| Round 5 | | AEK | 2 | 32 Bridge, 51 Diarra | | Half-time: | 1-0 | | Referee: | Wieser 6 | | Attendance: | 49,396 | | Possession: | 46%-54% | | Total shots: | 8-9 | | MoM: | Bridge |
| | 34 Gekas, 61 López | | (4-3-3): Doni 7, Ujfalusi 7, Bridge 8, Diarra 6 (63 Lakis 7), Albiol 7, Alexopoulos 6½, Wright-Phillips 7½, López 6, Drogba 7, Gekas 6, Di Natale 6½ | | Independiente | 1 | 64 Rodríguez |
| | (4-3-3): Víctor Valdés 7, Rodríguez 8, José Enrique 7, Carlos Martins 7, Paletta 7, Abraham 6, Ramón 7, Cardozo 7½, Sanogo 7½, Culio 6, Carlos Alberto 6½ | | Deportivo | 1 | 7 Xisco | | Half-time: | 1-0 | | Referee: | Barry 7½ | | Attendance: | 34,450 | | Possession: | 51%-49% | | Total shots: | 19-7 | | MoM: | González |
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| | (4-3-3): Munúa 7, Krøldrup 7, Pander 7½, Valerón 7½, Jorge Andrade 7½, Konchesky 6½ (65 Montella 6½), Gallardo 7½, Munitis 6½, Xisco 7, Taborda 6, Jô 6½ | | PSV | 1 | 72 Koller |
| | (4-3-3): Loncaric 6, Nélson 6½, Dedé 7, Albelda 7, Ooijer 6½, Ânderson 6½, González 8, Ball 6½, Koller 7, Motta 6½, Ewerthon 5½ | | Espanyol | 4 | 2 De La Peña, 5 Juanfran, 27 Tamudo, 58 Castro | | Half-time: | 3-2 | | Referee: | Heilbron 6½ | | Attendance: | 54,808 | | Possession: | 55%-45% | | Total shots: | 16-10 | | MoM: | Juanfran | | TV: | highlights |
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| | (4-3-3): Kameni 7, Ilsinho 7, David García 7, Diarra 7½, Fukal 7, Castro 7½, Juanfran 8, Morales 7, Tamudo 7, De La Peña 7, Luis García 7 | | Shakhtar | 2 | 16 Byelik, 33 Byelik |
| | (4-3-3): Lastùvka 6½, Stoican 6½, Schulz 7, Matuzalém 6½, Chyhrynskyi 6½, Rat 6½, Krasic 6, Tymoschuk 6½, Byelik 7½, Duljaj 6½, Marica 6 | | Hamburger SV | 2 | 19 Trochowski, 62 Yakubu | | Half-time: | 1-0 | | Referee: | Willard 7½ | | Attendance: | 54,945 | | Possession: | 59%-41% | | Total shots: | 14-6 | | MoM: | Beckham | | TV: | live |
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| | (4-3-3): Jentzsch 7½, Reveillère 8, Jansen 7½, Beckham 8, Nelsen 7, Boulahrouz 8, Farfán 7½, Trochowski 6½, Yakubu 7½, Kahlenberg 6½, Voronin 6½ | | Feyenoord | 0 |
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| | (4-3-3): Mondragón 7½, Greene 6½, Ergün 7½, Dessena 6½, Luizão 6½, Tomas 7, Ricken 6½, Buckley 5½, Kalou 6½, Amoah 6½, Nihat 6 | | Middlesbrough | 1 | 3 Viduka | | Half-time: | 1-0 | | Referee: | Sedlacek 6½ | | Attendance: | 35,113 | | Possession: | 56%-44% | | Total shots: | 16-14 | | MoM: | De Cler |
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| | (4-3-3): Schwarzer 7, Parnaby 6½, Queudrue 7, Boateng 7½, Miyamoto 7, Wheater 6, Cattermole 7, Downing 7½, Viduka 7½, Doriva 6½, Rivaldo 6½ | | Manchester City | 0 |
| | 12 Rosický | | (4-4-2): Van Der Sar 7, Ayala 7, De Cler 8, Juanito 6½, Makélélé 7, Dunne 7, Joaquín 6½, Rosický 7 (61 Jørgensen 7), Crespo 5½, Crouch 5½, Plasil 6½ (51 Angulo 6) | | Paris SG | 2 | 5 Frau, 37 Jaurès | | Half-time: | 2-1 | | Referee: | Ancion 5 | | Attendance: | 48,250 | | Possession: | 51%-49% | | Total shots: | 8-6 | | MoM: | Luyindula | | TV: | highlights |
| | 84 Luyindula | | (4-3-3): Létizi 6½, Pichot 7, Armand 6½, Luccin 7, Distin 6, Ismaël 6, Frau 7, Jaurès 7½, Luyindula 7½, Berson 6, Bamogo 6 | | Aston Villa | 2 | 21og Luccin, 74 Ballack |
| | (4-3-3): Howard 6, Hughes 7, Bouma 7, Mascherano 6½, Lescott 7½, Ridgewell 6, McCann 7, Whittingham 6½, Figueroa 6, Ballack 6½, McFadden 6 | | Real Betis | 1 | 29 Elano | | Half-time: | 1-0 | | Referee: | Valdomiro 7 | | Attendance: | 41,835 | | Possession: | 49%-51% | | Total shots: | 7-15 | | MoM: | Afellay |
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| | (4-3-3): Doblas 6½, Chica 7, Marc Torrejón 6½ (65 Lafita 6), Petit 7½, Alex 7, Jarque 7, Raúl García 6½, Elano 7, Yeste 6½, Marcos 6½ (61 Pallardó 6), Rosina 5½ | | Roma | 1 | 88 Faye |
| | (4-3-3): Pelizzoli 7, Bovo 6, Tonetto 7, Afellay 7½, Felipe 6½ (46 Volpato 7), Motta 6½, Sidwell 7, Mauri 7, Lucarelli 7 (59 Faye 6½), Hysén 6½, Ezquerro 6 | | Spartak | 2 | 10 Bilyaletdinov, 34 Pavlenko | | Half-time: | 2-0 | | Referee: | Boggi 7 | | Attendance: | 40,991 | | Possession: | 35%-65% | | Total shots: | 13-19 | | MoM: | Dyer |
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| | (4-3-3): Adler 7½, Shishkin 7, D'Alessandro 6½, Diego 6½, Evseev 6½, Titov 6½, Kuijt 6½, Bilyaletdinov 7, Fred 6, Sahar 6, Pavlenko 5½ | | Newcastle United | 0 |
| | 33 Mido | | (4-3-3): Cerný 8, Stalteri 8, Nyatanga 8, Dyer 8½, Hübschman 7½, Davies 7½, Bowyer 7, Emre 8, Saha 8, Mido 6, Luque 6 | | Udinese | 3 | 18 Djordjevic, 45+1 Zenoni, 77 Bonazzoli | | Half-time: | 2-0 | | Referee: | Chihi 7 | | Attendance: | 41,784 | | Possession: | 42%-58% | | Total shots: | 10-15 | | MoM: | Bonazzoli |
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| | (4-3-3): Ivankov 7½, Sagnol 6½, Cantaluppi 7, O'Shea 7½, Sala 6½, Pedretti 6, Zenoni 7, Djordjevic 6½, Bonazzoli 8, Maresca 6, Ronaldo 6 | | Fiorentina | 0 |
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| | (4-3-3): Calero 7½, Di Loreto 7½, Kirilov 7, Zanetti 8, Rodríguez 7½, Dainelli 6, Godeas 6½, Van Der Meyde 6½, Mista 7½, Donadel 6½, Cacau 7 | | Valencia | 1 | 51 Menez | | Half-time: | 0-3 | | Referee: | Cinciripini 5½ | | Attendance: | 54,904 | | Possession: | 39%-61% | | Total shots: | 11-17 | | MoM: | Ben Haim | | TV: | highlights |
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| | (4-4-2): Viera 5, Curro Torres 7½, Fábio Aurélio 6½, Mathijsen 6½, Hofland 6½, Rothen 6½, Regueiro 6, Daniel Carvalho 6, Menez 7, Rufete 6, Schaars 7½ | | Benfica | 3 | 28 Léo, 33p Smolarek, 39p Smolarek | | 67 André Bahia | | (4-3-3): Quim 5½, Ben Haim 8, Léo 7, Karagounis 7, André Bahia 6½, Nielsen 7, Geovanni 7½, Beasley 7 (64 Nuno Assis 6½), Smolarek 6½, Culina 6½, Mantorras 6½ | | Villarreal | 1 | 12 Arruabarrena | | Half-time: | 1-0 | | Referee: | Collina 7 | | Attendance: | 22,928 | | Possession: | 57%-43% | | Total shots: | 14-13 | | MoM: | Arruabarrena |
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| | (4-3-3): Timmer 7½, Labaka 7, Arruabarrena 8½, Miguel 6½, Arzo 7, Peña 6½, Font 8, Santi 7½, Delgado 6½, Giménez 6, Forlán 7 | | Bayern München | 0 |
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| | (4-3-3): Corona 7½, Salihamidzic 6½, Yepes 6½, Karimi 7½, Demichelis 6½, Görlitz 6, Dos Santos 6, Zé Roberto 7½, Santa Cruz 6½, Guerrero 5½, Makaay 6 | | Round 4 | | Feyenoord | 0 |
| | Half-time: | 0-0 | | Referee: | Franceschini 7½ | | Attendance: | 50,100 | | Possession: | 55%-45% | | Total shots: | 17-13 | | MoM: | Ergün |
| | 29 Tomas | | (4-3-3): Mondragón 6½, Greene 6½, Ergün 8, Dessena 6½, Luizão 8, Tomas 6, Ricken 7, Buckley 7, Amoah 7, Kalou 6, Nihat 7 | | AEK | 1 | 47 Di Natale | | 78 Alexopoulos | | (4-3-3): Doni 8, Ujfalusi 6, Bridge 7, Diarra 6½ (63 Lakis 7), Albiol 7, Alexopoulos 6, Wright-Phillips 8, López 6, Drogba 7, Gekas 5½, Di Natale 6 |
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