| Round 5 | | Chelsea | 0 |
| | Half-time: | 0-0 | | Referee: | Magerman 8 | | Attendance: | 37,800 | | Possession: | 39%-61% | | Total shots: | 4-13 | | MoM: | Muñoz |
| | 58 Bednarek | | (4-3-3): Hrádecký 8, Tavernier 7, Williams 6, Loftus-Cheek 6, Bednarek 6, Çaglar 6, Bamba 6, Pedro 6, Batshuayi 7, Adams 6, Richarlison 6½ | | Real Sociedad | 0 |
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| | (4-3-3): Zubikarai 7½, Thierry Correia 6½, Muñoz 8, Guridi 6½, Martínez 6½, Diego Rico 6½, Portu 7, Samu Castillejo 5½, Roberto López 7, Januzaj 5½, Vela 7½ | | Dinamo Zagreb | 2 | 19 Petkovic, 51 Petkovic | | Half-time: | 1-2 | | Referee: | Braamhaar 7 | | Attendance: | 34,548 | | Possession: | 48%-52% | | Total shots: | 11-16 | | MoM: | Petkovic | | TV: | highlights |
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| | (4-3-3): Lindner 4½, Théophile-Catherine 7, Rakitskyi 7½, Ljubicic 7, Sutalo 6, Peric 6 (80 Baturina 6), Moharrami 7½, Orsic 7, Petkovic 8, Andric 5½, Drmic 6½ | | Sporting | 3 | 14 Douglas Luiz, 45+1 Bentancur, 46 Gonçalo Ramos | | 1 Gonçalo Ramos, 25 Gabriel, 57 Gabriel, 76 Diogo Costa | | (4-3-3): Diogo Costa 5, Diogo Dalot 7, João Cancelo 7½, Douglas Luiz 6½, Tapsoba 7, Gabriel 6½, Bentancur 7, Brandt 6½, Gonçalo Ramos 7, Nico Williams 7, Pedro Gonçalves 6½ | | Fenerbahçe | 1 | 37 Muriqi | | Half-time: | 1-1 | | Referee: | Vink 6 | | Attendance: | 46,647 | | Possession: | 57%-43% | | Total shots: | 22-14 | | MoM: | Szalai |
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| | (4-3-3): Altay 7, Tisserand 7½, Ridvan 7½, Haidara 7½, Szalai 8½, Luan Peres 7½, Mert Hakan 6½ (83 Sener 6), Mor 6½, Muriqi 7, Slimani 6, Dursun 6 | | Hertha BSC Berlin | 1 | 22 Darida | | 40 Darida | | (4-3-3): Christensen 7, Maffeo 7, Jung 7, Darida 7, Rekik 6½, Gechter 6½, Redan 6, Dilrosun 6½, Selke 7, Kanga 5½, Ngankam 6 | | Feyenoord | 1 | 18 Malacia | | Half-time: | 1-1 | | Referee: | Fröhlich 7½ | | Attendance: | 47,308 | | Possession: | 52%-48% | | Total shots: | 22-17 | | MoM: | Malacia | | TV: | highlights |
| | 30 Giménez | | (4-3-3): Marciano 6½, Nieuwkoop 6½, Malacia 8, Timber 7, Hancko 7½, Trauner 6½, Wieffer 6½ (75 Sinisterra 7), Igor Paixâo 7, Pellé 7½, Vilhena 5½, Giménez 6 | | Hamburger SV | 2 | 40 Sala, 87 Mangala | | 38 Borré | | (4-3-3): Müller 6½, Sala 7, Kostic 6½, Endo 7, Mavropanos 7½, Papastathopoulos 6½, Lukebakio 7½, Jairo 6, Piatek 6½, Mangala 6½, Borré 6 | | Fiorentina | 1 | 27 Arthur | | Half-time: | 1-0 | | Referee: | Artur 7 | | Attendance: | 40,367 | | Possession: | 57%-43% | | Total shots: | 20-10 | | MoM: | Rodríguez |
| | 28 Zakaria, 43 Ikoné | | (4-3-3): Bravo 7½, Dodô 8, Marusic 6½, Rodríguez 8, Mancini 8, Senesi 6½, Castrovilli 7, Ikoné 7½, Arthur 7, Zakaria 7, Rebic 6½ | | Parma | 0 |
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| | (4-3-3): Sepe 7, Candreva 6½, Darmian 7½, Bernabé 6½, Masiello 7½, Circati 6½, Valiani 5½, Mounier 6, Okaka 6, Zé Eduardo 6, Sits 6 | | Grêmio | 2 | 11 Zé Rafael, 45 Bitello | | Half-time: | 2-0 | | Referee: | Sarvan 7 | | Attendance: | 36,035 | | Possession: | 60%-40% | | Total shots: | 15-5 | | MoM: | Bitello |
| | 89 Raúl García | | (4-3-3): Éverson 7½, Fagner 7, Reinaldo 7½, Bitello 7½, Rodrigo Caio 7, Nathan 7, Villasanti 7½, Zé Rafael 7½, Raúl García 6½, Carballo 7, Ferreira 6 | | CSKA | 0 |
| | 27 Ejuke, 30 Serderov, 84 Necid | | (4-3-3): Akinfeev 7½, Parshivlyuk 6½, Magnússon 6½, Oblyakov 7, Nababkin 7, Vasin 6½, Samedov 6, Ejuke 6, Necid 6, Mamaev 6½, Serderov 5½ | | IFK Göteborg | 0 |
| | Half-time: | 0-1 | | Referee: | Walton 8 | | Attendance: | 80,986 | | Possession: | 63%-37% | | Total shots: | 23-10 | | MoM: | Sané | | TV: | live |
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| | (4-2-3-1): Martínez 7, Di Lorenzo 6½, Akanji 8, Koke 8, Martínez 7, Romero 7, Kulusevski 7, Sané 8, Joelinton 6½, Rodri 7, Bruno Fernandes 6 | | Palmeiras | 2 | 37 Vitinho, 61 Vitinho |
| | (4-3-3): Weverton 7, Juninho Caiçara 6½, Douglas Santos 6½, Atuesta 7, Rodrigo Becão 7 (73 Piquerez 6), Gómez 7, Douglas 6, Vitinho 7, Deyverson 6, Chará 5½, Marquinhos Gabriel 5½ | | Rangers | 3 | 15 Itten, 25 Eze, 60 Eze | | Half-time: | 2-2 | | Referee: | Dinelli 7½ | | Attendance: | 34,013 | | Possession: | 42%-58% | | Total shots: | 11-19 | | MoM: | Amrabat |
| | 87 Itten | | (4-2-3-1): Benítez 6½, Juranovic 6½, Medina 6, Rice 6½, Guehi 6½, Diogo Leite 6½, Davis 7, Yusuf 6, Itten 6½, Eze 6½, Nkunku 5½ | | FC Utrecht | 2 | 35 Amrabat, 40 Kerk | | 30 Conboy, 59 Haller | | (4-3-3): Jensen 6½, Troupée 7, Bakker 7 (64 Hardeveld 6½), Amrabat 8, Van Der Maarel 7½, Conboy 6½, Berghuis 7½, Kerk 7, De Jong 7½, Haller 6½, Jørgensen 7½ | | Real Betis | 4 | 4 Rodri, 15 Dembélé, 27 Dembélé, 51 Loren | | Half-time: | 3-3 | | Referee: | Styles 6 | | Attendance: | 45,399 | | Possession: | 49%-51% | | Total shots: | 14-14 | | MoM: | Marcos Llorente |
| | 33 Ruibal, 66 Juan Cruz | | (4-3-3): Dani Martín 5½, Ruibal 6½, Bruno Peres 7, William Carvalho 7, Bartra 6, Édgar 6, Luiz Henrique 7, Dembélé 7½, Loren 6, Rodri 5 (54 Juan Cruz 7), López 6 | | Blackburn Rovers | 3 | 30 Malen, 39 Malen, 43 Pablo Fornals |
| | (4-3-3): Audero 5½, Ginter 7, Hysaj 6½, Can 7, Fabinho 6½, Boateng 7, Marcos Llorente 8, Malen 7, Calvert-Lewin 6½, Pablo Fornals 7, Santi Mina 6 | | Santos | 2 | 28 Felipe Anderson, 42 Matheuzinho | | Half-time: | 2-0 | | Referee: | Wieser 5½ | | Attendance: | 28,099 | | Possession: | 48%-52% | | Total shots: | 16-11 | | MoM: | Luiz |
| | 32 Matheuzinho, 45+1 Gabriel, 67 Gustavo Henrique | | (4-3-3): Vanderlei 7, Matheuzinho 6½, Caio 7½, Lucas Braga 6 (66 Luiz 8), Gustavo Henrique 7, Samir 6½, Auro 7 (85 Marinho 6), Felipe Anderson 7, Bacca 6½, González 6, Gabriel 6½ | | 1.FC Köln | 1 | 82 Hübers |
| | (4-3-3): Horn 7, Wolf 7, Jakobs 7, Skhiri 7, Hübers 6½, Soldo 7, Lemperle 6, Kainz 7, Modeste 6½, Rexhbecaj 6½, Duda 6 | | TSG Hoffenheim | 1 | 21p Kalajdzic | | Half-time: | 1-0 | | Referee: | Hansson 6 | | Attendance: | 4,914 | | Possession: | 59%-41% | | Total shots: | 17-13 | | MoM: | Kluivert |
| | 82 Evanilson | | (4-3-3): Baumann 7, Montiel 8, Wendell 7, McKennie 8, Smalling 7½, Klostermann 6, Skov Olsen 7, Kluivert 8, Kalajdzic 7, Vinicius 6, Evanilson 7 | | Auxerre | 1 | 48 Merdji |
| | (4-3-3): Costil 6½, Clauss 7, Machado 6½, Dja Djedje 6½, Da Silva 7, Jemerson 6½, Basic 6, Hein 7, Merdji 7, Coeff 5½, Kamano 5½ | | Round 3 | | Chelsea | 1 | 3 Pedro | | | 13 Adams | | (4-3-3): Hrádecký 7½, Tavernier 8, Williams 7, Loftus-Cheek 6½ (84 Chalobah 6), Bednarek 7½, Çaglar 7, Bamba 7, Pedro 6½, Batshuayi 7, Adams 6, Richarlison 6½ | | 1.FC Köln | 0 |
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| | (4-3-3): Horn 7, Wolf 7, Jakobs 7, Skhiri 7½, Hübers 7, Soldo 6½, Lemperle 7½, Kainz 6½, Modeste 8, Neuhaus 6, Duda 6 | | Round 4 | | FC Utrecht | 0 |
| | Half-time: | 0-0 | | Referee: | Sandra 5 | | Attendance: | 23,600 | | Possession: | 53%-47% | | Total shots: | 13-9 | | MoM: | Kerk |
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| | (4-3-3): Jensen 6½, Troupée 6½, Bakker 7½, Amrabat 8, Van Der Maarel 7½, Conboy 6½, Berghuis 6½, Kerk 8, De Jong 7, Haller 6, Jørgensen 6 | | Dinamo Zagreb | 1 | 74 Rakitskyi |
| | (4-3-3): Lindner 7, Théophile-Catherine 6, Rakitskyi 7½, Ljubicic 8, Sutalo 7 (75 Baturina 6), Peric 6½, Moharrami 6½, Orsic 7½, Petkovic 6, Andric 6, Drmic 6½ | | Sporting | 3 | 13 Nico Williams, 40 Tapsoba, 90 Pedro Gonçalves | | Half-time: | 2-0 | | Referee: | Arena 6½ | | Attendance: | 62,552 | | Possession: | 50%-50% | | Total shots: | 12-7 | | MoM: | Diogo Costa |
| | 47 Gonçalo Ramos, 55 Gabriel, 88 Bentancur | | (4-3-3): Diogo Costa 8, Diogo Dalot 7½, João Cancelo 7½, Douglas Luiz 7, Tapsoba 6½, Gabriel 7, Bentancur 7, Brandt 6½, Gonçalo Ramos 7½, Nico Williams 6½, Pedro Gonçalves 6½ | | Feyenoord | 0 |
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| | (4-3-3): Marciano 7, Nieuwkoop 7, Malacia 7, Timber 7, Hancko 7, Trauner 6, Wieffer 7 (64 Van Beek 5½), Igor Paixâo 6½, Pellé 6½, Vilhena 5½, Giménez 6 |
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