possession: | 46%-54% | | Total shots: | 13-10 | | MoM: | Mendy |
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| | (4-3-3): Lecomte 7½, Touré 7½, Mendy 8½, Camara 7 (58 Adrien Silva 7), Maripán 6½, Glik 6½, Sissoko 6½, Pepê 6½, Ben Yedder 6½, Diatta 6, Baldé 6 | | Celta Vigo | 1 | 5 Óscar | | 85 Araujo | | (4-3-3): Blanco 6½, Sergi Roberto 7, Javi Galán 6½, Gueye 7½, Llorente 7, Araujo 7, Solari 7, Sisto 7½, Larsen 7, Óscar 6½, Jonathan Cafú 5½ | | Shakhtar | 3 | 9 Martial, 44p Abraham, 48 Martial | | Half-time: | 2-0 | | Referee: | Clattenburg 6 | | Attendance: | 20,058 | | Possession: | 48%-52% | | Total shots: | 14-14 | | MoM: | Szczesny |
| | 77 Savic | | (4-3-3): Szczesny 8, Zeki 7, Shaw 7, Zambo Anguissa 8, Savic 7, Alex Grimaldo 7, Casemiro 7½, De Bruyne 7½, Abraham 7, Podence 7½, Martial 6½ | | West Ham United | 0 |
| | 81 Hudson-Odoi | | (4-3-3): Vicente Guaita 7, Coufal 6½, Cresswell 7, Partey 6½, Zouma 6½, Diop 6, Helinho 6, Hudson-Odoi 6½, Hernández 6½, Obiang 6, Van Bergen 6 | | Wolves | 2 | 22 Hwang, 51 He | | Half-time: | 1-1 | | Referee: | Wuyts 6 | | Attendance: | 28,764 | | Possession: | 49%-51% | | Total shots: | 16-18 | | MoM: | João Gomes |
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| | (4-3-3): José Sá 6½, Patric 7, Davies 5½, João Gomes 8, Kilman 7½, Boly 7, Saiss 5½, Hwang 6½, Jiménez 7½, Campbell 5½, He 5½ | | Torino | 2 | 7 Pussetto, 54 Danjuma |
| | (4-3-3): Milinkovic-Savic 6½, Zappacosta 7½, Rodriguez 7, Traoré 7½, Izzo 7, Djidji 6, Pussetto 7½, Danjuma 7, Sanabria 7, Verdi 7½, Álex Berenguer 6 |
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