| Round 3 | | Anderlecht | 1 | 72 Cocu | |
| | (4-3-3): Friedel 6, Cicinho 8, Goor 8, Cambiasso 7½, Hyypiä 8½, Coloccini 6½, Wilhelmsson 7½, Cocu 6½, Caicedo 7½, Zikos 7½, Tomasson 6½ | | Birmingham City | 2 | 13 Heskey, 17 Heskey | | 10 Painter, 64 Latka, 71 Butt | | (4-3-3): Taylor 7, Finnan 7, Arca 7½, Tainio 8, Latka 6½, Painter 6½, Johnson 7, Gray 6½, Shatskikh 5½, Butt 5½, Heskey 6½ | | Auxerre | 1 | 23 Muratori | | Half-time: | 1-1 | | Referee: | Bogdanov 5½ | | Attendance: | 21,848 | | Possession: | 47%-53% | | Total shots: | 13-10 | | MoM: | Ahumada |
| | 37 Gourcuff, 44 Gomis | | (4-3-3): Mandanda 7, Sagna 6½, Muratori 7, Flamini 7½, Delpierre 6½, Planus 6, Bellion 6½, Gourcuff 7, Gomis 6½, Cheyrou 6½ (83 Zubar 6), Gouffran 6 | | River Plate | 1 | 19 Pandiani |
| | (4-3-3): Carrizo 7, Ferrari 7, Mareque 6 (78 Ahumada 8), Montenegro 6 (72 Luciano Henrique 7), Caceres 6½, Talamonti 6, Patiño 6, Ivanschitz 7, Pandiani 7, Zapata 6, Farías 5½ | | Boca Juniors | 1 | 87 Palermo | | Half-time: | 0-0 | | Referee: | Christensen 6½ | | Attendance: | 40,319 | | Possession: | 44%-56% | | Total shots: | 12-16 | | MoM: | Volkan | | TV: | highlights |
| | 6 Guarín, 44 Morel Rodríguez, 46 Palermo | | (4-3-3): Sánchez 7, Ibarra 6½, Morel Rodríguez 6, Juande 7, Olarra 7, Díaz 6½, Guarín 6, João Coimbra 5½, Sergio García 6½, Palermo 5½, Buonanotte 7 | | Besiktas | 0 |
| | 77 Ibrahim | | (4-3-3): Volkan 8, Turaci 7, Mehmet Seyfettin 6½, Tümer 7, Madlung 7½, Ibrahim 6½, Okan 8, Ibrahim 6½, Serkan 7, Gökhan 6½, Verpakovskis 7 | | Borussia Dortmund | 2 | 76 Mutu, 84 Gilardino | | Half-time: | 0-0 | | Referee: | Nielsen 6½ | | Attendance: | 57,601 | | Possession: | 51%-49% | | Total shots: | 14-7 | | MoM: | Seedorf |
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| | (4-4-2): Carson 6, Zanetti 6 (76 Richards 7½), Kompany 7½, Xavi 7½, Ricardo Carvalho 6½, Touré 6, Hamit 6½, Seedorf 8, Gilardino 7½, Totti 7, Mutu 7 | | FK Austria | 1 | 63 Papac |
| | (1-3-3-3): Caranta 7, Schiemer 7, Dheedene 6, Blanchard 7½, Papac 7 (85 Janocko 6), Tokic 6, Sionko 7½, Vachousek 7, Linz 7, Kiesenebner 6, Lasnik 5½ | | Celta Vigo | 3 | 10 Tacchinardi, 15 Tacchinardi, 57 Tacchinardi | | Half-time: | 2-0 | | Referee: | Leduc 6 | | Attendance: | 31,676 | | Possession: | 57%-43% | | Total shots: | 14-15 | | MoM: | Edmílson | | TV: | live |
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| | (4-3-3): Pinto 7½, Ángel 7, Raúl Bravo 6, Edmílson 8, Jaliens 5½ (49 José Castro 6½), Sergio 6½, Park 7, Pires 6½, Fernando Baiano 7½, Tacchinardi 6½, Javi Guerrero 7 | | Sevilla | 0 |
| | 17 Kepa | | (4-3-3): Riesgo 7, Javi Navarro 7½, González 6, Renato 5½, Aitor Ocio 7, Prieto 6, Arteta 6½, Diego Capel 6½, Kepa 6½, Martí 7, Asamoah 7 | | FC Porto | 3 | 32 Németh, 43p Koné, 49 Koné | | Half-time: | 2-2 | | Referee: | Pauchard 5½ | | Attendance: | 40,626 | | Possession: | 49%-51% | | Total shots: | 9-13 | | MoM: | Koné | | TV: | highlights |
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| | (4-3-3): Paulo Ribeiro 6½, Fernandinho 7, Seric 7, Raul Meireles 8, Pedro Emanuel 7, Kenneth 5½, Liverani 7½, César Peixoto 5½ (64 Ivanildo 6), Koné 8, Schneider 6, Németh 6 | | São Paulo | 2 | 18og Seric, 25 Denílson | | 65 Josué | | (4-3-3): Bosco 6, Radamés 6½, Edcarlos 7, Josué 7½, Quiroga 6, André Dias 5½, Leandro 7, Richarlyson 7, Lenílson 6½, Denílson 6½, Rodrigo Fabri 7½ | | Palermo | 2 | 30 Mutarelli, 80 Mutarelli | | Half-time: | 1-0 | | Referee: | Ramos 7½ | | Attendance: | 37,867 | | Possession: | 51%-49% | | Total shots: | 12-8 | | MoM: | Barone |
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| | (4-3-3): Andújar 6, Zenoni 6 (77 Cuevas 6), Biava 6½, Barone 8, Ferrari 7, Capelli 7, Santana 7½, Mutarelli 6½, Filippini 5½, Tavano 6½, Semioli 7 | | Marseille | 2 | 84 Diané, 88 Niang | | 38 Kehl, 53 Civelli, 87 Ba | | (4-3-3): James 6½, Gabri 7½, Van Bronckhorst 7, Ba 6½, Méité 6½, Civelli 6½, Pagis 6, Kehl 7, Diané 7, Begeorgi 6, Niang 7 | | SV Werder Bremen | 2 | 42 Khizanishvili, 85 Menseguez | | Half-time: | 1-1 | | Referee: | Dardenne 6½ | | Attendance: | 42,362 | | Possession: | 42%-58% | | Total shots: | 12-14 | | MoM: | Van Damme |
| | 23 Andreasen, 37 Mudingayi, 81 Valdez | | (4-3-3): Wiese 6½, Khizanishvili 6½, Van Damme 7½, Fahrenhorst 6 (57 Väyrynen 7½), Baumann 6½, Andreasen 5½, Mudingayi 7, Jensen 7 (70 Atouba 6½), Menseguez 6½, Savage 6½, Valdez 7 | | Rosenborg | 1 | 15 Skjelbred | | 57 Johnsen | | (4-3-3): Johnsen 6½, Kvarme 7, Stensaas 6, Skjelbred 6, Riseth 6, Braaten 6, Strand 7½, Dorsin 6, Helstad 7 (78 Essediri 6), Johnsen 6, Iversen 6 | | West Ham United | 0 |
| | Half-time: | 0-1 | | Referee: | Bennett 7 | | Attendance: | 38,854 | | Possession: | 43%-57% | | Total shots: | 2-21 | | MoM: | Yobo |
| | 1 Belaid | | (4-3-3): Blazek 6½, Chimbonda 7½, Capdevila 7, Belaid 6½, Lopo 6, Ferdinand 6½, Zabaleta 7, Etherington 7, Dixon 6, Robail 5½, Lita 6½ | | Blackburn Rovers | 2 | 24 Davies, 49 Anichebe |
| | (4-3-3): Jääskeläinen 6½, Yobo 8, Baines 6½ (72 Tugay 8), Cahill 8, Garay 7½, Todd 6½, Frings 7, Davies 7½, Anichebe 7, Fábio Simplício 7, McCarthy 6 | | Round 4 | | Athletic Bilbao | 1 | 72 Amorebieta | | Half-time: | 0-1 | | Referee: | Durkin 6½ | | Attendance: | 39,829 | | Possession: | 53%-47% | | Total shots: | 15-9 | | MoM: | Rivera |
| | 4 Dañobeitia, 7 Recoba | | (4-3-3): Aranzubía 6, Lacruz 7½, Amorebieta 8, Rivera 8½, Cuéllar 7½, Prieto 6½, Etxeberria 8, Dañobeitia 6½, Llorente 7½, Orbáiz 6½, Recoba 6½ | | FC Twente | 1 | 37 Engelaar | | 38 N'Kufo, 54 Heubach, 79 Wilkshire | | (4-3-3): Paauwe 6½, Wilkshire 6½, Heubach 7, Brama 6½, Berezutsky 6½ (73 Touma 6), Braafheid 7, El Ahmadi 6½, Engelaar 6½, Koevermans 7, N'Kufo 5½, Elia 5½ | | Birmingham City | 1 | 31 Shatskikh | | Half-time: | 1-1 | | Referee: | Elleray 6 | | Attendance: | 29,905 | | Possession: | 44%-56% | | Total shots: | 8-11 | | MoM: | Park |
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| | (4-3-3): Taylor 6½, Finnan 7½, Arca 7, Tainio 6½, Latka 6½, Painter 6½, Johnson 6½, Gray 6, Shatskikh 7, Butt 6½ (83 Clemence 6), Heskey 7½ | | Celta Vigo | 2 | 16 Pires, 82 Fernando Baiano |
| | (4-3-3): Pinto 5½, Ángel 6½ (70 José Castro 6), Raúl Bravo 7, Edmílson 7½, Jaliens 7, Sergio 6, Park 8, Pires 6½, Fernando Baiano 7½, Tacchinardi 6½, Javi Guerrero 6½ | | Blackburn Rovers | 1 | 17 Davies | | Half-time: | 1-0 | | Referee: | Gallagher 5½ | | Attendance: | 31,342 | | Possession: | 42%-58% | | Total shots: | 15-12 | | MoM: | Flamini |
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| | (4-3-3): Jääskeläinen 7, Yobo 7, Baines 7, Cahill 7, Garay 5½, Todd 6, Frings 7, Davies 7, Anichebe 6½, Fábio Simplício 6, McCarthy 6½ | | Auxerre | 1 | 61 Gourcuff |
| | (4-3-3): Mandanda 6½, Sagna 7½, Muratori 5½, Flamini 7½, Delpierre 7½, Planus 5, Bellion 7, Gourcuff 6½, Gomis 7½, Cheyrou 6½ (83 Zubar 6), Gouffran 6 | | FK Austria | 0 |
| | Half-time: | 0-0 | | Referee: | Gergely 6 | | Attendance: | 11,773 | | Possession: | 49%-51% | | Total shots: | 16-11 | | MoM: | Morrone |
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| | (1-3-3-3): Caranta 6, Schiemer 6½, Dheedene 7, Blanchard 7, Papac 7 (52 Janocko 7), Tokic 7½, Sionko 7, Vachousek 7, Linz 7½, Kiesenebner 6½, Lasnik 5½ | | Parma | 2 | 51 Bresciano, 59 Paci |
| | (4-3-3): Bucci 6, Falcone 7, Castellini 7, Morrone 7½, Paci 7, Fernando Couto 6½, Parravicini 6, Bresciano 6½, Corradi 6½, Reginaldo 6½, Pisanu 6½ | | Rosenborg | 1 | 67 Helstad | | Half-time: | 0-0 | | Referee: | Reed 6½ | | Attendance: | 21,082 | | Possession: | 54%-46% | | Total shots: | 15-8 | | MoM: | Storflor |
| | 71 Tettey | | (4-3-3): Johnsen 7, Kvarme 7, Stensaas 7½, Skjelbred 6½ (60 Storflor 7½), Riseth 7½, Braaten 6½, Strand 7, Dorsin 7, Helstad 6½, Tettey 6, Iversen 6 | | Palermo | 1 | 60 Mutarelli |
| | (4-3-3): Andújar 6½, Zenoni 7, Biava 7½, Barone 7½, Ferrari 6½, Capelli 5½, Santana 7, Mutarelli 7, Slavkovski 5½, Di Michele 6, Semioli 6 | | Santos | 0 |
| | Half-time: | 0-1 | | Referee: | Bauer 7 | | Attendance: | 28,098 | | Possession: | 42%-58% | | Total shots: | 10-11 | | MoM: | Cambiasso |
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| | (4-3-3): Fábio Costa 6½, Kléber 7, Wendell 7, Pardo 7, Ânderson Polga 6½, Luíz Alberto 6½, Maldonado 6½, Pandev 6½, Ángel 6, Danilinho 5½, Amoroso 6 | | Anderlecht | 1 | 29 Cocu | | 5 Hyypiä | | (4-3-3): Friedel 6½, Cicinho 7, Goor 6½, Cambiasso 8, Coloccini 7½, Hyypiä 6½, Wilhelmsson 8, Cocu 7, Caicedo 6½, Zikos 7, Tomasson 5½ | | Sevilla | 2 | 59 Kepa, 79 Kepa | | Half-time: | 0-0 | | Referee: | Halsey 7 | | Attendance: | 44,269 | | Possession: | 47%-53% | | Total shots: | 14-16 | | MoM: | Riesgo |
| | 29 Renato, 45+2 Diego Capel | | (4-3-3): Riesgo 7½, Crespo 6½, Javi Navarro 6, Renato 7½, Aitor Ocio 6½, Prieto 6, Arteta 7½, Diego Capel 6½, Kepa 6½, Martí 6, Asamoah 6½ | | FC Porto | 0 |
| | 22 Schneider, 57 César Peixoto | | (4-3-3): Paulo Ribeiro 7, Fernandinho 7½, Seric 6, Raul Meireles 7, Pedro Emanuel 7, Kenneth 6½, Liverani 7, César Peixoto 6½, Koné 7, Schneider 7, Németh 6 | | São Paulo | 0 |
| | Half-time: | 0-3 | | Referee: | Campi 7 | | Attendance: | 39,390 | | Possession: | 52%-48% | | Total shots: | 8-13 | | MoM: | Richarlyson |
| | 45+1 Lenílson, 63 Richarlyson | | (4-3-3): Bosco 5½, Radamés 6½, Edcarlos 6, Josué 6, Quiroga 7, André Dias 6½, Leandro 7, Richarlyson 7½, Lenílson 6, Denílson 6½, Rodrigo Fabri 6½ | | SV Werder Bremen | 3 | 33 Baumann, 37 Menseguez, 42 Menseguez | | 16 Van Damme, 62 Mudingayi | | (4-3-3): Wiese 6, Khizanishvili 7, Van Damme 7, Fahrenhorst 7½, Baumann 6½ (59 Lamey 7½), Andreasen 7, Mudingayi 7, Jensen 6½, Menseguez 6, Savage 6½, Valdez 6 |
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