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| Round 1 (22) Ajax - Napoli Bayern München - Manchester City Boca Juniors - Flamengo Chelsea - Deportivo FC Basel - Paris SG FC Porto - Lyon Feyenoord - FC Schalke 04 Liverpool - Borussia Dortmund Manchester United - Barcelona Marseille - Real Madrid Sporting Braga - Aston Villa | Round 2 (23) Aston Villa - Bayern München Barcelona - Ajax Borussia Dortmund - Manchester United Deportivo - Boca Juniors FC Schalke 04 - FC Porto Flamengo - Marseille Lyon - Liverpool Manchester City - Sporting Braga Napoli - FC Basel Paris SG - Feyenoord Real Madrid - Chelsea |
| Round 3 (24) Ajax - Deportivo Bayern München - Real Madrid Boca Juniors - Aston Villa Chelsea - Lyon FC Basel - Manchester City FC Porto - Paris SG Feyenoord - Napoli Liverpool - FC Schalke 04 Manchester United - Flamengo Marseille - Barcelona Sporting Braga - Borussia Dortmund | Round 4 (25) Aston Villa - Feyenoord Barcelona - Chelsea Borussia Dortmund - Bayern München Deportivo - FC Porto FC Schalke 04 - Ajax Flamengo - Sporting Braga Lyon - FC Basel Manchester City - Marseille Napoli - Liverpool Paris SG - Manchester United Real Madrid - Boca Juniors |
| Round 5 (26) Ajax - Aston Villa Bayern München - Barcelona Boca Juniors - Napoli Chelsea - FC Schalke 04 FC Basel - Real Madrid FC Porto - Manchester City Feyenoord - Flamengo Liverpool - Paris SG Manchester United - Lyon Marseille - Borussia Dortmund Sporting Braga - Deportivo | Round 6 (27) Ajax - Manchester United Barcelona - Deportivo Boca Juniors - Bayern München Borussia Dortmund - Flamengo Chelsea - Liverpool FC Basel - Aston Villa FC Porto - Feyenoord FC Schalke 04 - Napoli Paris SG - Lyon Real Madrid - Manchester City Sporting Braga - Marseille |
| Round 7 (28) Aston Villa - Real Madrid Bayern München - Sporting Braga Deportivo - Borussia Dortmund Feyenoord - Chelsea Flamengo - FC Basel Liverpool - Ajax Lyon - FC Schalke 04 Manchester City - Barcelona Manchester United - FC Porto Marseille - Boca Juniors Napoli - Paris SG | Round 8 (29) Ajax - FC Porto Bayern München - Liverpool Borussia Dortmund - Barcelona FC Basel - Feyenoord Flamengo - Deportivo Manchester City - Aston Villa Manchester United - Chelsea Napoli - Marseille Paris SG - FC Schalke 04 Real Madrid - Lyon Sporting Braga - Boca Juniors |
| Round 9 (30) Aston Villa - Paris SG Barcelona - Flamengo Boca Juniors - Borussia Dortmund Chelsea - Ajax Deportivo - Manchester City FC Porto - FC Basel FC Schalke 04 - Real Madrid Feyenoord - Sporting Braga Liverpool - Manchester United Lyon - Napoli Marseille - Bayern München | Round 10 (31) Aston Villa - Liverpool Barcelona - Feyenoord Bayern München - FC Porto Boca Juniors - Chelsea Borussia Dortmund - FC Basel Deportivo - Lyon Flamengo - Napoli Manchester City - FC Schalke 04 Marseille - Ajax Real Madrid - Paris SG Sporting Braga - Manchester United |
| Round 11 (32) Ajax - Real Madrid Chelsea - Marseille FC Basel - Bayern München FC Porto - Flamengo FC Schalke 04 - Deportivo Feyenoord - Borussia Dortmund Liverpool - Boca Juniors Lyon - Barcelona Manchester United - Aston Villa Napoli - Manchester City Paris SG - Sporting Braga | Round 12 (33) Ajax - Boca Juniors Chelsea - Sporting Braga FC Basel - Barcelona FC Porto - Aston Villa FC Schalke 04 - Flamengo Feyenoord - Real Madrid Liverpool - Marseille Lyon - Borussia Dortmund Manchester United - Manchester City Napoli - Deportivo Paris SG - Bayern München |
| Round 13 (34) Aston Villa - Napoli Barcelona - Paris SG Bayern München - Ajax Boca Juniors - FC Porto Borussia Dortmund - FC Schalke 04 Deportivo - Feyenoord Flamengo - Lyon Manchester City - Chelsea Marseille - FC Basel Real Madrid - Manchester United Sporting Braga - Liverpool | Round 14 (35) Ajax - Manchester City Chelsea - Flamengo FC Basel - Sporting Braga FC Porto - Barcelona FC Schalke 04 - Aston Villa Feyenoord - Boca Juniors Liverpool - Real Madrid Lyon - Bayern München Manchester United - Marseille Napoli - Borussia Dortmund Paris SG - Deportivo |
| Round 15 (36) Aston Villa - Lyon Barcelona - FC Schalke 04 Bayern München - Chelsea Boca Juniors - Manchester United Borussia Dortmund - FC Porto Deportivo - FC Basel Flamengo - Paris SG Manchester City - Liverpool Marseille - Feyenoord Real Madrid - Napoli Sporting Braga - Ajax | Round 16 (37) Ajax - Flamengo Chelsea - Aston Villa FC Basel - Boca Juniors FC Porto - Real Madrid FC Schalke 04 - Sporting Braga Feyenoord - Manchester City Liverpool - Deportivo Lyon - Marseille Manchester United - Bayern München Napoli - Barcelona Paris SG - Borussia Dortmund |
| Round 17 (38) Ajax - Borussia Dortmund Bayern München - Flamengo Boca Juniors - Manchester City Chelsea - Paris SG FC Basel - FC Schalke 04 FC Porto - Napoli Feyenoord - Lyon Liverpool - Barcelona Manchester United - Deportivo Marseille - Aston Villa Sporting Braga - Real Madrid | Round 18 (39) Ajax - Lyon Aston Villa - Borussia Dortmund Bayern München - Feyenoord Boca Juniors - FC Schalke 04 Chelsea - FC Basel Liverpool - Flamengo Manchester City - Paris SG Manchester United - Napoli Marseille - Deportivo Real Madrid - Barcelona Sporting Braga - FC Porto |
| Round 19 (40) Barcelona - Aston Villa Borussia Dortmund - Chelsea Deportivo - Bayern München FC Basel - Ajax FC Porto - Marseille FC Schalke 04 - Manchester United Feyenoord - Liverpool Flamengo - Real Madrid Lyon - Manchester City Napoli - Sporting Braga Paris SG - Boca Juniors | Round 20 (41) Ajax - Paris SG Aston Villa - Flamengo Bayern München - Napoli Boca Juniors - Barcelona Chelsea - FC Porto Liverpool - FC Basel Manchester City - Borussia Dortmund Manchester United - Feyenoord Marseille - FC Schalke 04 Real Madrid - Deportivo Sporting Braga - Lyon |
| Round 21 (42) Barcelona - Sporting Braga Borussia Dortmund - Real Madrid Deportivo - Aston Villa FC Basel - Manchester United FC Porto - Liverpool FC Schalke 04 - Bayern München Feyenoord - Ajax Flamengo - Manchester City Lyon - Boca Juniors Napoli - Chelsea Paris SG - Marseille | |
| League rounds 22-42 (in brackets) are the respective return ties of rounds 1-21 above, i.e. round 42 is Ajax - Feyenoord, Aston Villa - Deportivo etc. | |