| Round 5 | | Baník Ostrava | 3 | 1 Giroud, 24 Arda, 48 Giroud | | Half-time: | 2-0 | | Referee: | Van Vliet 6 | | Attendance: | 17,294 | | Possession: | 54%-46% | | Total shots: | 14-14 | | MoM: | Arda |
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| | (4-3-3): Perin 7½, Hubocan 7½, Asamoah 7½, Medel 7½, Varane 5½ (67 Kondogbia 7), N'Koulou 6½, Traoré 6½, Arda 7½, Giroud 7, Arnold 6½, Totti 7 (68 Moreno 6½) | | Internacional | 0 |
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| | (4-3-3): Alisson 7, Danilo 7, Kléber 7, Fernando 7½, Hilton 6½, Marcelo 6, Marquinhos Gabriel 6½, Wellington Silva 6½, Walter 6½, João Pedro 6, Taison 6 | | Bayern München | 0 |
| | Half-time: | 0-0 | | Referee: | Rudy 7 | | Attendance: | 50,031 | | Possession: | 43%-57% | | Total shots: | 10-7 | | MoM: | Novillo |
| | 57 Forlin, 90+1 Coman | | (4-3-3): Andújar 6½, Essien 7, Ignjovski 7½, Sahin 7, Papastathopoulos 6½, Djourou 6½, Coman 7½, Ribéry 7, Aubameyang 6½, Forlin 6½, Anelka 6 | | Sevilla | 1 | 90+1 Piatti | | 35 Aleix Vidal | | (4-3-3): Navas 7, Silvestre 6½, Fernando Navarro 7, Renato 7 (70 Novillo 7½), Rami 7½, Naldo 7, Aleix Vidal 7½, Piatti 7, Kiessling 7, Kiko 6, Giovinco 6 | | Cruz Azul | 0 |
| | Half-time: | 0-0 | | Referee: | Young 7½ | | Attendance: | 35,876 | | Possession: | 54%-46% | | Total shots: | 15-9 | | MoM: | De Marcos |
| | 80 Ochs | | (4-3-3): Corona 7½, De Marcos 8, Riedewald 7½, Hamsík 7½, Castro 7½, Pereira 7½, Fellaini 7, Suso 7, João Pereira 6, Torrado 6½, Ochs 5½ | | Manchester City | 0 |
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| | (4-3-3): Bravo 8, Sagna 6½, Clichy 8, Touré 7, Kolarov 6½, Mangala 6, Navas 7½, Sané 7½, Ambrose 6, Källström 6½, Rodríguez 6 | | Deportivo | 3 | 4 Guardado, 41 Guardado, 89 Guardado | | Half-time: | 2-1 | | Referee: | Michel 6½ | | Attendance: | 34,551 | | Possession: | 48%-52% | | Total shots: | 15-7 | | MoM: | Angulo |
| | 22 Pablo Álvarez, 60 Guardado, 87 Colotto | | (4-3-3): Guilherme 7, Arbilla 7½, Jaume 5½ (55 Renato Silva 7½), Juan Domínguez 6½ (55 Angulo 7½), Colotto 7, José Castro 6, Pablo Álvarez 6, Guardado 7, Adúriz 7, Juan Rodríguez 6, Sabin 7 | | Dynamo | 1 | 45+2 Kravets | | 47 Pienaar, 64 Bystrov, 77 Blanco | | (4-3-3): Carrasso 6½, Vida 7, Nesmachnyi 7½, Harmash 7, Mykhalyk 7, Khacheridi 6, Bystrov 7, Blanco 6, Milevskyi 7, Pienaar 7, Kravets 6 | | Feyenoord | 4 | 23 De Guzman, 44 De Guzman, 45+1 Kuyt, 62p Castaignos | | Half-time: | 3-2 | | Referee: | Collina 6½ | | Attendance: | 44,551 | | Possession: | 54%-46% | | Total shots: | 12-10 | | MoM: | Kuyt | | TV: | live |
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| | (4-3-3): Vermeer 6½, Hutchinson 8, Pieters 6½, Leerdam 7½, Kongolo 7½, Van Beek 7½, Kuyt 8½, De Guzman 7, Castaignos 7½, Van Wolfswinkel 6½, Schaken 6½ | | Tottenham Hotspur | 2 | 12 Cáceres, 36 Vertonghen | | 34 Wickham, 67 Matavz | | (4-3-3): Leno 7, Cáceres 7½, Vertonghen 6½, Locatelli 6½, Ogbonna 7½, Álvarez 5½, Foor 6½ (53 Benitez 6½), Nani 5½, Matavz 6½, Wickham 5½, Gabbiadini 6½ | | Flamengo | 0 |
| | Half-time: | 0-0 | | Referee: | López Nieto 5½ | | Attendance: | 30,889 | | Possession: | 54%-46% | | Total shots: | 12-9 | | MoM: | Willians | | TV: | highlights |
| | 44 Marlos | | (4-3-3): Muriel 6½, Danilo Silva 7½, Adriano 7½, Willians 7½, Xandão 7, Samir 6, Belluschi 7½, Marlos 6½, Luiz Adriano 7, Everton 6½, Emerson 6 | | Manchester United | 2 | 55 Herrera, 83 Darmian |
| | (4-3-3): Amos 6, McNair 6½, Darmian 6½, Pogba 7, Blind 7, O'Shea 6½, Giovani 7, Lingard 7 (55 Obertan 6), Berbatov 6, Herrera 6, Martial 7 | | Hansa Rostock | 1 | 62 Goretzka | | Half-time: | 0-0 | | Referee: | Martin Navarrete 6 | | Attendance: | 28,845 | | Possession: | 53%-47% | | Total shots: | 18-13 | | MoM: | Johnson | | TV: | highlights |
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| | (4-3-3): Howard 7½, Piszczek 7½, Johnson 8, Gündogan 7½, Madlung 6, Pekarík 7½, Polanski 6½ (51 Dejagah 6), Goretzka 7½, Benteke 6, Schäfer 5½, Martins 6 | | CS Constantine | 1 | 76 Bony |
| | (4-3-3): Kameni 7½, Mandi 7½, Ghoulam 7, Witsel 8, Benatia 6½, Kouyaté 6, Belhanda 6½, Brahimi 6½, Bony 7, Taïder 6½, N'Jie 6 | | Newport County | 1 | 14 Bertrand | | Half-time: | 1-2 | | Referee: | Norman 7 | | Attendance: | 19,351 | | Possession: | 53%-47% | | Total shots: | 10-9 | | MoM: | Tomkins | | TV: | highlights |
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| | (4-3-3): McGregor 6, Tomkins 8, Bertrand 8, Badu 7, Dummett 7, Clark 7, Cleverley 7½, Ayew 6½ (79 Acheampong 6), Woodrow 7, Livermore 7 (80 Mowatt 6), Phillips 5½ | | Benfica | 2 | 15 Drogba, 24 César Peixoto | | 64 César Peixoto, 80 Eliseu | | (4-3-3): Lopes 6, Bosingwa 7, Eliseu 7½, Javi García 7, Ricardo Carvalho 7, Ayala 6½, Ruben Amorim 6, César Peixoto 6½, Drogba 7½, André Almeida 6, Cardozo 6½ | | Paris SG | 2 | 7 Jussiê, 68 Gakpé | | Half-time: | 1-0 | | Referee: | Piraux 7 | | Attendance: | 41,534 | | Possession: | 51%-49% | | Total shots: | 16-11 | | MoM: | Thiago Silva |
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| | (4-3-3): Trapp 7, Marquinhos 6½, Trémoulinas 7½, Stambouli 7½, Thiago Silva 8, Sané 6½, Traoré 6½, Gakpé 6½, Cavani 7, Sertic 6½, Jussiê 7 | | River Plate | 1 | 70 López | | 49 Castillejos | | (4-3-3): Caballero 6½, Mercado 7, Basanta 7, Johansen 7, Cabral 6, López 5½, Formica 6½, Buonanotte 6½, López 7, Castillejos 5½, Villalva 7 (46 Díaz 5½) | | Spartak | 3 | 9 Dzagoev, 11 Rondón, 21 Dzagoev | | Half-time: | 3-0 | | Referee: | Sarvan 7½ | | Attendance: | 39,160 | | Possession: | 58%-42% | | Total shots: | 23-4 | | MoM: | Ozdoev |
| | 45+1 Arshavin | | (4-3-3): Ryzhikov 7½, Mário Fernandes 7½, Kombarov 7, Ozdoev 8, Berezutsky 7, Makeev 6½, Bazhenov 6, Dzagoev 7½, Rondón 7½, Mamaev 7½, Arshavin 6 | | Fenerbahçe | 0 |
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| | (4-4-2): Serkan 7½, Gökhan 6½, Bekir 8, Özer 7, Egemen 6½, Remzi Giray 5½, Sezer 6½, Cech 6, Serdar 6, Serkan 5½, Ødegaard 6 | | Viktoria Plzen | 0 |
| | Half-time: | 0-0 | | Referee: | Dondarini 5 | | Attendance: | 34,842 | | Possession: | 51%-49% | | Total shots: | 16-13 | | MoM: | Raúl García |
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| | (4-3-3): Vaclik 6½, Gebre Selassie 6, Kadlec 7, Plasil 7, Hübschman 6½, Suchý 6, Kolár 7, Krejcí 6½, Tecl 7, Darida 6½, Lafata 6½ | | Brøndby | 1 | 83 Mirallas |
| | (4-3-3): Sirigu 7, Jantschke 6½, Lulic 7½, Raúl García 7½, Corluka 7, Zapata 6½, Pérez 6½ (47 Nagatomo 7½), Gervinho 7, Toivonen 6½, Selçuk 7, Mirallas 6½ | | Round 3 | | Bayern München | 1 | 36 Ribéry | | Half-time: | 1-1 | | Referee: | Onufer 6 | | Attendance: | 44,371 | | Possession: | 55%-45% | | Total shots: | 17-15 | | MoM: | Sahin |
| | 90+2 Aubameyang | | (4-3-3): Andújar 7, Essien 7, Ignjovski 6½, Sahin 8, Papastathopoulos 7½, Djourou 6½, Coman 6½, Ribéry 7½, Aubameyang 7, Forlin 6½, Anelka 5½ | | Brøndby | 1 | 19 Jantschke |
| | (4-3-3): Sirigu 7, Jantschke 7½, Lulic 6½, Raúl García 8, Corluka 8, Zapata 6, Pérez 7 (47 Nagatomo 6½), Gervinho 7, Toivonen 5½, Selçuk 6, Mirallas 5½ | | Viktoria Plzen | 3 | 22p Tecl, 57 Hübschman, 59 Krejcí | | Half-time: | 1-0 | | Referee: | Ziller 6½ | | Attendance: | 29,255 | | Possession: | 47%-53% | | Total shots: | 11-13 | | MoM: | Ghoulam |
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| | (4-3-3): Vaclik 7½, Gebre Selassie 7, Kadlec 7, Plasil 5½ (54 Hlousek 7½), Hübschman 6½, Suchý 6½, Kolár 6½, Krejcí 7, Tecl 6½, Darida 6, Lafata 6½ | | CS Constantine | 1 | 90+1 Bony |
| | (4-3-3): Kameni 6½, Mandi 7½, Ghoulam 7½, Witsel 7, Benatia 7, Kouyaté 6½, Belhanda 7½, Brahimi 7, Bony 7, Taïder 7, N'Jie 6 | | Round 4 | | River Plate | 1 | 68 Castillejos | | Half-time: | 0-1 | | Referee: | Pyanikh 6½ | | Attendance: | 30,744 | | Possession: | 55%-45% | | Total shots: | 20-12 | | MoM: | Hamsík |
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| | (4-3-3): Caballero 6½, Mercado 7½, Basanta 7, Johansen 7, Cabral 6½, López 7, Formica 7½, Buonanotte 8, López 7, Castillejos 6, Villalva 6½ (46 Díaz 5½) | | Cruz Azul | 2 | 41 Suso, 82 Hamsík |
| | (4-3-3): Corona 6, De Marcos 7, Riedewald 7, Hamsík 8, Castro 6½, Fellaini 5½, Torrado 6½, Suso 7½, João Pereira 6½ (69 Pereira 6½), Ishige 6, Ochs 5½ | | Round 3 | | Feyenoord | 3 | 18 Castaignos, 65 Leerdam, 83 Castaignos | | Half-time: | 1-1 | | Referee: | Dowd 8 | | Attendance: | 48,797 | | Possession: | 49%-51% | | Total shots: | 15-12 | | MoM: | Leerdam |
| | 22 Hutchinson, 30 Van Wolfswinkel | | (4-3-3): Vermeer 6½, Hutchinson 7, Pieters 6, Leerdam 8, Kongolo 7, Van Beek 7, Kuyt 7, De Guzman 7, Castaignos 7, Van Wolfswinkel 6, Schaken 5½ | | Sevilla | 1 | 2 Kiessling | | 13 Silvestre, 24 Piatti | | (4-3-3): Navas 7½, Silvestre 7, Fernando Navarro 7½, Renato 7½, Rami 7, Naldo 6½, Aleix Vidal 7 (82 Luscombe 6), Piatti 6½, Kiessling 6½, Kiko 6, Giovinco 6½ |
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