| Round 5 | | Accrington Stan. | 2 | 15 Rose, 38 Welbeck | | Half-time: | 2-1 | | Referee: | Piller 5½ | | Attendance: | 31,010 | | Possession: | 59%-41% | | Total shots: | 17-6 | | MoM: | Rose |
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| | (4-3-3): Hart 7½, Smalling 7½, Rose 8½, Cahill 8, Jagielka 7½, Ramsey 7, Musa 7, Allen 7, Sturridge 7, Barkley 6 (81 Williams 6), Welbeck 7½ | | Feyenoord | 1 | 43 De Guzman |
| | (4-3-3): Alvarado 6½, Hutchinson 7, Pieters 6, Leerdam 7, Maduro 6½, Schenkeveld 6, Kuyt 7, De Guzman 7, Castaignos 6, Van Wolfswinkel 5½, Jóhannsson 5½ | | Bayer Leverkusen | 0 |
| | Half-time: | 0-0 | | Referee: | Braschi 5 | | Attendance: | 22,413 | | Possession: | 54%-46% | | Total shots: | 12-12 | | MoM: | Schulz |
| | 69 Zárate | | (4-3-3): Giefer 5, Fritz 6, Schulz 8½, Cambiasso 7, Díaz 7, Servet 6½, Elano 7, Kakuta 7½, Kuranyi 7, Arango 5½, Zárate 6 | | Marseille | 4 | 63 Benzema, 76 Menez, 81 Tabanou, 87 Tabanou | | 6 Benzema, 51 Lamela | | (4-3-3): Riou 5½, Richarlyson 6½, Tabanou 8, Lamela 7, Kolodziejczak 8, Kaboré 6½, Pjanic 7½, Menez 6½, Abriel 6½ (49 Jarvis 6), Ben Arfa 7 (53 González 6½), Benzema 6½ | | FC Schalke 04 | 2 | 7 Crouch, 79 Durm | | Half-time: | 1-3 | | Referee: | Jol 8 | | Attendance: | 42,058 | | Possession: | 51%-49% | | Total shots: | 11-16 | | MoM: | Farfán |
| | 32 De Jong, 76 Farfán | | (4-3-3): Mielitz 6, Kelly 7, Durm 6½, Costa 6, Williamson 7, Avevor 6, Farfán 7½, Barnetta 7, Crouch 6, De Jong 6, Elmander 6 | | Ajax | 4 | 23 Huntelaar, 38 Sneijder, 45 Sneijder, 64og Costa |
| | (4-3-3): Krul 5½, Van Der Wiel 7, Willems 6½, De Jong 7½, De Vrij 7, Van Rhijn 6½, Promes 6½, Lens 7, Huntelaar 6½, Sneijder 7, Narsingh 6 | | Internacional | 2 | 19 Wágner, 60 Taison | | Half-time: | 1-1 | | Referee: | Silagailis 7 | | Attendance: | 55,984 | | Possession: | 62%-38% | | Total shots: | 19-11 | | MoM: | Mariano | | TV: | live |
| | 1 Fred | | (4-3-3): Fernando Henrique 6½, Mariano 8½, Kléber 6 (82 Marquinhos Gabriel 6), Fernando 8, Hilton 7½, Marcelo 7½, Giuliano 8, Wágner 8, Jô 7½, Fred 6, Taison 7½ | | Celtic | 1 | 8 McGeady | | 1 Cissé, 21 Cissé, 78 McGeady | | (4-3-3): Boruc 6½, José Ángel 5½, Izaguirre 7, Cahill 7, Rogne 6, Brown 5½, Oliver 6, McGeady 6½, Cissé 6½, Cissé 5½, Keane 6½ | | Lorient | 0 |
| | Half-time: | 0-2 | | Referee: | Larsen 6 | | Attendance: | 15,789 | | Possession: | 47%-53% | | Total shots: | 15-14 | | MoM: | Morel | | TV: | highlights |
| | 11 Diarra, 26 Pied, 44 Amalfitano | | (4-3-3): Guerrieri 5½, Congré 6½, Morel 8½, Mvuemba 6½, Puygrenier 7½, Kanté 6, Amalfitano 7½, Diarra 6½, Sagbo 7½, Pied 7 (57 Mignot 6), Birsa 5½ | | TSG Hoffenheim | 3 | 3 Maicosuel, 45+1 Sessègnon, 55 Salihovic | | 27 Ebondo | | (4-3-3): Fährmann 5½, Ebondo 7, Didac 6½, Maicosuel 7½, Ruíz 6½, Mangane 6, Zuculini 6, Carlos Eduardo 7, Ibisevic 7 (46 Gross 7), Salihovic 6½, Sessègnon 7 (62 Ogbuke 6½) | | Manchester City | 2 | 5 Vertonghen, 39 Vucinic | | Half-time: | 2-0 | | Referee: | Rennie 5½ | | Attendance: | 35,355 | | Possession: | 47%-53% | | Total shots: | 17-9 | | MoM: | Raúl Baena |
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| | (4-3-3): Arrizabalaga 6½, Sagna 7, Vertonghen 7, Källström 7, Vidic 7½, Badstuber 7½, Rodríguez 6½, Herrmann 6½, Soldado 6½, Ocampos 6, Vucinic 7½ | | Espanyol | 1 | 52 Pareja | | 50 Olic | | (4-3-3): Álvarez 7, Roncaglia 6½, Coke 6½, Raúl Baena 8, Pareja 7, Hangeland 6½, Corominas 7, Verdú 6, Tamudo 6½, Juanmi 6½, Olic 5½ | | Manchester United | 1 | 53 O'Shea | | Half-time: | 0-0 | | Referee: | Borriello 5½ | | Attendance: | 33,765 | | Possession: | 46%-54% | | Total shots: | 7-14 | | MoM: | Berbatov | | TV: | highlights |
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| | (4-3-3): Kuszczak 6½, Rafael 6½ (48 Gibson 7), Santon 7, Carrick 7, Matip 6½, O'Shea 6, Giovani 6½, King 6, Berbatov 7½, Shelvey 6, Diouf 5½ | | Napoli | 1 | 57 Mokotjo | | 4 El Kaoutari, 62 Keita | | (4-3-3): Sepe 7, Campagnaro 7½, El Kaoutari 6, Keita 7½, Cannavaro 7½, Gastaldello 6½, Cigarini 6, Gargano 6½, Gignac 7, Mokotjo 7 (58 Aronica 7), Quagliarella 6½ | | River Plate | 0 |
| | Half-time: | 0-1 | | Referee: | Oskam 7 | | Attendance: | 47,523 | | Possession: | 45%-55% | | Total shots: | 9-7 | | MoM: | Kombarov |
| | 14 Castillejos, 50 López | | (4-3-3): Caballero 7, Mercado 6½, Basanta 7, Buonanotte 6, Cabral 7, López 6, Formica 6, Amrabat 7, López 7½, Castillejos 6, Víctor 5 | | Spartak | 1 | 43 Dzagoev | | 56 Berezutsky, 75 Makeev, 87 Zhirkov | | (4-3-3): Ryzhikov 7½, Parshivlyuk 6½, Kombarov 8, Mamaev 6½, Makeev 6, Berezutsky 7, Zhirkov 6½, Dzagoev 7½, Rondón 6½, Ozdoev 6½, Yakovlev 7 | | Sevilla | 2 | 21 Kiessling, 56 Kiessling | | Half-time: | 1-0 | | Referee: | Brito Arceo 6 | | Attendance: | 34,587 | | Possession: | 47%-53% | | Total shots: | 11-8 | | MoM: | Vrsaljko | | TV: | highlights |
| | 64 Navas | | (4-3-3): Navas 8, Silvestre 8, Fernando Navarro 7½, Raul Meireles 7½, Naldo 7, Squillaci 6½, Navas 7, Luscombe 6½, Kiessling 6½, Makoun 6½, Kiko 6½ | | Liverpool | 0 |
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| | (4-3-3): Pyatov 7, Vrsaljko 8½, Insúa 7, Badelj 7, Taylor 6½, Nolan 6, Aleksic 5½, Vitolo 6½, Carroll 8, Keane 6, Németh 5½ | | Tottenham Hotspur | 0 |
| | | 45+2 Gabbiadini | | (4-3-3): Leno 5½, Cáceres 6½, Cole 7, Shirokov 7, Rami 7½, Álvarez 6½, Wickham 6, Nani 7, Torres 6, Fierro 5½, Gabbiadini 5½ | | Palermo | 3 | 4 Cassano, 7 Insigne, 15 Cassano |
| | (4-4-2): Consigli 6, Darmian 7½, Montolivo 7½, Moretti 7½, Bonaventura 7½, Astori 7, Criscito 7½, Cassano 6½, Candreva 7, Inler 6, Insigne 7 | | Viktoria Plzen | 3 | 10 Kadlec, 18 Lafata, 39 Kolár | | Half-time: | 3-0 | | Referee: | Sedlacek 7½ | | Attendance: | 44,849 | | Possession: | 62%-38% | | Total shots: | 18-6 | | MoM: | Hübschman |
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| | (4-3-3): Vaclik 7½, Gebre Selassie 7½, Kadlec 7½, Darida 7½, Hübschman 8, Suchý 6½, Kolár 7½, Rosický 7½, Vydra 7, Sivok 7½, Lafata 7 | | SV Werder Bremen | 0 |
| | 3 Parish | | (4-4-2): Parish 6½, Prödl 8, Diego Capel 5½, Bargfrede 6½, Smith 5½, Samaris 6, Oar 6, Hunt 6½, Dost 6½, Fetfatzidis 6, Wagner 5½ | | Round 3 | | FC Schalke 04 | 3 | 23 De Jong, 26 Barnetta, 76 Kroos | | Half-time: | 2-3 | | Referee: | Beschin 7 | | Attendance: | 35,723 | | Possession: | 43%-57% | | Total shots: | 7-16 | | MoM: | El Kaoutari |
| | 90 Avevor | | (4-3-3): Mielitz 5, Kelly 7 (80 Simpson 6), Durm 6½, Träsch 6½, Williamson 6, Avevor 6½, Farfán 7, Barnetta 6½, De Jong 7½, Hugo Almeida 5½ (53 Kroos 6½), Elmander 5½ | | Napoli | 4 | 13 Gargano, 24 Gignac, 34 Keita, 70 Quagliarella | | 20 Cannavaro, 82 Quagliarella | | (4-3-3): Sepe 5½, Campagnaro 7, El Kaoutari 8, Keita 8, Cannavaro 7, Gastaldello 6, Cigarini 7, Gargano 6½ (61 Necip 6½), Gignac 7, Mokotjo 6, Quagliarella 6½ | | Tottenham Hotspur | 3 | 8 Shirokov, 50 Gabbiadini, 57 Nani | | Half-time: | 1-0 | | Referee: | López Nieto 6½ | | Attendance: | 30,195 | | Possession: | 54%-46% | | Total shots: | 11-15 | | MoM: | Crescenzi |
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| | (4-3-3): Leno 7½, Cáceres 8, Cole 7½, Shirokov 5½ (63 Crescenzi 8½), Rami 7, Álvarez 5½, Wickham 6½, Nani 7½, Torres 7, Fierro 5½, Gabbiadini 6½ | | TSG Hoffenheim | 1 | 65 Ba |
| | (4-3-3): Fährmann 7, Ebondo 6, Didac 7½, Maicosuel 7, Ruíz 6½, Amat 6½, Salihovic 6½, Carlos Eduardo 7, Ba 6½, Ibisevic 6½ (71 Zuculini 6), Sessègnon 6 | | Accrington Stan. | 3 | 27 Sturridge, 32 Sturridge, 51 Welbeck | | Half-time: | 2-1 | | Referee: | Cardona 5½ | | Attendance: | 30,922 | | Possession: | 57%-43% | | Total shots: | 19-9 | | MoM: | Musa |
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| | (4-3-3): Hart 7, Smalling 7½, Rose 7, Cahill 7, Jagielka 7, Ramsey 6½, Musa 8, Allen 6½, Sturridge 7½, Barkley 5½ (81 Williams 6), Welbeck 6½ | | Marseille | 2 | 11 Menez, 88 Menez | | 45+4 Kolodziejczak, 61 Menez, 73 Benzema | | (4-3-3): Riou 6, Richarlyson 5½, Tabanou 7, Lamela 7, Kolodziejczak 6, Kaboré 6, Pjanic 7, Menez 6, Abriel 6½, Ben Arfa 6½, Benzema 6 |
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