| Round 5 | | Athletic Bilbao | 0 |
| | Half-time: | 0-1 | | Referee: | Ziller 7 | | Attendance: | 39,251 | | Possession: | 48%-52% | | Total shots: | 10-10 | | MoM: | Hwang |
| | 80 Vivian, 89 Villalibre | | (4-3-3): Agirrezabala 6½, Lekue 7, Matviyenko 7½, Vesga 7½, Vivian 7, Yeray 6, Feghouli 7, Muniain 7½, Guruzeta 6½, Guardado 6½, Villalibre 6½ | | Wolves | 1 | 43 Jiménez | | 1 Campbell, 10 He, 20 Patric, 33 Boly, 74 Jiménez | | (4-3-3): José Sá 7, Patric 7½, Davies 7, João Gomes 6½, Kilman 7, Boly 5½, Saiss 6½, Hwang 7½, Jiménez 7, Campbell 5½, He 6 | | Atlético-MG | 0 |
| | Half-time: | 0-1 | | Referee: | Vorjas 6 | | Attendance: | 31,158 | | Possession: | 50%-50% | | Total shots: | 18-14 | | MoM: | Róger |
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| | (4-3-3): Ustari 7½, Guga 7, Fábio Santos 5, Soriano 6½, Murilo Cerqueira 7, Maicon 6½, Róger 8, Éverton Ribeiro 6, Dodds 7, Renato Augusto 6½, Willian 6 | | Shakhtar | 1 | 27 De Bruyne | | 37 Casemiro, 74 De Bruyne, 90 Tiago Djaló | | (4-3-3): Szczesny 7½, Zeki 7½, Shaw 6½, Zambo Anguissa 7, Savic 7, Tiago Djaló 6½, Casemiro 7, De Bruyne 6½, Abraham 7, Podence 6, Martial 7 | | Boca Juniors | 3 | 12 Gigliotti, 41 Mahrez, 52 Vázquez | | Half-time: | 2-0 | | Referee: | Hauge 6 | | Attendance: | 44,811 | | Possession: | 49%-51% | | Total shots: | 10-13 | | MoM: | Guendouzi | | TV: | live |
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| | (4-3-3): Rossi 6, Advíncula 7½, Pelmard 7, Varela 7, Laporte 7½, Zambrano 6½, Mahrez 7, Moi Gómez 6, Gigliotti 7½, Romero 6, Vázquez 6 | | Anderlecht | 2 | 54 Koopmeiners, 60 Guendouzi | | 62 Immobile, 69 Trossard | | (4-3-3): Meret 6½, Geertruida 7½, Raum 7, Fofana 7, Le Normand 7½, Maguire 6½, Guendouzi 8, Koopmeiners 6½, Immobile 6½, Gakpo 6½, Trossard 6½ | | Celta Vigo | 4 | 17 Larsen, 32 Larsen, 52 Javi Galán, 58og Tomiyasu | | Half-time: | 2-1 | | Referee: | Øvrebø 5 | | Attendance: | 32,658 | | Possession: | 37%-63% | | Total shots: | 7-12 | | MoM: | Javi Galán |
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| | (4-3-3): Blanco 6½, Sergi Roberto 6½, Javi Galán 8½, Gueye 7, Llorente 7, Araujo 6½, Solari 6, Sisto 7, Larsen 6, Óscar 6½, Jonathan Cafú 6 | | Everton | 1 | 7 Allan |
| | (4-3-3): Begovic 6½, Tomiyasu 7, Mykolenko 7½, Doucouré 8, Tarkowski 8, Keane 6½, McNeil 8, Bellegarde 7½, Rondón 7, Allan 7, Maupay 7 | | FC Porto | 2 | 64 Oliver, 71 Alex Telles | | Half-time: | 0-1 | | Referee: | Bertolt 7 | | Attendance: | 45,410 | | Possession: | 42%-58% | | Total shots: | 13-14 | | MoM: | Cuadrado |
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| | (4-3-3): Fabiano 7, Corona 7½, Alex Telles 7, Stephen Eustáquio 7½, Uribe 6 (65 Rafa 5½), Cédric 6½, João Mário 6½, Otavio 7, Aboubakar 7, Oliver 6½, Taremi 5½ | | Ajax | 1 | 6 Promes | | 62 Danilo, 64 Danilo, 70 Magallán, 75 Promes | | (4-3-3): Trapp 7½, Cuadrado 8, Denswil 7, Wendel 7, Veltman 6½, Magallán 6½, Danilo 6, Promes 7, Sierhuis 6, Chiquinho 6½, Furuhashi 6 | | Leicester City | 1 | 30 Iheanacho | | Half-time: | 1-1 | | Referee: | Rudy 7½ | | Attendance: | 32,375 | | Possession: | 48%-52% | | Total shots: | 11-8 | | MoM: | Weigl |
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| | (4-3-3): Ward 6, Aguilar 7½, Castagne 7½, Gueye 7, Amartey 7, Vestergaard 6½ (55 McAteer 6½), Mendy 6½, Ayoze 7½, Iheanacho 7, Choudhury 6, Gray 6½ | | Borussia Dortmund | 2 | 37 Weigl, 62 Herrmann | | 69 Elneny | | (4-3-3): Bürki 6½, Toljan 7½, Ito 7½, Weigl 7½, Lindelöf 7½, Maloney 6, Knauff 7, Herrmann 7 (71 Klimowicz 7), Lázaro 6½, Elneny 7, Azmoun 6 | | Lyon | 1 | 45+1 Cornet | | Half-time: | 1-1 | | Referee: | Pinto Correia 6½ | | Attendance: | 45,048 | | Possession: | 52%-48% | | Total shots: | 15-11 | | MoM: | Caqueret |
| | 59 Vanaken | | (4-3-3): Turati 6½, Dubois 7, Chilwell 7½, Caqueret 8, Danilo 7, Chambers 6, Tousart 6½ (71 Scarlett 6), Cornet 7½, Diallo 6½, Vanaken 7, Marcos Leonardo 6 | | Marseille | 2 | 31 N'Jie, 71 Sánchez |
| | (4-3-3): Mandanda 7, Sarr 7, Nuno Tavares 8, Gerson 6½, Gigot 7 (72 Ben Seghir 6), Payet 6, Strootman 7, Sánchez 7½, N'Jie 6, Sanson 6, Dieng 6 | | Real Madrid | 2 | 17 Nacho, 45+1 Djuricic | |
| | (4-3-3): Lunin 6½, Nacho 6½, Marcelo 7, Vecino 7, Jesús Vallejo 7½, Rafa 6, Weiser 7, Djuricic 7, Mariano 6½, Ramsey 6½, Giovinco 6½ | | Independiente | 2 | 49 Sottil, 66 Cervi |
| | (4-3-3): Campaña 7, Rosier 7, Alonso 7½, Sottil 7½, Martínez Quarta 7½, Rojo 7, Vecchio 6½, Cervi 6, Benedetto 6½, Meza 7, Pavón 6 | | Torino | 2 | 65 Rodriguez, 84 Zappacosta | | Half-time: | 0-2 | | Referee: | Levnikov 7½ | | Attendance: | 27,950 | | Possession: | 45%-55% | | Total shots: | 16-14 | | MoM: | Kjær | | TV: | highlights |
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| | (4-3-3): Milinkovic-Savic 6, Zappacosta 7½, Rodriguez 7½, Traoré 6½, Izzo 7, Djidji 6½, Pussetto 6½, Danjuma 6½, Sanabria 6 (76 Baselli 7), Verdi 7, Álex Berenguer 6 | | Milan | 2 | 14 Zaccagni, 40 Kjær | | 28 Bennacer | | (4-3-3): Diego López 6½, Ricardo Pereira 7, Aina 6½, Bennacer 6½ (47 Thauvin 7), Kjær 7½, Umtiti 7½, Suso 7½, Zaccagni 6½, Origi 7, Santamaría 7, Niang 6 | | Valencia | 1 | 53 Maranhão | | Half-time: | 0-0 | | Referee: | McCluskey 7 | | Attendance: | 34,605 | | Possession: | 51%-49% | | Total shots: | 15-14 | | MoM: | Romero | | TV: | highlights |
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| | (4-3-3): Romero 8½, De Marcos 6½ (77 Cömert 6½), Samuel Lino 8, Parejo 7, Pepe 6½, Gabriel Paulista 7, Coquelin 7, Nani 7, Maranhão 7, Ilaix 7, Hugo Duro 7 | | Lokomotiv | 0 |
| | 24 Golovin, 64 Jedvaj | | (4-3-3): Guilherme 7½, Jedvaj 6½, Denisov 6½ (68 Lebedenko 6), Miranchuk 7, Bijol 7½, Magkeev 6, Isidor 6½, Golovin 6½, Smolov 7, Éder 5½, Lysov 6 | | West Ham United | 3 | 10 Lanzini, 34 Hernández, 62 Van Bergen | | Half-time: | 2-0 | | Referee: | Young 6 | | Attendance: | 25,964 | | Possession: | 44%-56% | | Total shots: | 12-12 | | MoM: | Mendy |
| | 16 Zouma, 42 Van Bergen | | (4-3-3): Vicente Guaita 6, Johnson 6½, Masuaku 6, Partey 7, Zouma 7, Diop 7, Helinho 6½, Lanzini 7, Hernández 6½, Obiang 7½, Van Bergen 5½ | | Monaco | 2 | 55og Partey, 82 Pepê | | 57 Ben Yedder | | (4-3-3): Lecomte 6½, Touré 7, Mendy 8, Camara 7 (58 Adrien Silva 7), Maripán 6½, Glik 7½, Sissoko 7, Pepê 7½, Ben Yedder 6½, Diatta 5, Baldé 6½ | | Round 3 | | Celta Vigo | 1 | 88 Murillo | | Half-time: | 0-1 | | Referee: | Ducrocq 8 | | Attendance: | 32,674 | | Possession: | 42%-58% | | Total shots: | 8-20 | | MoM: | Zaccagni |
| | 9 Sisto, 73 Gueye | | (4-3-3): Blanco 5½, Sergi Roberto 7, Javi Galán 7, Gueye 7½, Llorente 6½, Araujo 6, Solari 6½, Sisto 6½, Larsen 6½ (76 Murillo 6), Óscar 6, Jonathan Cafú 5½ | | Milan | 2 | 43 Zaccagni, 90+3 Origi | | 71 Kjær | | (4-3-3): Diego López 6½, Ricardo Pereira 7, Aina 5½, Bennacer 7 (47 Thauvin 8), Kjær 6, Umtiti 7, Suso 7½, Zaccagni 8, Origi 7½, Santamaría 6, Niang 6½ | | Athletic Bilbao | 1 | 10 Muniain | | Half-time: | 1-0 | | Referee: | Martin Navarrete 7 | | Attendance: | 39,740 | | Possession: | 58%-42% | | Total shots: | 14-9 | | MoM: | Shaw |
| | 73 Vivian | | (4-3-3): Agirrezabala 7½, Lekue 6½ (50 Kurzawa 7), Matviyenko 8, Vesga 8, Vivian 7½, Yeray 6½, Feghouli 7½, Muniain 7, Guruzeta 7½, Dzyuba 6½, Villalibre 6 | | Shakhtar | 0 |
| | 77 Szczesny | | (4-3-3): Szczesny 7, Zeki 7, Shaw 8, Zambo Anguissa 6, Savic 6, Tiago Djaló 6, Casemiro 6, De Bruyne 7, Abraham 6½, Podence 6, Martial 6½ | | Lyon | 1 | 37 Cornet | | Half-time: | 1-1 | | Referee: | Detruche 6½ | | Attendance: | 33,281 | | Possession: | 53%-47% | | Total shots: | 15-11 | | MoM: | Chilwell |
| | 7 Vanaken, 33 Cornet, 61 Danilo | | (4-3-3): Turati 6½, Dubois 5½, Chilwell 8, Caqueret 7½, Danilo 7, Chambers 6, Tousart 6½ (69 Scarlett 6), Cornet 7, Diallo 7½, Vanaken 7, Marcos Leonardo 6 | | Monaco | 2 | 10 Ben Yedder, 62p Ben Yedder |
| | (4-3-3): Lecomte 7, Touré 7 (78 Adrien Silva 6), Mendy 7, Camara 7½, Maripán 7 (73 Rony Lopes 6), Glik 7, Sissoko 7, Pepê 6½, Ben Yedder 7½, Diatta 6, Baldé 5½ | | Atlético-MG | 3 | 31 Renato Augusto, 83 Maicon, 86 Éverton Ribeiro | | Half-time: | 1-2 | | Referee: | Piller 6 | | Attendance: | 24,762 | | Possession: | 51%-49% | | Total shots: | 10-14 | | MoM: | Henrique |
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| | (4-3-3): Ustari 6½, Guga 6½, Henrique 8, Soriano 7, Murilo Cerqueira 6½, Maicon 6½, Róger 7½, Éverton Ribeiro 7½, Dodds 5½, Renato Augusto 5½ (65 Maicon 6½), Willian 6 | | Ajax | 2 | 8 Furuhashi, 33 Sierhuis |
| | (4-3-3): Trapp 6½, Cuadrado 7½, Denswil 7½, Wendel 7, Veltman 6½, Fofana 6, Danilo 6, Promes 7, Sierhuis 7, Chiquinho 6½, Furuhashi 6 |
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