| Round 6 | | Aston Villa | 3 | 10 McCann, 15og Tymoschuk, 48 McCann | | Half-time: | 2-0 | | Referee: | Dunn 5 | | Attendance: | 42,383 | | Possession: | 48%-52% | | Total shots: | 10-11 | | MoM: | Bouma |
| | 78 McCann | | (4-3-3): Howard 7½, Hughes 8, Bouma 9, Mascherano 7½, Lescott 7, Ridgewell 6½, McCann 6½, Whittingham 6½, Figueroa 6½, Ballack 6½, McFadden 6 | | Shakhtar | 1 | 76 Tymoschuk |
| | (4-3-3): Lastùvka 7½, Stoican 6½, Schulz 7, Matuzalém 6½, Chyhrynskyi 7, Rat 7, Krasic 5½, Tymoschuk 7, Byelik 6½, Duljaj 7, Marica 6½ | | Espanyol | 3 | 2 Tamudo, 5 Morales, 60 Morales | | Half-time: | 2-0 | | Referee: | Styles 6½ | | Attendance: | 54,878 | | Possession: | 57%-43% | | Total shots: | 17-3 | | MoM: | Diarra | | TV: | highlights |
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| | (4-3-3): Kameni 7, Ilsinho 7, David García 7½, Diarra 8½, Fukal 8, Castro 6½, Juanfran 8, Morales 8, Tamudo 7, De La Peña 6, Luis García 7 | | Spartak | 1 | 79 Bilyaletdinov |
| | (4-3-3): Adler 6, Shishkin 6½ (62 Hammill 6), D'Alessandro 6½, Diego 7½, Evseev 6½, Titov 6, Kuijt 6, Bilyaletdinov 6½, Fred 7½, Sahar 6, Pavlenko 7 (73 Isidoro 5½) | | Fiorentina | 4 | 7 Donadel, 27 Cacau, 45 Mista, 59 Cacau | | Half-time: | 3-0 | | Referee: | Clark 7 | | Attendance: | 38,939 | | Possession: | 46%-54% | | Total shots: | 10-6 | | MoM: | Van Der Meyde | | TV: | highlights |
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| | (4-3-3): Calero 7, Di Loreto 5 (48 Bojinov 7), Kirilov 6½, Zanetti 7½, Rodríguez 6½, Dainelli 7, Godeas 7, Van Der Meyde 7½, Mista 6½, Donadel 6, Cacau 6½ | | Newcastle United | 0 |
| | 36 Cerný, 54 Dyer, 76 Davies | | (4-3-3): Cerný 7, Stalteri 6½, Nyatanga 7, Dyer 7½, Hübschman 7½, Davies 6, Bowyer 7, Emre 7, Saha 7½, Mido 6, Luque 6 | | Hamburger SV | 1 | 16 Yakubu | | Half-time: | 1-0 | | Referee: | Jorge Corroado 7 | | Attendance: | 54,976 | | Possession: | 60%-40% | | Total shots: | 14-9 | | MoM: | Jansen |
| | 49 Trochowski | | (4-3-3): Jentzsch 7½, Reveillère 6½, Jansen 8½, Beckham 7½, Nelsen 7½, Boulahrouz 7, Farfán 8½, Trochowski 7½, Yakubu 7½, Kahlenberg 6, Voronin 6 | | Deportivo | 0 |
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| | (4-3-3): Munúa 7½, Krøldrup 6½, Pander 6½, Valerón 7½, Jorge Andrade 7½, Konchesky 6½, Gallardo 6, Munitis 7, Xisco 7, Taborda 5½, Jô 6 | | Independiente | 1 | 65 Carlos Alberto | | Half-time: | 0-0 | | Referee: | Arena 7 | | Attendance: | 41,035 | | Possession: | 47%-53% | | Total shots: | 10-12 | | MoM: | Carlos Martins |
| | 69 Paletta, 85 Cardozo | | (4-3-3): Víctor Valdés 7, Rodríguez 7½, José Enrique 7, Carlos Martins 8, Paletta 7, Abraham 6, Ramón 6½, Cardozo 7, Sanogo 7, Culio 6½, Carlos Alberto 6½ | | Bayern München | 1 | 83 Makaay |
| | (4-3-3): Corona 6½, Salihamidzic 7½, Yepes 5½, Karimi 7, Demichelis 8, Görlitz 6, Dos Santos 6½, Zé Roberto 7, Santa Cruz 7½, Guerrero 5½, Makaay 6½ | | Manchester City | 1 | 40 Crespo | | Half-time: | 1-0 | | Referee: | Pellegrino 5½ | | Attendance: | 50,722 | | Possession: | 57%-43% | | Total shots: | 11-13 | | MoM: | Joaquín |
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| | (4-4-2): Van Der Sar 7½, Ayala 7 (74 Melli 6), De Cler 7½, Juanito 7, Makélélé 7, Dunne 6½ (66 Heitinga 7½), Joaquín 8, Rosický 8, Crespo 6½, Crouch 6½, Angulo 6 | | Feyenoord | 0 |
| | 18 Tomas | | (4-3-3): Mondragón 7½, Greene 7, Ergün 7½, Dessena 7½, Luizão 5½, Tomas 6½, Ricken 6½, Buckley 7, Amoah 7, Kalou 5½, Nihat 6½ | | Middlesbrough | 1 | 42 Downing | | Half-time: | 1-0 | | Referee: | Blankenstein 7½ | | Attendance: | 35,077 | | Possession: | 54%-46% | | Total shots: | 15-14 | | MoM: | Schwarzer | | TV: | live |
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| | (4-3-3): Schwarzer 7½, Parnaby 7, Queudrue 5½, Boateng 7½, Miyamoto 6½, Wheater 6, Cattermole 6½, Downing 7, Viduka 7, Doriva 7, Rivaldo 7 | | AEK | 1 | 78 Drogba | | 80 Gekas | | (4-3-3): Doni 6½, Ujfalusi 7, Bridge 6½ (71 Georgeas 7½), Diarra 7, Albiol 7, Alexopoulos 6, Wright-Phillips 7, López 6, Drogba 6, Gekas 6, Di Natale 5½ | | PSV | 0 |
| | Half-time: | 0-1 | | Referee: | Webb 5½ | | Attendance: | 35,088 | | Possession: | 54%-46% | | Total shots: | 14-10 | | MoM: | Albelda |
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| | (4-3-3): Loncaric 6, Nélson 7 (48 Lucius 7), Dedé 7½, Albelda 8½, Ooijer 7, Ânderson 6½, González 7, Ball 7, Koller 7½, Motta 6½, Ewerthon 6 | | Benfica | 2 | 5 Culina, 82 Geovanni | | 14 Quim, 73 Nuno Assis | | (4-3-3): Quim 6, Ben Haim 8, Léo 7½, Karagounis 7, André Bahia 6½, Nielsen 7, Geovanni 7, Beasley 7 (64 Nuno Assis 6½), Smolarek 6, Culina 7, Mantorras 5½ | | Paris SG | 2 | 2 Luyindula, 22 Jaurès | | Half-time: | 2-0 | | Referee: | Pinto Correia 7 | | Attendance: | 42,684 | | Possession: | 54%-46% | | Total shots: | 9-14 | | MoM: | Armand |
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| | (4-3-3): Létizi 7, Mendy 7½, Armand 8, Luccin 7, Distin 6 (57 Pino 7½), Pichot 6, Didot 7½, Jaurès 7, Luyindula 6, Berson 7, Frau 6½ | | Roma | 1 | 87 Afellay |
| | (4-3-3): Pelizzoli 7, Bovo 7½, Tonetto 7½, Afellay 7, Felipe 6½ (46 Volpato 6½), Motta 6, Sidwell 6½, Mauri 6½, Lucarelli 7 (59 Faye 6½), Hysén 6½, Ezquerro 6 | | Real Betis | 0 |
| | Half-time: | 0-1 | | Referee: | Stafoggia 6½ | | Attendance: | 41,968 | | Possession: | 57%-43% | | Total shots: | 19-12 | | MoM: | Elano | | TV: | highlights |
| | 81 Jarque | | (4-3-3): Doblas 7, Chica 7, Marc Torrejón 8, Petit 7½, Alex 8, Jarque 7 (82 Lafita 6), Raúl García 7, Elano 8, Yeste 7½, Marcos 7, Rosina 6½ | | Villarreal | 1 | 13 Font |
| | (4-3-3): Timmer 7, Labaka 7, Arruabarrena 6½, Miguel 7, Arzo 7, Peña 6, Font 6, Santi 7, Delgado 5½, Giménez 5½, Forlán 5½ | | Valencia | 1 | 1p Regueiro | | Half-time: | 1-2 | | Referee: | Knight 7 | | Attendance: | 42,134 | | Possession: | 44%-56% | | Total shots: | 10-11 | | MoM: | Zenoni |
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| | (4-4-2): Viera 6, Curro Torres 6½, Fábio Aurélio 7, Mathijsen 6½, Hofland 6½, Rothen 6, Regueiro 7, Daniel Carvalho 6, Menez 6½, Rufete 7, Schaars 6 | | Udinese | 2 | 9 Bonazzoli, 39 Bonazzoli |
| | (4-3-3): Ivankov 7, Sagnol 7½, Cantaluppi 7, O'Shea 7½, Sala 6½, Pedretti 6, Zenoni 8, Djordjevic 7, Bonazzoli 7½, Maresca 7, Ronaldo 6 | | Round 7 | | AEK | 2 | 33 Di Natale, 54 Diarra | | Half-time: | 1-0 | | Referee: | Hey 7 | | Attendance: | 58,684 | | Possession: | 44%-56% | | Total shots: | 10-10 | | MoM: | Chica |
| | 71 López | | (4-3-3): Doni 6½, Ujfalusi 7, Bridge 8, Diarra 6 (63 Lakis 7½), Albiol 6½, Alexopoulos 6½, Wright-Phillips 7, López 6½, Drogba 7, Gekas 6, Di Natale 5½ | | Real Betis | 1 | 61 Marcos | | 4 Rosina, 75 Petit, 77 Elano | | (4-3-3): Doblas 7½, Chica 8, Marc Torrejón 7½, Petit 7, Alex 8, Jarque 7 (82 Lafita 6), Raúl García 8, Elano 7½, Yeste 6½, Marcos 7, Rosina 6 | | Bayern München | 2 | 53 Santa Cruz, 73 Santa Cruz | | Half-time: | 0-1 | | Referee: | Reijgwart 6½ | | Attendance: | 41,070 | | Possession: | 46%-54% | | Total shots: | 10-16 | | MoM: | Santa Cruz |
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| | (4-3-3): Corona 6½, Salihamidzic 6½, Yepes 6, Karimi 6½, Demichelis 7, Görlitz 6, Dos Santos 6, Zé Roberto 6½, Santa Cruz 8, Guerrero 5½, Makaay 5½ | | Manchester City | 2 | 43 Crespo, 60 Rosický | | 21 Juanito | | (4-4-2): Van Der Sar 7, Ayala 7½, De Cler 7, Juanito 7, Makélélé 7, Dunne 6½ (66 Heitinga 8), Joaquín 8, Rosický 7, Crespo 6½, Crouch 7, Angulo 5½ | | Benfica | 1 | 16 Karagounis | | Half-time: | 1-2 | | Referee: | Collina 5½ | | Attendance: | 48,988 | | Possession: | 48%-52% | | Total shots: | 10-12 | | MoM: | Karagounis |
| | 7 Geovanni | | (4-3-3): Quim 5½, Ben Haim 7, Léo 6½, Karagounis 7½, André Bahia 6½, Nielsen 6½, Geovanni 6½, Beasley 7½, Smolarek 7, Culina 6½, Mantorras 7 | | Fiorentina | 3 | 14 Zanetti, 18 Kirilov, 81 Donadel | | 67 Cacau | | (4-3-3): Calero 6½, Di Loreto 6½ (48 Bojinov 6½), Kirilov 7, Zanetti 7½, Rodríguez 6½, Dainelli 7, Godeas 6½, Van Der Meyde 7, Mista 6, Donadel 6½, Cacau 6 | | Deportivo | 0 |
| | Half-time: | 0-1 | | Referee: | Reed 7½ | | Attendance: | 34,437 | | Possession: | 51%-49% | | Total shots: | 12-7 | | MoM: | Xisco |
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| | (4-3-3): Munúa 6½, Krøldrup 7½, Pander 7, Valerón 7, Jorge Andrade 6, Konchesky 6½, Gallardo 6, Munitis 7½, Xisco 7½, Taborda 6, Jô 7 | | Valencia | 1 | 44 Regueiro |
| | (4-4-2): Viera 7, Curro Torres 7, Fábio Aurélio 6½, Mathijsen 7, Hofland 7, Rothen 7½, Regueiro 7, Daniel Carvalho 7, Menez 6½, Rufete 7, Schaars 6½ | | Feyenoord | 1 | 30 Amoah | | Half-time: | 1-1 | | Referee: | Vraykov 7½ | | Attendance: | 36,226 | | Possession: | 56%-44% | | Total shots: | 13-10 | | MoM: | Buckley |
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| | (4-3-3): Mondragón 7, Greene 7½, Ergün 7½, Dessena 7½, Luizão 7½, Tomas 6½, Ricken 7, Buckley 8, Amoah 7, Kalou 6½, Nihat 7 | | Independiente | 1 | 32og Greene |
| | (4-3-3): Víctor Valdés 7, Rodríguez 7, José Enrique 6½, Carlos Martins 7½, Paletta 7, Abraham 6½, Ramón 6½, Cardozo 7, Sanogo 6½, Culio 5½, Carlos Alberto 6 | | Newcastle United | 2 | 65 Saha, 69 Saha | | Half-time: | 0-1 | | Referee: | Jol 6½ | | Attendance: | 46,841 | | Possession: | 45%-55% | | Total shots: | 11-12 | | MoM: | Didot |
| | 4 Emre, 24 Mido | | (4-3-3): Cerný 7, Stalteri 7, Nyatanga 6 (65 Chopra 6½), Dyer 7, Hübschman 7½, Davies 6, Bowyer 7, Emre 7, Saha 7, Mido 6, Luque 6 | | Paris SG | 1 | 28 Jaurès |
| | (4-3-3): Létizi 7½, Pichot 7½, Armand 7, Luccin 7, Distin 6½ (49 Berson 7), Mendy 6½, Didot 7½, Jaurès 7, Luyindula 6½, Dia 5½, Frau 7 | | Roma | 1 | 6 Hysén | | Half-time: | 1-1 | | Referee: | Van Vliet 5½ | | Attendance: | 45,277 | | Possession: | 47%-53% | | Total shots: | 7-15 | | MoM: | Mascherano |
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| | (4-3-3): Pelizzoli 6, Bovo 6, Tonetto 6½, Afellay 7½, Felipe 7, Motta 6, Sidwell 6, Mauri 7½, Lucarelli 6½, Hysén 6, Ezquerro 6 | | Aston Villa | 1 | 38 Figueroa |
| | (4-3-3): Howard 6½, Hughes 6½, Bouma 7½, Mascherano 8, Lescott 7½, Ridgewell 6½, McCann 7, Whittingham 6½, Figueroa 7, Ballack 6½, McFadden 7 | | Shakhtar | 2 | 14 Tymoschuk, 76 Tymoschuk | | Half-time: | 1-1 | | Referee: | Brncic 7 | | Attendance: | 40,285 | | Possession: | 52%-48% | | Total shots: | 18-11 | | MoM: | Matuzalém |
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| | (4-3-3): Lastùvka 6½, Stoican 6, Schulz 7, Matuzalém 8, Chyhrynskyi 6½, Rat 7, Krasic 7½, Tymoschuk 6 (77 Caffa 6), Byelik 7, Duljaj 7, Marica 6 | | PSV | 2 | 8 Ball, 48 Motta | | 30 Motta | | (4-3-3): Loncaric 7, Nélson 7, Dedé 8, Albelda 8, Ooijer 6½, Ânderson 6½, González 6½, Ball 7, Koller 6½, Motta 6½, Ewerthon 5½ | | Spartak | 1 | 4p Fred | | Half-time: | 1-1 | | Referee: | Krug 6½ | | Attendance: | 38,159 | | Possession: | 42%-58% | | Total shots: | 7-11 | | MoM: | Diego |
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| | (4-3-3): Adler 7, Shishkin 7, D'Alessandro 6, Diego 8, Evseev 6½, Titov 6, Kuijt 7, Bilyaletdinov 7, Fred 6½, Sahar 5½, Pavlenko 5½ | | Middlesbrough | 1 | 5 Viduka |
| | (4-3-3): Schwarzer 7, Parnaby 6, Queudrue 7½, Boateng 7½, Miyamoto 6½, Wheater 7, Cattermole 6, Downing 7½, Viduka 6½, Doriva 7, Rivaldo 6 |
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