| Round 5 | | Baník Ostrava | 1 | 58 Di Natale | | Half-time: | 0-1 | | Referee: | Braschi 7½ | | Attendance: | 17,269 | | Possession: | 52%-48% | | Total shots: | 22-14 | | MoM: | Barzagli | | TV: | live |
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| | (3-4-3): Courtois 7½, Di Natale 7, Filipe Luis 5½, N'Koulou 6½, Busquets 7, Barzagli 7½, Kuba 6½, Hubocan 6, Arda 7, Giroud 6½, Totti 6½ | | Espanyol | 2 | 29 Tamudo, 73 Tamudo | | 84 Raúl Baena | | (4-3-3): Álvarez 6, Chica 7, Pinto 6, Ninkovic 7½, Pareja 6½, Roncaglia 6½, Callejón 6½, Verdú 6, Tamudo 6½, Raúl Baena 6, Olic 6½ | | Bayer Leverkusen | 2 | 3 Castro, 6 Castro | | Half-time: | 2-1 | | Referee: | Beeby 7 | | Attendance: | 22,408 | | Possession: | 43%-57% | | Total shots: | 5-14 | | MoM: | Fritz |
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| | (4-3-3): Wiese 6½, Piszczek 7, Arango 5½, Cambiasso 7, Friedrich 6½, Díaz 6, Fritz 8, Castro 6½, Kuranyi 7, Rubén Pérez 7, Kakuta 6 | | FC Schalke 04 | 1 | 30 Farfán | | 19 Träsch | | (4-3-3): Bailly 7, Westermann 6½, Rausch 7½, Träsch 6½ (70 Kelly 6½), Salcido 7, Williamson 6½, Farfán 6½, Costa 6½, De Jong 7, Gündogan 7, Elmander 6½ | | Bayern München | 4 | 11 Pranjic, 35 Pranjic, 62 Marin, 70 Pranjic | | Half-time: | 2-0 | | Referee: | Clattenburg 7 | | Attendance: | 54,653 | | Possession: | 54%-46% | | Total shots: | 18-15 | | MoM: | Palacios |
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| | (4-3-3): Andújar 7½, Görlitz 7, Pranjic 6½, Ignjovski 8, Papastathopoulos 7, Senderos 7, Palacios 8, Marin 7, Barrios 7, Diaby 7, Anelka 7 | | Spartak | 0 |
| | 3 Arshavin, 42 Yakovlev, 64 Rondón | | (4-3-3): Ryzhikov 7½, Parshivlyuk 7, Yanbaev 6, Mamaev 7 (84 Komisov 6), Makeev 6½, Zhirkov 7, Bazhenov 6½, Torbinsky 6, Rondón 6½, Yakovlev 6, Arshavin 6 | | Genoa | 0 |
| | Half-time: | 0-0 | | Referee: | Webb 6 | | Attendance: | 36,445 | | Possession: | 50%-50% | | Total shots: | 21-14 | | MoM: | Nagatomo |
| | 58 Antonini | | (4-3-3): Landreau 7½, Onuoha 6½, Nagatomo 7½, Bogliacino 7, André Dias 6½, Antonini 6, Kharja 6, Sculli 6½, Acquafresca 6, Zapater 6, Immobile 7 | | Helsingborg | 0 |
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| | (4-3-3): Marchetti 7½, Abate 6, Santon 7½, Olsson 6½, Agger 7½, Wernbloom 6½, Giovinco 7, Elm 6½, Finnbogason 6, Eriksen 6, Balotelli 6½ | | Internacional | 1 | 56 Wágner | | Half-time: | 0-0 | | Referee: | Marriner 7 | | Attendance: | 47,673 | | Possession: | 52%-48% | | Total shots: | 14-12 | | MoM: | Wágner | | TV: | highlights |
| | 71 Jô | | (4-3-3): Rafael 7½, Mariano 7, Marcelo 6½, Sandro 6½ (69 João Pedro 7), Hilton 7, Giuliano 6½, Fernando 7, Wágner 7½, Fred 6½ (72 Dalton 7), Jô 6, Taison 6½ | | Feyenoord | 1 | 68 Castaignos |
| | (4-3-3): Mulder 7½, De Vrij 6½, Pieters 6½, Fer 7, Vlaar 7, Maduro 6, Kuyt 6½ (72 Dingsdag 6), Van La Parra 6½, Castaignos 7, Leerdam 7, Biseswar 7 | | Juventus | 1 | 77 Afellay | | Half-time: | 0-0 | | Referee: | Emerisic 6½ | | Attendance: | 27,879 | | Possession: | 42%-58% | | Total shots: | 14-16 | | MoM: | Banega |
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| | (4-3-3): Adler 7½, Corluka 8, De Ceglie 6½ (78 Torosidis 6), Felipe Melo 7½, Bassong 6½, Palombo 6, Camoranesi 7½, Afellay 7½, Sigþórsson 6½, Berg 5½, Nenê 6½ | | Atlético Madrid | 0 |
| | 6 Ismail | | (4-3-3): Sergio Asenjo 7½, Mario 7, Ismail 7, Banega 8½, Rodríguez 6½, Marc Muniesa 6½, Biglia 7½, Schaars 7½, Borja 7 (56 Reyes 6½), Perisic 6½, Rodrigo 6 | | Lorient | 1 | 12 Sagbo | | Half-time: | 1-3 | | Referee: | Cinciripini 5½ | | Attendance: | 15,798 | | Possession: | 52%-48% | | Total shots: | 12-11 | | MoM: | Mvuemba |
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| | (4-3-3): Sorin 5½, Congré 7, Morel 6½, Balmont 6, Kanté 7½, Puygrenier 6½, Pied 6, Birsa 7½, Hoarau 6½ (79 Jouffre 6), Mvuemba 7½, Sagbo 7 | | Flamengo | 3 | 13 Lima, 26 Alex Teixeira, 36p Lima | | 84 Artur | | (4-3-3): Artur 5, Leo Moura 6½, Siqueira 7½, Willians 7, Xandão 7 (60 Fabrício 7), Welinton 5½, Marlos 6½, Alex Teixeira 6½, Lima 7, Juan 6, Emerson 6 | | River Plate | 1 | 30 Castillejos | | Half-time: | 1-0 | | Referee: | Sandra 7 | | Attendance: | 53,470 | | Possession: | 49%-51% | | Total shots: | 13-11 | | MoM: | Ospina | | TV: | highlights |
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| | (4-3-3): Ospina 8, López 6½ (50 Díaz 6½), Rojo 7, Prediger 7½, Cabral 7, Orban 7, Formica 7, Buonanotte 6, López 7½, Castillejos 7, Mouche 5½ | | Napoli | 0 |
| | 21 Quagliarella, 80 Keita | | (4-3-3): Sepe 7, Campagnaro 7, Moretti 8, Gargano 7, Ranocchia 7, Cannavaro 6½, Necip 7, Keita 6½, Gignac 7, Pazienza 5½, Quagliarella 6 | | SV Werder Bremen | 2 | 4 Hunt, 20p Adebayor | | Half-time: | 2-1 | | Referee: | Collina 7½ | | Attendance: | 36,294 | | Possession: | 55%-45% | | Total shots: | 17-14 | | MoM: | Prödl | | TV: | highlights |
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| | (4-3-3): Gabulov 6, Uchida 6½, Perthel 7, Bargfrede 7½, Prödl 8, Santacroce 6½, Diego Capel 6, Hunt 6½, Adebayor 7, Wagner 6½, Dost 6½ | | Hamburger SV | 2 | 25 Rincón, 65 Guerrero |
| | (4-3-3): Karnezis 6, Demel 7, Jansen 7, Rincón 7, Mathijsen 7, Rozehnal 6, Ebert 6½, Elia 7, Guerrero 7, Pavlyuchenko 6, Petric 7 | | Sevilla | 1 | 9 Kiessling | | Half-time: | 1-1 | | Referee: | Coué 5½ | | Attendance: | 40,942 | | Possession: | 36%-64% | | Total shots: | 9-8 | | MoM: | Maicosuel |
| | 19 Fernández, 27 Fernández | | (4-3-3): Carrizo 6½, Alexis 8, Fernando Navarro 7½, Raul Meireles 7, Naldo 6½, Fernández 7, Navas 7, Luscombe 5½, Kiessling 7, Renato 6, Kiko 6 | | TSG Hoffenheim | 1 | 29 Ibisevic |
| | (4-3-3): Hildebrand 6½, Ebondo 8, Luna 7½, Maicosuel 8, Ruíz 8, Amat 6, Owomoyela 7½, Salihovic 6½, Ibisevic 7, Ba 6, Sessègnon 5½ | | West Ham United | 0 |
| | Half-time: | 0-0 | | Referee: | González 8 | | Attendance: | 34,379 | | Possession: | 51%-49% | | Total shots: | 8-12 | | MoM: | Upson |
| | 28 Johnson, 41 Parker | | (4-3-3): Green 7½, Eastmond 7, Baines 7, Gerrard 7 (66 Upson 8½), Samba 6½, Mancienne 6½, Jenas 7, Johnson 7, Bent 6½, Parker 6, Sellin 6 | | VfB Stuttgart | 0 |
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| | (4-3-3): Ulreich 7, Hamit 6, Boka 6½, Aquilani 7½, Niedermeier 7, Osorio 6, Kuzmanovic 6½, Gebhart 6½, Schieber 6½, Kehl 6, Cacau 5½ | | Round 3 | | Baník Ostrava | 5 | 15 Di Natale, 36 Kuba, 63 Di Natale, 70og Gargano, 81 Di Natale | | Half-time: | 2-0 | | Referee: | Brito Arceo 6 | | Attendance: | 17,330 | | Possession: | 50%-50% | | Total shots: | 20-9 | | MoM: | Arda |
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| | (3-4-3): Courtois 6½, Di Natale 7½, Filipe Luis 7, N'Koulou 7, Busquets 7, Barzagli 7, Kuba 6½, Hubocan 6½, Arda 7½, Giroud 7, Totti 6 | | Napoli | 1 | 57 Pazienza | | 7 Quagliarella, 59 Sepe, 68 Ranocchia | | (4-3-3): Sepe 6½, Campagnaro 7, Moretti 7, Gargano 7, Ranocchia 7, Cannavaro 6½, Necip 6½, Cigarini 6, Gignac 7, Pazienza 5½, Quagliarella 6½ |
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