| Round 5 | | Benfica | 0 |
| | Half-time: | 0-1 | | Referee: | Penicka 7 | | Attendance: | 64,834 | | Possession: | 51%-49% | | Total shots: | 14-8 | | MoM: | Raspadori | | TV: | live |
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| | (4-3-3): Remiro 6½, Pedro Porro 7½, Nuno Mendes 6½, Thuram-Ulien 7 (61 Wind 7½), Araújo 6½ (71 Ferguson 6), António Silva 5, Torres 7½, González 7½, Raspadori 8, Sancet 6½, Wahi 6½ | | SC Heerenveen | 1 | 38 Mitchell | | 54 Simons, 71 Hincapié | | (4-1-3-2): Arrizabalaga 7, Baku 7½, Mitchell 7½, Hincapié 6½, Thiaw 7, Mikel Merino 7, Chukwueze 7½, Aouar 6, Moffi 7½, Simons 6, Rafael Leão 7 | | Club Brugge | 1 | 66 Buchanan | | Half-time: | 0-0 | | Referee: | Nardi 7 | | Attendance: | 28,878 | | Possession: | 56%-44% | | Total shots: | 15-11 | | MoM: | Mechele |
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| | (4-3-3): Mignolet 7½, Boyata 7½, Meijer 7, Faes 7, Mechele 8½, Nielsen 7½, Skóras 7, Buchanan 8, Thiago 6½, Vetlesen 5½, Balanta 5½ | | Kaiserslautern | 0 |
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| | (4-3-3): Sippel 7½, Beyer 7½, Bensebaini 6½, Ilic 6½ (59 Lainer 7), Friedrich 7½, N'Soki 7, Kramer 6, Zuck 6½, Boyd 7, Ritter 6, Zolinski 5½ | | Espanyol | 1 | 45 Joselu | | Half-time: | 1-1 | | Referee: | Gumienny 6½ | | Attendance: | 38,144 | | Possession: | 46%-54% | | Total shots: | 13-20 | | MoM: | Melendo |
| | 61 Melendo | | (4-3-3): Álvaro 6, Óscar Gil 6½, Adrià Pedrosa 7, Melendo 7½, Roco 7, Arbilla 6½, Vinicius Souza 6, Koleosho 7, Joselu 7, Bare 6½, Caicedo 7 | | Leeds United | 2 | 42 Antonio, 62 Antonio |
| | (4-3-3): Joel 6½, Kristensen 6½, Struijk 6½, Dallas 6½, Koch 6½ (59 Drameh 7), Cooper 6, Aaronson 6½, Harrison 6½, Antonio 7, Rutter 6, Bamford 7 | | Hansa Rostock | 0 |
| | Half-time: | 0-0 | | Referee: | Cesari 6 | | Attendance: | 28,836 | | Possession: | 44%-56% | | Total shots: | 12-8 | | MoM: | Kübler |
| | 12 Brenet, 34 Suárez, 64 Arnautovic | | (4-3-3): Unnerstall 7, Kübler 8, Nkounkou 7, Karazor 7½, Brooks 7, Godfrey 7 (60 Stark 6½), Aránguiz 7, Arnautovic 7½, Brenet 6, De Sart 6½, Suárez 6½ | | Lille | 1 | 80 Weah |
| | (4-3-3): Grbic 7, Zedadka 7, Bard 7, André 7, Diakité 6½, Yoro 6, Lihadji 6, Cabella 7, Weah 7 (81 Bayo 6), De Wit 6½, Sotoca 6 | | Middlesbrough | 3 | 33 Latte Lath, 71 Latte Lath, 82 Latte Lath | | Half-time: | 1-0 | | Referee: | Knight 5½ | | Attendance: | 21,855 | | Possession: | 38%-62% | | Total shots: | 7-12 | | MoM: | Cristaldo |
| | 4 Lenihan, 50 McGree | | (4-3-3): Dieng 6½, Jones 7, Coulson 6½, Crooks 7, McNair 5½ (78 Smith 6), Lenihan 6, Howson 6½, Willis 6½, Latte Lath 7, McGree 6, Rogers 6 | | Vélez Sársfield | 1 | 79 Cristaldo | | 31 Ramírez, 68 De Los Santos, 76 Calleri | | (4-3-3): Rulli 7, Fernández 8, García 7½, Florentín 7, Izquierdoz 7½, De Los Santos 7 (81 Guidara 6), Cristaldo 8½, Ramírez 7½, Calleri 7, Di Santo 6, Bou 7 | | Rayo Vallecano | 3 | 2 Unai López, 4 Falcao, 24og Pléa | | Half-time: | 3-0 | | Referee: | Ziller 6 | | Attendance: | 14,689 | | Possession: | 51%-49% | | Total shots: | 12-10 | | MoM: | Trejo | | TV: | highlights |
| | 9 Isi Palazón | | (4-3-3): Dimitrievski 7½, Iván 7, Álvaro 6, Óscar Valentín 7½, Catena 7, Mumin 6½, Trejo 8, Isi Palazón 7, Falcao 5½ (68 Bebé 7), Unai López 7, Andrés 6 | | Karlsruher SC | 0 |
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| | (4-3-3): Olschowsky 7, Kaderábek 8, Heise 6, Laimer 7½, André 7, Dragovic 5½, Pléa 6, Schleusener 7 (62 Koné 6), Matanovic 6½, Demirbay 6, Brosinski 6 | | SV Werder Bremen | 1 | 55og Latza | | Half-time: | 0-2 | | Referee: | Strampe 7 | | Attendance: | 33,553 | | Possession: | 56%-44% | | Total shots: | 18-4 | | MoM: | Bailey |
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| | (4-3-3): Langer 6, Agu 8, Caldirola 7½, Klaassen 7, Pieper 7½, Moisander 7, Dinkçi 7½, Bailey 9, Füllkrug 8, Stage 7½, Bebou 7 | | FC Schalke 04 | 2 | 25 Bülter, 37 Aydin | | 71 Boujellab | | (4-3-3): Pavlenka 7, Kenny 6½, Mendyl 7 (47 Latza 6½), Mollet 7, Yoshida 6½, Matriciani 6, Aydin 6, Bülter 6, Flick 5½, Schöpf 6, Boujellab 6 | | Sevilla | 2 | 26 Lamela, 64 Amadou | | Half-time: | 1-2 | | Referee: | Foy 6 | | Attendance: | 31,733 | | Possession: | 55%-45% | | Total shots: | 14-12 | | MoM: | Lamela |
| | 17 Navas, 33 Aleix Vidal | | (4-3-3): Mamardashvili 6, Navas 7, Marc Cucurella 7, Banega 7, Mercado 7, Gnagnon 6, Aleix Vidal 6½, Lamela 7½, Celar 7½, Amadou 6 (81 Vázquez 6), Idrissi 6 | | Mallorca | 2 | 10 De Sciglio, 15 De Sciglio |
| | (4-3-3): Iago 7, Corchia 6, De Sciglio 7½, Baba 6½, Valjent 6, Dresevic 6½, Joaquín 6, Tello 6½, Prats 6½, Ruiz De Galarreta 7 (65 André Gomes 7), Kadewere 6½ | | Udinese | 1 | 18 Beto | | Half-time: | 1-2 | | Referee: | Hill 6 | | Attendance: | 41,749 | | Possession: | 51%-49% | | Total shots: | 12-12 | | MoM: | Barák |
| | 22 Zapata | | (4-3-3): Skorupski 5, Ehizibue 6, Pérez 5½, Barák 8, Rrahmani 6½, Zapata 6½, Ebosele 6, Gerard 6½, Beto 7½, Pereyra 6½, Muriel 6½ (74 Shomuradov 7) | | Aston Villa | 3 | 17 Traoré, 32 Watkins, 79 Maatsen | | 3 Ramsey | | (4-3-3): Olsen 6½, Cash 7½, Maatsen 7, McGinn 7½, Mings 6½, Lenglet 6½, Traoré 7, Pereira 7½, Watkins 7, Ramsey 6½, Durán 6½ | | VfB Stuttgart | 1 | 19 Weghorst | |
| | (4-3-3): Fährmann 6, Jérez 7½, Marcano 7½, Berkay 7½, Vogt 7, Schlotterbeck 5½, Didavi 7½, Rodríguez 8, Weghorst 6½ (72 Schmitz 7), Ascacíbar 7½, Carlos Fernández 5½ | | AIK | 3 | 5 Sarr, 29 Larsson, 84 Sarr | | 21 Ajeti | | (4-3-3): Omlin 6, Xhaka 6½, Kahl 7½, Hussein 7, Helander 7½, Tihi 6½, Larsson 6½, Zuber 6½, Larsson 6½, Ajeti 5½, Sarr 5½ | | Zaragoza | 1 | 5 Williams | | Half-time: | 1-1 | | Referee: | Reijgwart 6½ | | Attendance: | 34,421 | | Possession: | 45%-55% | | Total shots: | 15-10 | | MoM: | Isco |
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| | (4-3-3): Álvarez 6, Wass 7½, Marcos Alonso 6½ (52 Espino 6), Luis Alberto 6½, Aidoo 6½, Ruíz 6½, Isco 8, Williams 6½, Milik 7½, Inui 6½, Poulsen 7 | | São Paulo | 2 | 22 David, 70 David | | 53 Lucas Beraldo | | (4-3-3): Jean Paulo 6½, Marcos Rocha 7 (78 Mariano 7), Welington 7, Igor Gomes 6½, Lucas Beraldo 7, Arboleda 6, Vítor 7½, David 7, Marcelo Moreno 7, Luan 7, Luciano 6½ | | Round 4 | | Mallorca | 2 | 36 Tello, 60 Tello | | Half-time: | 1-0 | | Referee: | Damgaard 7 | | Attendance: | 24,917 | | Possession: | 51%-49% | | Total shots: | 11-7 | | MoM: | Karazor |
| | 16 Corchia | | (4-3-3): Iago 6, Corchia 7, De Sciglio 7, Baba 7, Valjent 7, Copete 6½, Joaquín 7, Tello 7, Prats 6½, Ruiz De Galarreta 6 (78 Dresevic 6), Kadewere 6½ | | Hansa Rostock | 1 | 82 Godfrey | | 47 Karazor | | (4-3-3): Unnerstall 7½, Kübler 7, Nkounkou 7½, Karazor 7½, Brooks 7, Stark 6½, Aránguiz 7 (56 Godfrey 7), Arnautovic 6½, Brenet 6, Kampl 6, Suárez 6 | | Round 3 | | Espanyol | 1 | 90+4 Javi Puado | | Half-time: | 0-0 | | Referee: | Borja 8½ | | Attendance: | 33,131 | | Possession: | 47%-53% | | Total shots: | 15-14 | | MoM: | Cristaldo |
| | 21 Javi Puado, 36 Arbilla, 63 Joselu, 65 Melendo | | (4-3-3): Álvaro 7, Óscar Gil 7, Adrià Pedrosa 6½, Vinicius Souza 7, Roco 7, Arbilla 6½ (78 Bare 6), Melendo 6½, Koleosho 6½, Joselu 6½, Caicedo 6½, Javi Puado 6 | | Vélez Sársfield | 0 |
| | 6 Izquierdoz, 7 Ortega, 84 Calleri | | (4-3-3): Rulli 8, Fernández 7½, García 7½, Florentín 6½, Izquierdoz 6½, De Los Santos 6½, Cristaldo 8, Ramírez 7 (69 Giannetti 6), Calleri 7½, Ortega 5½, Bou 6 |
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