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| Round 1 (22) Ajax - FC Schalke 04 Aston Villa - Borussia Dortmund Barcelona - Real Madrid Bayer Leverkusen - Bayern München Boca Juniors - Lyon Deportivo - FC Porto Feyenoord - Paris SG Independiente - Liverpool Manchester City - Flamengo Marseille - Sporting Braga Newcastle United - RB Leipzig | Round 2 (23) Bayern München - Aston Villa Borussia Dortmund - Ajax FC Porto - Independiente FC Schalke 04 - Marseille Flamengo - Bayer Leverkusen Liverpool - Deportivo Lyon - Newcastle United Paris SG - Boca Juniors RB Leipzig - Feyenoord Real Madrid - Manchester City Sporting Braga - Barcelona |
| Round 3 (24) Ajax - Liverpool Aston Villa - Lyon Barcelona - FC Schalke 04 Bayer Leverkusen - RB Leipzig Boca Juniors - Real Madrid Deportivo - Flamengo Feyenoord - Bayern München Independiente - Paris SG Manchester City - Sporting Braga Marseille - Borussia Dortmund Newcastle United - FC Porto | Round 4 (25) Bayern München - Boca Juniors Borussia Dortmund - Manchester City FC Porto - Marseille FC Schalke 04 - Bayer Leverkusen Flamengo - Independiente Liverpool - Feyenoord Lyon - Barcelona Paris SG - Newcastle United RB Leipzig - Deportivo Real Madrid - Ajax Sporting Braga - Aston Villa |
| Round 5 (26) Ajax - Paris SG Aston Villa - FC Porto Barcelona - Liverpool Bayer Leverkusen - Real Madrid Boca Juniors - Sporting Braga Deportivo - Lyon Feyenoord - Flamengo Independiente - Bayern München Manchester City - FC Schalke 04 Marseille - RB Leipzig Newcastle United - Borussia Dortmund | Round 6 (27) Ajax - FC Porto Aston Villa - Bayer Leverkusen Barcelona - Marseille Bayern München - Lyon Boca Juniors - Manchester City Deportivo - Feyenoord FC Schalke 04 - Real Madrid Flamengo - RB Leipzig Newcastle United - Independiente Paris SG - Liverpool Sporting Braga - Borussia Dortmund |
| Round 7 (28) Bayer Leverkusen - Barcelona Borussia Dortmund - FC Schalke 04 FC Porto - Paris SG Feyenoord - Newcastle United Independiente - Deportivo Liverpool - Bayern München Lyon - Flamengo Manchester City - Aston Villa Marseille - Boca Juniors RB Leipzig - Ajax Real Madrid - Sporting Braga | Round 8 (29) Ajax - Marseille Aston Villa - Barcelona Bayer Leverkusen - Boca Juniors Borussia Dortmund - Feyenoord Deportivo - Newcastle United FC Schalke 04 - Sporting Braga Flamengo - Bayern München Independiente - Manchester City Liverpool - FC Porto Paris SG - Real Madrid RB Leipzig - Lyon |
| Round 9 (30) Barcelona - Ajax Bayern München - RB Leipzig Boca Juniors - Aston Villa FC Porto - FC Schalke 04 Feyenoord - Independiente Lyon - Liverpool Manchester City - Bayer Leverkusen Marseille - Deportivo Newcastle United - Flamengo Real Madrid - Borussia Dortmund Sporting Braga - Paris SG | Round 10 (31) Bayern München - Marseille Deportivo - Bayer Leverkusen FC Porto - Manchester City Feyenoord - Aston Villa Flamengo - Ajax Independiente - Barcelona Liverpool - Sporting Braga Lyon - Real Madrid Newcastle United - Boca Juniors Paris SG - FC Schalke 04 RB Leipzig - Borussia Dortmund |
| Round 11 (32) Ajax - Independiente Aston Villa - Paris SG Barcelona - RB Leipzig Bayer Leverkusen - FC Porto Boca Juniors - Feyenoord Borussia Dortmund - Liverpool FC Schalke 04 - Deportivo Manchester City - Newcastle United Marseille - Flamengo Real Madrid - Bayern München Sporting Braga - Lyon | Round 12 (33) Ajax - Bayern München Aston Villa - Newcastle United Barcelona - FC Porto Bayer Leverkusen - Liverpool Boca Juniors - Deportivo Borussia Dortmund - Lyon FC Schalke 04 - Independiente Manchester City - Feyenoord Marseille - Paris SG Real Madrid - Flamengo Sporting Braga - RB Leipzig |
| Round 13 (34) Bayern München - FC Schalke 04 Deportivo - Manchester City FC Porto - Borussia Dortmund Feyenoord - Ajax Flamengo - Sporting Braga Independiente - Aston Villa Liverpool - Boca Juniors Lyon - Marseille Newcastle United - Barcelona Paris SG - Bayer Leverkusen RB Leipzig - Real Madrid | Round 14 (35) Ajax - Deportivo Aston Villa - Liverpool Barcelona - Bayern München Bayer Leverkusen - Feyenoord Boca Juniors - RB Leipzig Borussia Dortmund - Flamengo FC Schalke 04 - Lyon Manchester City - Paris SG Marseille - Newcastle United Real Madrid - Independiente Sporting Braga - FC Porto |
| Round 15 (36) Bayern München - Sporting Braga Deportivo - Aston Villa FC Porto - Real Madrid Feyenoord - Marseille Flamengo - Barcelona Independiente - Boca Juniors Liverpool - Manchester City Lyon - Ajax Newcastle United - Bayer Leverkusen Paris SG - Borussia Dortmund RB Leipzig - FC Schalke 04 | Round 16 (37) Ajax - Newcastle United Aston Villa - RB Leipzig Barcelona - Paris SG Bayer Leverkusen - Independiente Boca Juniors - FC Porto Borussia Dortmund - Bayern München FC Schalke 04 - Flamengo Manchester City - Lyon Marseille - Liverpool Real Madrid - Feyenoord Sporting Braga - Deportivo |
| Round 17 (38) Ajax - Sporting Braga Aston Villa - Flamengo Barcelona - Borussia Dortmund Bayer Leverkusen - Lyon Boca Juniors - FC Schalke 04 Deportivo - Paris SG Feyenoord - FC Porto Independiente - RB Leipzig Manchester City - Bayern München Marseille - Real Madrid Newcastle United - Liverpool | Round 18 (39) Aston Villa - Real Madrid Bayer Leverkusen - Borussia Dortmund Boca Juniors - Ajax Deportivo - Barcelona FC Porto - Flamengo Feyenoord - Lyon Independiente - Marseille Liverpool - FC Schalke 04 Manchester City - RB Leipzig Newcastle United - Sporting Braga Paris SG - Bayern München |
| Round 19 (40) Ajax - Aston Villa Barcelona - Feyenoord Bayern München - FC Porto Borussia Dortmund - Deportivo FC Schalke 04 - Newcastle United Flamengo - Boca Juniors Lyon - Independiente Marseille - Manchester City RB Leipzig - Paris SG Real Madrid - Liverpool Sporting Braga - Bayer Leverkusen | Round 20 (41) Aston Villa - FC Schalke 04 Bayer Leverkusen - Marseille Boca Juniors - Barcelona Deportivo - Real Madrid FC Porto - RB Leipzig Feyenoord - Sporting Braga Independiente - Borussia Dortmund Liverpool - Flamengo Manchester City - Ajax Newcastle United - Bayern München Paris SG - Lyon |
| Round 21 (42) Ajax - Bayer Leverkusen Barcelona - Manchester City Bayern München - Deportivo Borussia Dortmund - Boca Juniors FC Schalke 04 - Feyenoord Flamengo - Paris SG Lyon - FC Porto Marseille - Aston Villa RB Leipzig - Liverpool Real Madrid - Newcastle United Sporting Braga - Independiente | |
| League rounds 22-42 (in brackets) are the respective return ties of rounds 1-21 above, i.e. round 42 is Aston Villa - Marseille, Bayer Leverkusen - Ajax etc. | |