| Round 5 | | Anderlecht | 2 | 49 Cocu, 77 Cicinho | | Half-time: | 0-1 | | Referee: | Fucci 6½ | | Attendance: | 27,886 | | Possession: | 50%-50% | | Total shots: | 19-7 | | MoM: | Cambiasso | | TV: | highlights |
| | 26 Tomasson | | (4-3-3): Friedel 6½, Cicinho 7, Goor 7½, Cambiasso 8, Coloccini 6½, Hyypiä 7, Wilhelmsson 7, Cocu 7½, Caicedo 6, Zikos 7, Tomasson 7½ | | Marseille | 1 | 22 Niang |
| | (4-3-3): James 7½, Gabri 7½, Van Bronckhorst 6½, Ba 6, Méité 6½, Civelli 6, Pagis 6½, Kehl 6½, Diané 7, Begeorgi 5½, Niang 6½ | | Auxerre | 2 | 15 Gomis, 61 Gomis | | Half-time: | 1-1 | | Referee: | Luci 7 | | Attendance: | 21,923 | | Possession: | 47%-53% | | Total shots: | 8-10 | | MoM: | Flamini |
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| | (4-3-3): Mandanda 6, Sagna 7, Muratori 6½, Flamini 8, Delpierre 7, Planus 6, Bellion 7, Gourcuff 6½, Gomis 7, Cheyrou 6 (61 Kaboul 6½), Gouffran 6½ | | Sevilla | 1 | 6 Diego Capel | | 50 Arteta, 78 Javi Navarro | | (4-3-3): Riesgo 7, Crespo 7, Javi Navarro 6½, Renato 7½, Aitor Ocio 6, Prieto 6, Arteta 7, Diego Capel 7, Kepa 7, Martí 6½, Asamoah 7½ | | Boca Juniors | 3 | 29 Sergio García, 52 Sergio García, 73p Sergio García | | Half-time: | 1-1 | | Referee: | Nicchi 6 | | Attendance: | 46,316 | | Possession: | 46%-54% | | Total shots: | 12-7 | | MoM: | Etxeberria |
| | 68 Díaz | | (4-3-3): Sánchez 6, Ibarra 7½, Morel Rodríguez 7, Juande 5½ (76 Obinna 6), Olarra 6½, Díaz 6½, Guarín 7½, João Coimbra 5½, Sergio García 7, Palermo 6½, Buonanotte 6½ | | Athletic Bilbao | 2 | 16p Llorente, 76 Llorente | | 4 Amorebieta, 37 Llorente, 38 Dañobeitia, 70 Cuéllar, 73 Rivera, 76 Orbáiz | | (4-3-3): Aranzubía 6½, Expósito 7, Amorebieta 6, Rivera 7, Cuéllar 7, Rivas 6, Etxeberria 8, Dañobeitia 5½, Llorente 7½, Orbáiz 6½, Recoba 7 | | Borussia Dortmund | 4 | 24 Seedorf, 37og Josué, 41 Gilardino, 90+1 Mutu | | Half-time: | 3-0 | | Referee: | Pairetto 6½ | | Attendance: | 57,609 | | Possession: | 47%-53% | | Total shots: | 13-6 | | MoM: | Bosco |
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| | (4-4-2): Carson 7½, Richards 8, Kompany 5 (76 Drenthe 6), Xavi 7, Ricardo Carvalho 7, Zanetti 6½, Hamit 6½, Seedorf 7½, Gilardino 7 (86 Bojan 6), Totti 6½, Mutu 6½ | | São Paulo | 0 |
| | 39 Denílson, 61 Richarlyson, 90+2 Quiroga | | (4-3-3): Bosco 8, Radamés 6½, Edcarlos 7, Josué 6½, Quiroga 7, André Dias 7, Leandro 6½, Richarlyson 6, Lenílson 6½, Denílson 6, Rodrigo Fabri 6½ | | Celta Vigo | 1 | 53 Pires | | Half-time: | 0-2 | | Referee: | Ruggiero 7 | | Attendance: | 31,712 | | Possession: | 53%-47% | | Total shots: | 8-18 | | MoM: | Park | | TV: | live |
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| | (4-3-3): Pinto 5, Ángel 7, Raúl Bravo 7½, Edmílson 7, Jaliens 7, Sergio 5½, Park 8, Pires 7, Fernando Baiano 6½ (60 José Castro 7½), Tacchinardi 6½, Javi Guerrero 7 | | Rosenborg | 4 | 33 Kvarme, 45 Iversen, 50 Helstad, 88 Iversen |
| | (4-3-3): Johnsen 5½, Kvarme 7, Stensaas 7½, Skjelbred 7, Riseth 7, Dorsin 6, Strand 7 (83 Braaten 6), Solli 6½, Helstad 7, Johnsen 6, Iversen 7 | | FC Porto | 2 | 13 Koné, 79 Fernandinho | | Half-time: | 1-1 | | Referee: | Stafoggia 7½ | | Attendance: | 39,604 | | Possession: | 55%-45% | | Total shots: | 14-15 | | MoM: | Fernandinho |
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| | (4-3-3): Paulo Ribeiro 7, Fernandinho 8, Seric 7, Raul Meireles 7½, Pedro Emanuel 7, Kenneth 6½, Liverani 8, César Peixoto 7½, Koné 7½, Schneider 7, Németh 5½ | | Santos | 2 | 28 Ángel, 63og Seric |
| | (4-3-3): Fábio Costa 6½, Kléber 6, Wendell 7, Pardo 6½, Ânderson Polga 7, Luíz Alberto 6½, Maldonado 6½, Pandev 6½, Ángel 6½, Danilinho 6½, Amoroso 6 | | FC Twente | 3 | 2 Elia, 30 Elia, 72 Koevermans | | Half-time: | 2-0 | | Referee: | Felgate 7 | | Attendance: | 13,135 | | Possession: | 49%-51% | | Total shots: | 13-9 | | MoM: | Boschker |
| | 49 Denneboom, 51 Engelaar, 82 Touma | | (4-3-3): Boschker 8, Wilkshire 7, Heubach 8, Touma 6½, Berezutsky 6½, Braafheid 7, Brama 6½, Engelaar 6½, Koevermans 7½, Denneboom 6½, Elia 6 | | Birmingham City | 0 |
| | 6 Latka, 28 Heskey, 39 Gray, 89 Tainio | | (4-3-3): Taylor 7, Finnan 7, Arca 7½, Butt 7, Latka 6, Painter 6½ (70 Clapham 6), Johnson 6½, Gray 5½, Shatskikh 7, Tainio 7, Heskey 6 | | Palermo | 0 |
| | Half-time: | 0-0 | | Referee: | Benkö 6½ | | Attendance: | 37,987 | | Possession: | 42%-58% | | Total shots: | 8-13 | | MoM: | Mareque |
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| | (4-3-3): Andújar 6½, Zenoni 5½, Biava 6½, Barone 7, Ferrari 6½, Capelli 6, Santana 6½, Mutarelli 7, Slavkovski 7 (80 Rodrigo 6), Di Michele 5½, Semioli 6 | | River Plate | 1 | 50 Pandiani | | 1 Zapata | | (4-3-3): Carrizo 7½, Ferrari 7½, Mareque 8, Montenegro 7½, Caceres 7, Talamonti 7, Patiño 7, Ivanschitz 6½ (64 Oberman 7½), Pandiani 7, Zapata 6½, Farías 6½ | | Parma | 1 | 41 Corradi | | Half-time: | 1-0 | | Referee: | Blareau 5½ | | Attendance: | 28,975 | | Possession: | 45%-55% | | Total shots: | 15-9 | | MoM: | Morrone |
| | 30 Paci, 84 Castellini | | (4-3-3): Bucci 7, Falcone 7½, Castellini 6, Morrone 8, Paci 7, Fernando Couto 7, Parravicini 7, Bresciano 7½, Corradi 6½, Reginaldo 5½, Pisanu 6½ | | Blackburn Rovers | 0 |
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| | (4-3-3): Jääskeläinen 7½, Yobo 7½, Baines 7, Cahill 7, Garay 7½, Todd 6½, Frings 7½, Davies 8, Anichebe 7, Fábio Simplício 6½, McCarthy 7½ | | SV Werder Bremen | 1 | 13 Valdez | | Half-time: | 1-0 | | Referee: | Angelov 7 | | Attendance: | 42,391 | | Possession: | 45%-55% | | Total shots: | 13-14 | | MoM: | Ibrahim |
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| | (4-3-3): Wiese 7, Khizanishvili 6, Van Damme 7½, Fahrenhorst 6½ (83 Lagerblom 6), Baumann 6½, Andreasen 6½, Savage 5½, Polenz 6½, Menseguez 7, Väyrynen 6½, Valdez 7 (83 Banecki 6) | | Besiktas | 1 | 83 Ibrahim |
| | (4-3-3): Volkan 7½, Turaci 7, Mehmet Seyfettin 7½, Tümer 7, Madlung 7, Ibrahim 6½, Okan 7½, Ibrahim 7½, Serkan 7, Gökhan 5½, Verpakovskis 6½ | | West Ham United | 0 |
| | Half-time: | 0-0 | | Referee: | Veiga Trigo 5½ | | Attendance: | 28,778 | | Possession: | 44%-56% | | Total shots: | 4-11 | | MoM: | Dheedene | | TV: | highlights |
| | 22 Dixon, 72 Robail | | (4-3-3): Blazek 7, Chimbonda 8, Capdevila 7½, Belaid 6, Lopo 7½, Ferdinand 6, Zabaleta 7½, Etherington 7, Dixon 6, Robail 5½, Lita 6½ | | FK Austria | 1 | 48 Linz |
| | (1-3-3-3): Caranta 7, Schiemer 7, Dheedene 8, Blanchard 7½, Papac 7 (79 Janocko 6), Tokic 7, Sionko 7½, Vachousek 7, Linz 7, Kiesenebner 6½, Lasnik 6 | | Round 3 | | FC Twente | 1 | 16 Engelaar | | Half-time: | 1-1 | | Referee: | Sundell 6½ | | Attendance: | 13,145 | | Possession: | 59%-41% | | Total shots: | 11-13 | | MoM: | Engelaar |
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| | (4-3-3): Boschker 6, Wilkshire 7½, Heubach 7½, Zomer 6½, Berezutsky 7, Braafheid 7, Brama 6½, Engelaar 7½, Koevermans 6½ (82 Gerritsen 6), Denneboom 6, Elia 6½ | | Santos | 2 | 24 Amoroso, 51 Maldonado |
| | (4-3-3): Fábio Costa 6, Kléber 6½, Wendell 6½, Pardo 7½, Ânderson Polga 7½, Luíz Alberto 6, Maldonado 7, Pandev 6½, Ángel 6, Danilinho 6, Amoroso 6½ | | Round 4 | | Besiktas | 2 | 2 Ibrahim, 36 Ibrahim | | Half-time: | 2-0 | | Referee: | Bogdanov 6½ | | Attendance: | 27,813 | | Possession: | 53%-47% | | Total shots: | 15-13 | | MoM: | Madlung |
| | 22 Okan, 72 Turaci | | (4-3-3): Volkan 6½, Turaci 7½, Mehmet Seyfettin 8, Tümer 7, Madlung 8½, Ibrahim 7½, Okan 7, Ibrahim 7½, Serkan 7½, Gökhan 6½, Verpakovskis 6 | | West Ham United | 2 | 82 Etherington, 88 Zabaleta | | 70 Belaid | | (4-3-3): Blazek 7, Chimbonda 6½, Capdevila 7½, Belaid 6½ (89 Hreiðarsson 6), Lopo 7, Ferdinand 6, Zabaleta 8, Etherington 7, Dixon 6, Robail 5½, Lita 5½ |
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