| Round 3 | | AEK | 2 | 42 Drogba, 83 Drogba | | Half-time: | 1-0 | | Referee: | Bazzoli 7 | | Attendance: | 52,300 | | Possession: | 45%-55% | | Total shots: | 16-18 | | MoM: | Dunne | | TV: | highlights |
| | 67 Di Natale, 76 Gekas | | (4-3-3): Doni 6½, Ujfalusi 6½, Bridge 7, Diarra 6 (63 Lakis 6), Albiol 7½, Alexopoulos 6, Wright-Phillips 7½, López 5½, Drogba 7, Gekas 6, Di Natale 6 | | Manchester City | 1 | 89 Joaquín |
| | (4-4-2): Van Der Sar 6, Ayala 7, De Cler 6½, Juanito 6½, Makélélé 6, Dunne 8½, Joaquín 6½, Rosický 6½, Crespo 7½, Crouch 8, Plasil 6½ | | Deportivo | 1 | 37 Pander | | Half-time: | 1-0 | | Referee: | Strugeon 7 | | Attendance: | 34,429 | | Possession: | 53%-47% | | Total shots: | 15-6 | | MoM: | Sergio |
|
| | (4-3-3): Munúa 7, Krøldrup 6½ (70 Taborda 7), Pander 6½, Sergio 8, Jorge Andrade 7½, Konchesky 6½, Gallardo 6½, Munitis 7, Xisco 6½, Montella 6½, Jô 6½ | | Aston Villa | 1 | 85 Smith | | 2 Smith, 8 Hughes, 15 Richardson, 30 Ballack, 32 McFadden, 90 Ridgewell | | (4-3-3): Howard 7, Hughes 6½, Lescott 7½, Diarra 6 (76 Makoun 7), Ridgewell 6½, Samuel 7, Pennant 6½ (50 Dagoberto 7), Richardson 7, Smith 7, Ballack 6½, McFadden 6 | | Espanyol | 5 | 19 Tamudo, 45+1 Morales, 47p Tamudo, 72 Tamudo, 85 David García | | Half-time: | 2-1 | | Referee: | Pedro Proença 5½ | | Attendance: | 53,754 | | Possession: | 50%-50% | | Total shots: | 19-14 | | MoM: | Diarra |
|
| | (4-3-3): Kameni 7½, Ilsinho 6½, David García 6½, Diarra 8, Fukal 7, Castro 7, Juanfran 7½, Morales 6½, Tamudo 6½, De La Peña 5½, Luis García 6 | | Independiente | 1 | 26 Cardozo |
| | (4-3-3): Víctor Valdés 7½, Rodríguez 7, José Enrique 7½, Carlos Martins 7, Paletta 7, Abraham 6½, Ramón 5½, Cardozo 6½, Sanogo 7, Culio 7, Carlos Alberto 6 | | Hamburger SV | 2 | 68 Yakubu, 88 Jansen | | Half-time: | 0-0 | | Referee: | Pairetto 7½ | | Attendance: | 52,108 | | Possession: | 57%-43% | | Total shots: | 23-4 | | MoM: | Jentzsch | | TV: | live |
| | 9 Kahlenberg | | (4-3-3): Jentzsch 7½, Reveillère 7, Jansen 7, Beckham 7½, Nelsen 6½, Boulahrouz 7, Farfán 7, Trochowski 7½, Yakubu 7, Kahlenberg 6½, Voronin 6 | | Roma | 0 |
|
| | (4-3-3): Pelizzoli 7½, Panucci 6½, Tonetto 6½, Afellay 7, Bovo 7, Felipe 6½, Sidwell 7, Mauri 7, Lucarelli 6½, Hysén 5½, Ezquerro 6½ (56 Musampa 5½) | | Middlesbrough | 4 | 6 Downing, 14 Downing, 76 Viduka, 78og Görlitz | | Half-time: | 2-0 | | Referee: | Ruggiero 7½ | | Attendance: | 31,587 | | Possession: | 49%-51% | | Total shots: | 19-9 | | MoM: | Corona |
|
| | (4-3-3): Schwarzer 7, Parnaby 6½, Taylor 6½, Boateng 7½, Wheater 7, Miyamoto 7, Cattermole 5 (60 Davies 8), Downing 7, Viduka 7, Doriva 6½, Rivaldo 6½ | | Bayern München | 0 |
|
| | (4-3-3): Corona 8, Salihamidzic 7, Yepes 7, Ottl 6½, Demichelis 7½, Görlitz 6, Karimi 7, Zé Roberto 6, Santa Cruz 7½, Guerrero 6, Makaay 6 | | Paris SG | 1 | 52 Didot | | Half-time: | 0-1 | | Referee: | Stafoggia 6 | | Attendance: | 48,230 | | Possession: | 51%-49% | | Total shots: | 17-14 | | MoM: | Matuzalém |
|
| | (4-3-3): Létizi 7, Mendy 7, Distin 8, Luccin 7½, Ismaël 6½, Armand 6½, Didot 6½ (64 Bamogo 6), Meghni 6½, Luyindula 7½, Dia 6½, Frau 7½ | | Shakhtar | 1 | 28 Tymoschuk |
| | (4-3-3): Lastùvka 6½, Stoican 6½, Schulz 7½, Matuzalém 8, Chyhrynskyi 7, Rat 6½, Krasic 7, Tymoschuk 6½ (53 Caffa 7), Byelik 7, Duljaj 7, Marica 6½ | | Spartak | 0 |
| | Half-time: | 0-1 | | Referee: | Pellegrino 6 | | Attendance: | 46,322 | | Possession: | 46%-54% | | Total shots: | 5-18 | | MoM: | Dessena |
|
| | (4-3-3): Adler 6½, Shishkin 7, D'Alessandro 6, Diego 7½, Vidic 8, Evseev 6, Kuijt 7, Bilyaletdinov 6½, Sahar 6, Titov 6½, Pavlenko 5½ | | Feyenoord | 1 | 25 Buckley |
| | (4-3-3): Mondragón 7, Greene 7½, Ergün 6½ (55 Ricken 7½), Dessena 8½, Luizão 7½, Tomas 6½, Vincken 6, Buckley 7, Amoah 6½, Van Der Gun 7, Kalou 6 | | Valencia | 2 | 18 Menez, 80 Schaars | | Half-time: | 1-0 | | Referee: | Quartuccio 6½ | | Attendance: | 54,304 | | Possession: | 43%-57% | | Total shots: | 9-6 | | MoM: | Mathijsen |
|
| | (4-4-2): Viera 7, Curro Torres 6½, Fábio Aurélio 7½, Mathijsen 8½, Hofland 6½, Rothen 6½, Regueiro 6, Daniel Carvalho 6½, Menez 7½, Rufete 7, Schaars 7 | | Fiorentina | 1 | 63 Donadel |
| | (4-3-3): Lobont 7½, Rodríguez 6½ (81 Brivio 6), Kirilov 7½, Zanetti 7, Dainelli 7½, Di Loreto 6, Godeas 6½, Van Der Meyde 7½, Mista 7, Donadel 7, Cacau 6½ | | Round 4 | | Aston Villa | 0 |
| | Half-time: | 0-0 | | Referee: | Racalbuto 5½ | | Attendance: | 42,413 | | Possession: | 44%-56% | | Total shots: | 8-14 | | MoM: | Beckham | | TV: | highlights |
| | 27 Richardson, 34 Diarra, 36 Pennant, 44 Bouma | | (4-3-3): Howard 7, Hughes 7½, Lescott 7, Mascherano 7½, Bouma 6, Ridgewell 6, Pennant 6, Richardson 6½, Smith 6½, Diarra 7, Dagoberto 6 | | Hamburger SV | 1 | 51 Trochowski |
| | (4-3-3): Jentzsch 6½, Reveillère 6½, Jansen 7½, Beckham 7½, Nelsen 6, Boulahrouz 7, Farfán 7, Trochowski 7, Yakubu 7, Kahlenberg 6½, Voronin 5½ | | Bayern München | 1 | 69 Santa Cruz | | Half-time: | 0-0 | | Referee: | Rodomonti 6½ | | Attendance: | 39,487 | | Possession: | 55%-45% | | Total shots: | 12-14 | | MoM: | Zé Roberto |
|
| | (4-3-3): Corona 7½, Salihamidzic 6½, Yepes 6, Ottl 7, Demichelis 7, Görlitz 7, Karimi 7, Zé Roberto 7½, Santa Cruz 7, Guerrero 6, Makaay 5½ | | Paris SG | 0 |
| | 34 Didot, 49 Didot | | (4-3-3): Létizi 6½, Mendy 6½, Distin 7, Luccin 7, Ismaël 6½, Armand 6½ (82 Berson 6), Didot 6½, Meghni 7, Luyindula 7, Dia 6½, Frau 5½ | | Benfica | 2 | 19 Smolarek, 67 Karagounis | | Half-time: | 1-1 | | Referee: | Rosica 7 | | Attendance: | 49,704 | | Possession: | 56%-44% | | Total shots: | 14-9 | | MoM: | Addo | | TV: | highlights |
| | 35 Mantorras, 49 Smolarek, 69 Culina | | (4-3-3): Quim 6, Ben Haim 6 (50 Addo 8½), Léo 7, Karagounis 7½, André Bahia 7½, Nielsen 7, Geovanni 6½, Beasley 7, Smolarek 7½, Culina 6, Mantorras 6½ | | Espanyol | 2 | 37p Tamudo, 87 Tamudo |
| | (4-3-3): Kameni 6, Ilsinho 7, David García 8, Diarra 6, Fukal 6½, Castro 7, Juanfran 6½, Morales 6½, Tamudo 6½, De La Peña 6, Luis García 6 | | Fiorentina | 1 | 64 Dainelli | | Half-time: | 0-0 | | Referee: | Benkö 6½ | | Attendance: | 40,058 | | Possession: | 44%-56% | | Total shots: | 4-14 | | MoM: | Sergio |
|
| | (4-3-3): Calero 6½, Di Loreto 7, Kirilov 8, Zanetti 6½, Rodríguez 7½, Dainelli 6½, Godeas 6½, Van Der Meyde 6½, Mista 6½, Donadel 6½, Cacau 6 | | Deportivo | 1 | 47 Xisco |
| | (4-3-3): Munúa 7, Krøldrup 6, Pander 7½, Sergio 8, Jorge Andrade 7½, Konchesky 7, Gallardo 7, Munitis 7½, Xisco 7, Montella 6, Jô 6 | | Independiente | 1 | 41 Sanogo | | Half-time: | 1-1 | | Referee: | Blareau 6 | | Attendance: | 45,085 | | Possession: | 54%-46% | | Total shots: | 17-11 | | MoM: | José Enrique |
|
| | (4-3-3): Víctor Valdés 7, Rodríguez 6½, José Enrique 8, Carlos Martins 7½, Paletta 7½, Abraham 7, Ramón 6, Cardozo 7, Sanogo 7½, Culio 5½, Carlos Alberto 6½ | | Villarreal | 1 | 39 Santi |
| | (4-3-3): Timmer 6, Labaka 7, Arruabarrena 7, Mikel Alonso 7½, Arzo 6, Peña 6½, Font 6½, Santi 7, Delgado 6, Giménez 6, Forlán 6 | | Manchester City | 1 | 28 Plasil | | Half-time: | 1-0 | | Referee: | Sars 6½ | | Attendance: | 45,091 | | Possession: | 55%-45% | | Total shots: | 11-12 | | MoM: | De Cler |
| | 21 Makélélé, 72 Crespo | | (4-4-2): Van Der Sar 7½, Ayala 7½, De Cler 8, Juanito 7, Makélélé 7 (74 Rozehnal 7½), Dunne 6½ (66 Melli 7½), Joaquín 7, Rosický 7, Crespo 6, Crouch 6, Plasil 7 | | Real Betis | 0 |
|
| | (4-3-3): Armando 7, Chica 7, Marc Torrejón 7, Petit 7½, Alex 6½, Jarque 6½, Raúl García 6½, Elano 6, Carew 6, Yeste 6½ (54 Del Horno 6), Rosina 5½ | | Newcastle United | 2 | 30 Emre, 85p Mido | | Half-time: | 1-1 | | Referee: | Veiga Trigo 6 | | Attendance: | 49,167 | | Possession: | 53%-47% | | Total shots: | 9-9 | | MoM: | Hübschman |
| | 55 Boa Morte | | (4-3-3): Cerný 6, Stalteri 7, Nyatanga 7, Bowyer 7, Hübschman 7½, Davies 6 (85 Pattison 6), Dyer 7, Emre 6½, Mido 7, Luque 5½, Boa Morte 7 | | Valencia | 1 | 31 Regueiro |
| | (4-4-2): Viera 6½, Curro Torres 6½, Fábio Aurélio 7, Mathijsen 7, Hofland 7, Rothen 7, Regueiro 6½, Daniel Carvalho 7, Menez 6½, Rufete 7, Schaars 5½ | | PSV | 2 | 62p Koller, 67 Motta | | Half-time: | 0-2 | | Referee: | Meese 7 | | Attendance: | 35,248 | | Possession: | 55%-45% | | Total shots: | 21-12 | | MoM: | Aissati |
| | 39 Ball | | (4-3-3): Loncaric 6, Nélson 7, Dedé 7½, Albelda 6 (68 Aissati 8), Ooijer 7½, Ânderson 7½, González 7, Ball 7, Koller 7½, Motta 6½, Ewerthon 6 | | Middlesbrough | 2 | 5 Viduka, 8og Nélson |
| | (4-3-3): Schwarzer 6½, Parnaby 6½ (79 Hasselbaink 6½), Taylor 7, Boateng 6½, Wheater 7, Miyamoto 6, Cattermole 6, Downing 6½, Viduka 6½, Rochemback 5½, Rivaldo 6½ | | Roma | 2 | 21 Felipe, 23 Afellay | | Half-time: | 2-0 | | Referee: | Piraux 6½ | | Attendance: | 41,078 | | Possession: | 57%-43% | | Total shots: | 19-16 | | MoM: | Dabo |
|
| | (4-3-3): Pelizzoli 8, Panucci 7, Tonetto 8, Dabo 8, Bovo 7½, Felipe 6½, Sidwell 6½, Afellay 7½, Lucarelli 7, Mauri 7, Ezquerro 6½ | | Spartak | 0 |
|
| | (4-3-3): Adler 7, Shishkin 6½, Evseev 6, Diego 7, Vidic 7½, Hines 6, Kuijt 6, D'Alessandro 6½, Sahar 7 (61 Pavlenko 6), Titov 6½, Bilyaletdinov 5½ | | Shakhtar | 1 | 66 Byelik | | Half-time: | 0-1 | | Referee: | Sandra 6 | | Attendance: | 40,451 | | Possession: | 52%-48% | | Total shots: | 12-9 | | MoM: | Bedoya |
|
| | (4-3-3): Lastùvka 7, Stoican 6, Schulz 7, Matuzalém 7½, Chyhrynskyi 7, Rat 6½, Krasic 7½, Tymoschuk 6½ (66 Caffa 7), Byelik 7, Duljaj 7, Marica 6½ | | Udinese | 1 | 42 Sala |
| | (4-3-3): Ivankov 7, Sagnol 6, Bedoya 8, O'Shea 7½, Sala 7½, Cantaluppi 6½, Zenoni 6, Djordjevic 7, Bonazzoli 6½, Pedretti 6½, Ronaldo 6 |
|
