| Round 3 | | Arsenal | 2 | 10 Balogun, 70 Mayoral | | Half-time: | 1-2 | | Referee: | Rudy 5½ | | Attendance: | 38,371 | | Possession: | 57%-43% | | Total shots: | 17-5 | | MoM: | Mkhitaryan | | TV: | highlights |
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| | (4-3-3): Turner 6, Williams 6, Marcos Alonso 7½, Mkhitaryan 7½, Pablo 7½, De Winter 7, Fábio Vieira 7½, Grealish 7, Mayoral 6½, Xhaka 7½, Balogun 6½ | | Sevilla | 2 | 5 En-Nesyri, 45+2 Fran García | | 17 Jota | | (4-3-3): Dmitrovic 6½, Álex Sola 5½, Fran García 7, Jota 7½, Gudelj 6, Sergio Ramos 6½, Álex Pozo 6, Álex Moreno 6½ (59 Rafa Mir 7), En-Nesyri 6, Fernando 6, El Haddadi 7 (63 Pau Navarro 6) | | Aston Villa | 2 | 18 João Félix, 45 João Félix | | Half-time: | 2-1 | | Referee: | José Pratas 6½ | | Attendance: | 38,906 | | Possession: | 48%-52% | | Total shots: | 17-13 | | MoM: | Sanusi |
| | 57 Kolo-Muani | | (4-3-3): Pope 6½, McKennie 6½, Viña 7, Højbjerg 7, Mings 6½, Keane 6, Kjær 6, João Félix 6½, Abraham 6½, Ramsey 6, Kolo-Muani 6 | | FC Porto | 2 | 16 Pepê, 71og João Félix |
| | (4-3-3): Remiro 6½, Manafá 7, Sanusi 7½, Stephen Eustáquio 7, Danilo 6½, Otávio 6½, Nanu 6, Pepê 7, Willian 7, Uribe 6, Galeno 6½ (71 Mbemba 6) | | Chelsea | 1 | 22 Horta | | Half-time: | 1-1 | | Referee: | Krondl 6 | | Attendance: | 45,931 | | Possession: | 45%-55% | | Total shots: | 14-10 | | MoM: | Junior Firpo |
| | 7 Horta | | (4-3-3): Meslier 6, Chalobah 6, Junior Firpo 7½, William Carvalho 6½, Humphreys 6, Ricardo Esgaio 6, Horta 6½, João Pedro 6½, Jiménez 6½, Weghorst 5½, Pléa 6 | | Spartak | 1 | 44 Haraldsson |
| | (4-3-3): Aréola 6½, Reynolds 6½, Manu Sánchez 7, Pasalic 7½, Bednarek 7½, Bailly 6½, Moses 6, Haraldsson 7, Embolo 7, Nico 6½, Lee 6½ | | Napoli | 2 | 63 Fekir, 70 Retegui | | Half-time: | 0-1 | | Referee: | Huzu 7 | | Attendance: | 48,377 | | Possession: | 45%-55% | | Total shots: | 13-12 | | MoM: | Oriol Romeu | | TV: | highlights |
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| | (4-3-3): Pau López 6½, Zanoli 7, Friedl 7½, Oriol Romeu 8, Llorente 7½, Maksimovic 6½, Gonçalo Guedes 6 (63 Sensi 6½), Politano 6½, Fekir 6, Zerbin 5½, Retegui 6½ | | Villarreal | 2 | 7 Yéremy Pino, 68 Yéremy Pino |
| | (4-3-3): Jörgensen 6½, Traoré 6½, Moreno 6 (71 Jorge Cuenca 6), Manu Morlanes 8, Lenglet 7, Eder Militão 6½, Daramy 7, Yéremy Pino 7, Jackson 7, Sansone 6, Azmoun 6 | | Sassuolo | 2 | 11 Lopez, 60 Viti | | Half-time: | 1-0 | | Referee: | Michel 6½ | | Attendance: | 20,487 | | Possession: | 44%-56% | | Total shots: | 14-15 | | MoM: | Uduokhai |
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| | (4-3-3): De Gea 7, Pedersen 5½, Kolasinac 7, Bajrami 7½, Rrahmani 7, Viti 6½, Boloca 6, Samu Castillejo 7, Dovbyk 7, Lopez 6½, Raspadori 6½ | | Dundee United | 1 | 75 Berardi |
| | (4-3-3): Barkas 7½, Dodô 7½, Mykolenko 5½, Baumgartner 7½, Uduokhai 8, Davis 7, McCausland 7, Adeyemi 7½, Alario 6½ (46 Berardi 6½), Barrenechea 5½, Sarr 7 (63 Holding 6½) | | Sporting | 2 | 22 Mitoma, 90+1 José Marsà | | Half-time: | 1-1 | | Referee: | Onufer 7½ | | Attendance: | 44,522 | | Possession: | 53%-47% | | Total shots: | 17-11 | | MoM: | Geny Catamo | | TV: | highlights |
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| | (4-3-3): Rui Silva 7, Geny Catamo 7½, José Marsà 6½, Daniel Bragança 6 (90+2 Balogh 6), Tomás Araújo 6½, Coates 7, Rafa 6½, Mitoma 7, Beto 7, Anderson Talisca 7, Toni 6 | | VfB Stuttgart | 1 | 5 Ito |
| | (4-3-3): Flekken 7½, Maffeo 7, Ito 6½, Karazor 6½, Kempf 6½, Ullrich 6½, Endo 7, Führich 6½, Perea 6½, Mangala 7, Zuber 6 | | Torino | 1 | 45 Mikel Merino | | Half-time: | 1-0 | | Referee: | Pyanikh 8 | | Attendance: | 60,882 | | Possession: | 64%-36% | | Total shots: | 23-8 | | MoM: | Mikel Merino |
| | 34 Eze, 88 Cambiaso | | (4-3-3): Nübel 7½, Gatti 6½, Cambiaso 6½, Rabiot 8, Zabarnyi 7, Vivian 6½, Greenwood 7, Eze 7½, Mikel Merino 8, Jones 7½, Schade 6½ | | Tottenham Hotspur | 0 |
| | 79 Golovin | | (4-3-3): Forster 7, Pedro Porro 7, Colwill 6½, Lo Celso 6½, Mandi 6½, Coady 6, Tolisso 6, Golovin 6, Sargent 6½, Harit 6½, Harrison 6 | | Round 4 | | B.Mönchengladbach | 2 | 53 Ndoye, 69 Raúl | | Half-time: | 0-2 | | Referee: | Hansson 6 | | Attendance: | 44,710 | | Possession: | 45%-55% | | Total shots: | 15-11 | | MoM: | Friedl |
| | 3 Savona | | (4-3-3): Zetterer 6, Scally 7, Martha 6, Koné 7, Itakura 6½, Savona 5½, Hofmann 7, Ndoye 7½, Raúl 6½, Eggestein 7, Abde 6½ | | Napoli | 2 | 4p Fekir, 34 Fekir |
| | (4-3-3): Pau López 6½, Zanoli 7, Friedl 7½, Oriol Romeu 6 (81 Verdi 6), Llorente 7, Maksimovic 6, Gonçalo Guedes 7½, Politano 7 (70 Sensi 6½), Fekir 7, Zerbin 5½, Retegui 6½ | | Dundee United | 2 | 28 Sarr, 73 Dodô | | Half-time: | 1-1 | | Referee: | Pereira 7½ | | Attendance: | 44,186 | | Possession: | 53%-47% | | Total shots: | 18-8 | | MoM: | Dodô |
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| | (4-3-3): Barkas 6, Dodô 8, Mykolenko 6½, Baumgartner 7, Uduokhai 7½, Davis 6½, McCausland 6½, Adeyemi 7½, Alario 7½, Barrenechea 6½, Sarr 7 | | RB Leipzig | 2 | 20 Murphy, 78 Sørloth |
| | (4-3-3): Blaswich 6½, O'Brien 6½, Ritchie 6½, Haidara 7, Adarabioyo 6½, Ampadu 5½, Murphy 6½ (73 Matriciani 6), Willock 5½, Sørloth 6½, Schlager 6, Nketiah 6 | | FC Porto | 1 | 79 Pepê | | Half-time: | 0-1 | | Referee: | Colic 6½ | | Attendance: | 35,520 | | Possession: | 50%-50% | | Total shots: | 8-15 | | MoM: | Sanusi |
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| | (4-3-3): Remiro 6½, Manafá 7, Sanusi 8, Stephen Eustáquio 6½, Danilo 6½, Otávio 6, Nanu 6½, Pepê 7½, Willian 6½, Uribe 6½, Galeno 6½ | | Atalanta | 2 | 29 Bellanova, 65 Bensebaini |
| | (4-3-3): Scuffet 7, Bellanova 6½, Bensebaini 7½, De Roon 7½, Martínez Quarta 6½, Carboni 7, Evjen 6½, Minamino 7, Piccoli 7 (51 Frattesi 6½), Szymanski 6½, Tiago Tomás 6½ | | Fiorentina | 2 | 6 Rots, 44 Nzola | | Half-time: | 2-0 | | Referee: | López Nieto 7 | | Attendance: | 47,154 | | Possession: | 51%-49% | | Total shots: | 16-14 | | MoM: | Mandragora | | TV: | live |
| | 27 Solanke | | (4-3-3): Skorupski 7½, Kayode 7, Theate 6½, Mandragora 7½, Ranieri 6½, Okoli 7, Pierozzi 7, Rots 6½, Solanke 6, Svanberg 7½, Nzola 6 | | Chelsea | 0 |
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| | (4-3-3): Meslier 7, Chalobah 6½, Junior Firpo 6½, William Carvalho 6 (62 Gil 6½), Humphreys 6, Ricardo Esgaio 6, Horta 7, João Pedro 6, Jiménez 7, Weghorst 5½, Pléa 6½ (52 James 6½) | | Manchester City | 1 | 32p Sterling | | Half-time: | 1-0 | | Referee: | Gumienny 6 | | Attendance: | 43,718 | | Possession: | 49%-51% | | Total shots: | 13-14 | | MoM: | Kolasinac |
| | 24 Scarlett | | (4-3-3): Schmeichel 7, Wan-Bissaka 7½, João Cancelo 6½, Longstaff 7, Orban 7, Maguire 7, Mount 6½ (75 Bennacer 6½), Mané 7, Sterling 6, Smith Rowe 6½, Scarlett 6½ | | Sassuolo | 1 | 83 Pedersen |
| | (4-3-3): De Gea 7, Pedersen 7, Kolasinac 8, Bajrami 7½, Rrahmani 7, Viti 6, Boloca 6½, Samu Castillejo 6½ (78 Toljan 6), Dovbyk 7, Lopez 6½, Raspadori 6 | | Sevilla | 2 | 11 Álex Moreno, 90+1 Fran García | | Half-time: | 1-1 | | Referee: | Pontikis 6 | | Attendance: | 44,959 | | Possession: | 52%-48% | | Total shots: | 13-14 | | MoM: | Geny Catamo |
| | 3 Álex Sola, 19 El Haddadi | | (4-3-3): Dmitrovic 5½, Álex Sola 6 (68 Gnagnon 7½), Fran García 7½, Jota 7, Gudelj 7, Sergio Ramos 5½, Álex Pozo 7½, Álex Moreno 6½, En-Nesyri 7, Fernando 5½, El Haddadi 5½ | | Sporting | 3 | 28 Tomás Araújo, 68p Beto, 78og Gudelj |
| | (4-3-3): Rui Silva 6, Geny Catamo 7½, José Marsà 7, Daniel Bragança 7 (77 Balogh 6), Tomás Araújo 7, Coates 6½, Rafa 7, Mitoma 6½, Beto 7, Anderson Talisca 6½, Toni 7 | | Spartak | 2 | 32 Nico, 40 Embolo | | Half-time: | 2-0 | | Referee: | Hauge 6½ | | Attendance: | 42,630 | | Possession: | 39%-61% | | Total shots: | 11-12 | | MoM: | McKennie |
| | 89 Manu Sánchez | | (4-3-3): Aréola 7½, Reynolds 7, Manu Sánchez 6, Pasalic 7½, Bednarek 6, Bailly 6½, Moses 6, Haraldsson 6½, Embolo 6½, Nico 6½, Lee 6½ | | Aston Villa | 0 |
| | 69 João Félix | | (4-3-3): Pope 7, McKennie 8, Viña 7½, Højbjerg 7½, Mings 7, Keane 6, Kjær 6½, João Félix 7, Abraham 7½, Ramsey 7½, Kolo-Muani 7 | | Tottenham Hotspur | 0 |
| | Half-time: | 0-0 | | Referee: | Racalbuto 5½ | | Attendance: | 36,233 | | Possession: | 39%-61% | | Total shots: | 5-12 | | MoM: | Golovin |
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| | (4-3-3): Forster 6½, Pedro Porro 7 (72 Bowden 7½), Colwill 6½, Lo Celso 6½, Mandi 6, Coady 6, Tolisso 6½, Golovin 8, Sargent 6½, Harit 7, Harrison 6 | | Arsenal | 0 |
| | 61 De Winter | | (4-3-3): Turner 8, Williams 7, Marcos Alonso 8, Mkhitaryan 8, Pablo 7, De Winter 6½, Fábio Vieira 7½, Grealish 7½, Mayoral 6½, Xhaka 6½, Balogun 6 | | Valencia | 1 | 53 Kondogbia | | Half-time: | 0-1 | | Referee: | Rodomonti 7½ | | Attendance: | 45,303 | | Possession: | 51%-49% | | Total shots: | 10-12 | | MoM: | Samuel Lino |
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| | (4-3-3): Soria 7, Foulquier 6½ (46 Thierry Correia 7½), Samuel Lino 8½, Parejo 7½, Gabriel Paulista 6½, Diakhaby 6, Marvin 6½, Hélder Costa 6½, Rubén Sobrino 7, Kondogbia 7½, Rodrigo 6 | | Lille | 2 | 8 Bamba, 89 Bayo | | 37 André, 90+4 Bamba | | (4-3-3): Chevalier 6, Weah 7½, Reinildo 8, Gomes 6½, Tiago Djaló 6½, Gudmundsson 6, Zhegrova 6½, Bamba 7, Bayo 6, André 6½, Kamano 6½ | | Villarreal | 1 | 35 Jackson | | Half-time: | 1-1 | | Referee: | Ziober 7½ | | Attendance: | 22,866 | | Possession: | 55%-45% | | Total shots: | 12-11 | | MoM: | Lenglet |
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| | (4-3-3): Jörgensen 6½, Traoré 7, Moreno 7, Manu Morlanes 7½, Lenglet 8, Eder Militão 6½ (51 Danjuma 6½), Daramy 6½, Yéremy Pino 7½, Jackson 7, Joan Jordán 7½, Azmoun 7 | | FC Twente | 1 | 15og Daramy |
| | (4-3-3): Drommel 6½, Meunier 6½, Blind 6, Berghuis 6, Van Hecke 7, St Juste 6½, Stengs 7, Lokonga 6½, Wilson 7, Bruns 6½, George 6 |
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