| Round 6 | | Athletic Bilbao | 1 | 27 Llorente | | Half-time: | 1-0 | | Referee: | Sarvan 5½ | | Attendance: | 39,804 | | Possession: | 53%-47% | | Total shots: | 13-11 | | MoM: | Okan |
| | 17 Rivas | | (4-3-3): Aranzubía 6½, Expósito 7, Amorebieta 7½, Rivera 7, Cuéllar 7, Rivas 6½, Etxeberria 6½, Dañobeitia 7½, Llorente 7, Orbáiz 7, Recoba 7 | | Besiktas | 2 | 48 Serkan, 50 Ibrahim |
| | (4-3-3): Volkan 7, Turaci 7, Mehmet Seyfettin 6, Tümer 6½, Madlung 7, Ibrahim 6½, Okan 8, Ibrahim 6½, Serkan 6½, Gökhan 6, Verpakovskis 6 | | Auxerre | 3 | 10 Gourcuff, 34 Muratori, 39 Gomis | | Half-time: | 3-1 | | Referee: | Greth 6½ | | Attendance: | 21,997 | | Possession: | 42%-58% | | Total shots: | 13-12 | | MoM: | Raúl Bravo | | TV: | live |
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| | (4-3-3): Mandanda 6½, Sagna 6½, Muratori 7, Flamini 6½, Delpierre 6½, Planus 6½, Bellion 7, Gourcuff 7, Gomis 7, Cheyrou 5½ (49 Kaboul 6½), Gouffran 5½ | | Celta Vigo | 2 | 14 Pires, 62 Javi Guerrero | | 32 Ángel, 80 Jaliens | | (4-3-3): Pinto 7, Ángel 7, Raúl Bravo 7½, Edmílson 6½, Jaliens 7, Sergio 6½, Park 7, Pires 7, Fernando Baiano 6½ (60 José Castro 7), Tacchinardi 6½, Javi Guerrero 6½ | | Blackburn Rovers | 1 | 10 Baines | | Half-time: | 1-0 | | Referee: | Barber 6½ | | Attendance: | 31,274 | | Possession: | 54%-46% | | Total shots: | 20-9 | | MoM: | Cahill | | TV: | highlights |
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| | (4-3-3): Jääskeläinen 7, Yobo 7½, Baines 6½ (72 Tugay 6½), Cahill 9, Garay 8, Todd 6, Frings 7, Davies 8, Anichebe 6½, Fábio Simplício 7, McCarthy 6½ | | São Paulo | 0 |
| | 32 Souza, 61 Lenílson | | (4-3-3): Rogério 6½, Radamés 6, Edcarlos 7, Josué 7, André Dias 7, Quiroga 5½, Leandro 7, Danilo 6½, Lenílson 6½, Souza 6, Rodrigo Fabri 5½ | | Boca Juniors | 1 | 84 Buonanotte | | Half-time: | 0-0 | | Referee: | Sars 5½ | | Attendance: | 51,153 | | Possession: | 45%-55% | | Total shots: | 11-9 | | MoM: | Wendell | | TV: | highlights |
| | 33 João Coimbra, 87 Buonanotte | | (4-3-3): Sánchez 7½, Ibarra 7, Morel Rodríguez 7½, Juande 6½ (85 Obinna 6), Olarra 5½, Díaz 6, Guarín 7, João Coimbra 6, Sergio García 7, Palermo 6½, Buonanotte 6½ | | Santos | 0 |
| | 32 Ángel, 38 Ânderson Polga, 50 Danilinho | | (4-3-3): Fábio Costa 7½, Kléber 7, Wendell 8, Pardo 7½, Ânderson Polga 6½, Luíz Alberto 6½, Maldonado 7½, Pandev 7, Ángel 6½, Danilinho 6½, Amoroso 7 | | Borussia Dortmund | 1 | 63 Gilardino | | Half-time: | 0-0 | | Referee: | Reijgwart 5 | | Attendance: | 67,999 | | Possession: | 56%-44% | | Total shots: | 18-5 | | MoM: | Seedorf |
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| | (4-4-2): Carson 7½, Richards 7½, Kompany 6½ (76 Drenthe 6), Xavi 7½, Ricardo Carvalho 6½, Zanetti 7½, Hamit 7½, Seedorf 8, Gilardino 6½ (86 Bojan 6), Totti 7, Mutu 7½ | | West Ham United | 0 |
| | 61 Lopo | | (4-3-3): Blazek 7½, Chimbonda 7, Capdevila 7½, Belaid 6½, Lopo 6½, Ferdinand 6, Zabaleta 7, Etherington 7, Dixon 6, Robail 5½, Lita 6 | | FC Porto | 1 | 4 César Peixoto | | Half-time: | 1-0 | | Referee: | Kasnaferis 6 | | Attendance: | 40,716 | | Possession: | 45%-55% | | Total shots: | 10-9 | | MoM: | Seric |
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| | (4-3-3): Tiago 7½, Bosingwa 7½, Seric 8½, Raul Meireles 7, Dellas 7, Cirillo 6½, Fernandinho 6½ (47 Sonkaya 6½), César Peixoto 6½, Koné 6½ (59 Cech 6), Schneider 7½, Németh 7 | | Palermo | 0 |
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| | (4-3-3): Andújar 7, Zenoni 7, Biava 7, Barone 7½, Ferrari 6½, Capelli 6½, Santana 6½, Mutarelli 7½, Slavkovski 6½ (80 Rodrigo 6), Di Michele 6, Semioli 7½ | | FC Twente | 1 | 73 Engelaar | | Half-time: | 0-0 | | Referee: | Marriner 6½ | | Attendance: | 13,080 | | Possession: | 59%-41% | | Total shots: | 19-11 | | MoM: | Castellini |
| | 80 Braafheid | | (4-3-3): Boschker 7, Wilkshire 7, Heubach 7½, Zomer 7½, Berezutsky 7½, Braafheid 7½, Brama 7, Engelaar 7½, Koevermans 7½, Denneboom 6, Elia 6½ | | Parma | 1 | 76 Bresciano |
| | (4-3-3): Bucci 7½, Falcone 7, Castellini 8, Morrone 7 (74 Coly 7), Paci 7, Fernando Couto 7½, Parravicini 6, Bresciano 7, Corradi 7, Reginaldo 5½, Pisanu 6 | | FK Austria | 0 |
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| | (1-3-3-3): Caranta 6½, Schiemer 7, Dheedene 6, Blanchard 7½, Papac 7 (51 Janocko 7½), Tokic 7, Sionko 8, Vachousek 7, Linz 7, Kiesenebner 6, Lasnik 6 | | Marseille | 1 | 12 Niang |
| | (4-3-3): James 7½, Gabri 7½, Van Bronckhorst 8½, Ba 6½, Méité 6½, Civelli 6½, Pagis 6, Kehl 6½, Diané 6, Begeorgi 5½, Niang 7½ | | Rosenborg | 1 | 85 Helstad | | Half-time: | 0-0 | | Referee: | Nikolaev 5½ | | Attendance: | 21,128 | | Possession: | 53%-47% | | Total shots: | 6-17 | | MoM: | Ferrari |
| | 47 Helstad, 48 Stensaas, 75 Solli | | (4-3-3): Johnsen 7½, Strand 7, Stensaas 7, Skjelbred 6½, Tettey 7½, Dorsin 6, Essediri 7, Solli 6½ (86 Koppinen 6), Helstad 7, Storflor 6½, Iversen 6 | | River Plate | 1 | 52 Farías | | 45+1 Farías, 60 Ivanschitz, 69 Caceres | | (4-3-3): Carrizo 6½, Ferrari 7½, Mareque 6½, Montenegro 7, Caceres 6½, Talamonti 7 (69 Luciano Henrique 6), Patiño 7, Ivanschitz 6½, Reinaldo 7, Pandiani 5½, Farías 6 | | SV Werder Bremen | 0 |
| | | 12 Valdez, 24 Polenz | | (4-3-3): Wiese 7, Khizanishvili 8, Van Damme 6½, Fahrenhorst 7 (49 Lagerblom 7½), Baumann 6½, Andreasen 6, Savage 7, Polenz 6½, Menseguez 7, Väyrynen 6½, Valdez 7 (74 Banecki 6½) | | Anderlecht | 0 |
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| | (4-3-3): Friedel 7, Cicinho 7, Goor 7, Cambiasso 7, Hyypiä 6½, Coloccini 6, Wilhelmsson 7½, Cocu 6½, Caicedo 7½, Tiffert 5½, Mpenza 7 | | Round 7 | | Anderlecht | 0 |
| | Half-time: | 0-2 | | Referee: | Lekovic 6½ | | Attendance: | 27,874 | | Possession: | 42%-58% | | Total shots: | 13-20 | | MoM: | Flamini |
| | 45+2 Mpenza | | (4-3-3): Friedel 6, Cicinho 6½, Goor 7½, Cambiasso 7, Coloccini 6, Hyypiä 6, Wilhelmsson 6½, Cocu 7, Caicedo 6, Mpenza 6, Tomasson 7 | | Auxerre | 3 | 8 Gourcuff, 37 Gourcuff, 71 Gomis |
| | (4-3-3): Mandanda 6, Sagna 7, Muratori 7, Flamini 8, Delpierre 7½, Planus 6, Bellion 7, Gourcuff 7, Gomis 7, Cheyrou 7 (49 Kaboul 6½), Gouffran 5½ | | Besiktas | 1 | 80 Ibrahim | | Half-time: | 0-1 | | Referee: | Damgaard 6½ | | Attendance: | 27,906 | | Possession: | 38%-62% | | Total shots: | 7-12 | | MoM: | Cahill |
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| | (4-3-3): Volkan 7, Turaci 6½, Mehmet Seyfettin 6½, Tümer 7, Madlung 7, Ibrahim 6½, Okan 7½, Ibrahim 7, Serkan 6½, Gökhan 6½, Verpakovskis 5 | | Blackburn Rovers | 2 | 27 Davies, 74og Madlung |
| | (4-3-3): Jääskeläinen 6½, Yobo 8, Baines 6½ (72 Tugay 7½), Cahill 8, Garay 7½, Todd 7, Frings 6½, Davies 7½, Anichebe 6½, Fábio Simplício 6½, McCarthy 6 | | Birmingham City | 0 |
| | Half-time: | 0-0 | | Referee: | Alcock 7 | | Attendance: | 29,943 | | Possession: | 42%-58% | | Total shots: | 9-15 | | MoM: | Strand |
| | 17 Heskey, 22 Shatskikh, 31 Taylor, 33 Butt, 62 Gray, 78 Shatskikh, 86 Sibierski | | (4-3-3): Taylor 6, Finnan 6½, Arca 7½, Butt 7, Latka 6, Taylor 6½, Johnson 7½, Gray 6, Shatskikh 7, Heskey 5½, Sibierski 6 | | Rosenborg | 1 | 81 Solli |
| | (4-3-3): Johnsen 7, Strand 8, Stensaas 6, Skjelbred 7½, Braaten 7, Dorsin 7½, Essediri 7½, Solli 7, Helstad 7, Johnsen 6½, Iversen 6 | | Celta Vigo | 2 | 24 Pires, 33 Tacchinardi | | Half-time: | 2-0 | | Referee: | Luinge 6 | | Attendance: | 31,617 | | Possession: | 54%-46% | | Total shots: | 12-12 | | MoM: | Edmílson |
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| | (4-3-3): Pinto 7½, Ángel 7, Raúl Bravo 7, Edmílson 8, Jaliens 6 (49 José Castro 7½), Sergio 6½, Park 7, Pires 7, Fernando Baiano 6½, Tacchinardi 7½, Javi Guerrero 5½ | | FC Porto | 0 |
| | 9 Németh | | (4-3-3): Tiago 7½, Bosingwa 6½, Seric 7½, Raul Meireles 7½, Dellas 6½, Cirillo 6½, Fernandinho 6½, César Peixoto 6½, Koné 6, Schneider 6½, Németh 6 | | Marseille | 1 | 72 Niang | | Half-time: | 0-0 | | Referee: | Joslin 8 | | Attendance: | 44,794 | | Possession: | 45%-55% | | Total shots: | 18-10 | | MoM: | Sánchez |
| | 50 Kehl, 54 Méité | | (4-3-3): James 7½, Gabri 6½, Van Bronckhorst 6½, Ba 6, Méité 7½, Civelli 6½, Pagis 6½, Kehl 6½, Diané 7½, Begeorgi 5½, Niang 7½ | | Boca Juniors | 0 |
| | 78 Buonanotte | | (4-3-3): Sánchez 8, Ibarra 8, Morel Rodríguez 8, Juande 8, Olarra 7½, Díaz 7, Guarín 7½, João Coimbra 6, Sergio García 5½, Palermo 7, Buonanotte 6 | | Palermo | 3 | 30 Biava, 41 Santana, 50 Santana | | Half-time: | 2-2 | | Referee: | Shandor 5½ | | Attendance: | 37,837 | | Possession: | 49%-51% | | Total shots: | 13-16 | | MoM: | Van Damme |
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| | (4-3-3): Andújar 5½, Zenoni 7½, Biava 7, Barone 7½, Ferrari 7, Capelli 6, Santana 7, Mutarelli 6½, Slavkovski 6, Di Michele 6, Semioli 7 | | SV Werder Bremen | 3 | 7 Van Damme, 23og Barone, 71p Menseguez | | 79 Banecki, 90 Polenz | | (4-3-3): Wiese 6½, Khizanishvili 6½, Van Damme 8, Fahrenhorst 7 (49 Lagerblom 6½), Baumann 7½, Andreasen 6, Savage 7, Polenz 6, Menseguez 7, Väyrynen 6, Valdez 7 (74 Banecki 6) | | Parma | 1 | 27 Morrone | | Half-time: | 1-1 | | Referee: | Wilkie 5½ | | Attendance: | 29,057 | | Possession: | 50%-50% | | Total shots: | 16-21 | | MoM: | Morrone |
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| | (4-3-3): Bucci 7, Falcone 6½, Castellini 7, Morrone 8, Paci 7, Fernando Couto 6, Parravicini 6½, Bresciano 6½, Corradi 6½, Reginaldo 5½, Pisanu 5½ | | Borussia Dortmund | 1 | 36 Gilardino |
| | (4-4-2): Carson 7, Richards 7½, Kompany 6 (76 Drenthe 6), Xavi 7½, Ricardo Carvalho 7, Zanetti 7½, Hamit 7½, Seedorf 7, Gilardino 7 (86 Bojan 6), Totti 7, Mutu 7 | | River Plate | 2 | 1 Reinaldo, 14 Ivanschitz | | Half-time: | 2-0 | | Referee: | Pyanikh 5½ | | Attendance: | 37,070 | | Possession: | 56%-44% | | Total shots: | 10-11 | | MoM: | Montenegro |
| | 3 Farías | | (4-3-3): Carrizo 7, Ferrari 7, Mareque 7, Montenegro 8, Caceres 7, Talamonti 6½, Patiño 6 (53 Álvarez 7½), Ivanschitz 7, Reinaldo 7, Zapata 7, Farías 6½ | | Sevilla | 1 | 62 Kepa | | 51 Diego Capel | | (4-3-3): Riesgo 7, Javi Navarro 6½, González 7, Renato 6, Aitor Ocio 7, Prieto 6, Arteta 6½ (70 Rodri 6), Diego Capel 6½, Kepa 7, Martí 7, Asamoah 6½ | | Santos | 2 | 1 Ángel, 54 Amoroso | | Half-time: | 1-0 | | Referee: | Waddel 8 | | Attendance: | 28,199 | | Possession: | 52%-48% | | Total shots: | 13-11 | | MoM: | Cuéllar |
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| | (4-3-3): Fábio Costa 7, Kléber 6½, Wendell 6½, Pardo 7½, Ânderson Polga 7, Luíz Alberto 6, Maldonado 7, Pandev 7, Ángel 6½, Danilinho 6, Amoroso 7 | | Athletic Bilbao | 1 | 81 Etxeberria | | 5 Orbáiz, 18 Rivera, 79 Recoba | | (4-3-3): Aranzubía 6½, Expósito 6½, Amorebieta 7, Rivera 6½, Cuéllar 7½, Rivas 6, Etxeberria 7, Dañobeitia 6, Llorente 7, Orbáiz 6, Recoba 7 | | São Paulo | 2 | 14 Lenílson, 33 Josué | | Half-time: | 2-0 | | Referee: | Radivojevic 7½ | | Attendance: | 30,723 | | Possession: | 47%-53% | | Total shots: | 13-10 | | MoM: | Dheedene |
| | 5 Josué, 44 Danilo | | (4-3-3): Rogério 7½, Radamés 7, Edcarlos 6, Josué 7½, André Dias 6½, Quiroga 6 (58 Denílson 6), Leandro 7, Danilo 6, Lenílson 6½, Souza 6½ (70 Renan 6), Rodrigo Fabri 6½ | | FK Austria | 0 |
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| | (1-3-3-3): Caranta 7½, Schiemer 7, Dheedene 7½, Blanchard 7½, Papac 7 (51 Janocko 7½), Tokic 7, Sionko 7½, Vachousek 6½, Linz 7, Kiesenebner 6, Lasnik 5½ | | West Ham United | 0 |
| | Half-time: | 0-1 | | Referee: | Mustafa Ilker 7½ | | Attendance: | 31,017 | | Possession: | 44%-56% | | Total shots: | 7-16 | | MoM: | Heubach |
| | 44 Ferdinand, 67 Zabaleta | | (4-3-3): Blazek 5½, Chimbonda 7, Capdevila 6½, Belaid 6½, Lopo 7½, Ferdinand 6, Zabaleta 6½, Etherington 7, Dixon 6, Robail 5½, Lita 5½ | | FC Twente | 4 | 22 Elia, 49 Berezutsky, 83 Engelaar, 90 Braafheid | | 73 Zomer | | (4-3-3): Boschker 6, Wilkshire 8, Heubach 8½, Zomer 7, Berezutsky 7, Braafheid 7, Brama 8, Engelaar 7½, Koevermans 6½, Denneboom 6, Elia 6 |
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