| League Cup results | | Round 2 | | Sunderland | 4-0 | QPR | | 01 | Díaz |
| | | | 91 | Messi |
| | | | 42 | Díaz |
| | | | 392 | Díaz |
| | | | Millwall | 1-0 | Preston North End | | 32 | Ekitiké |
| | | | Sheffield Weds. | 0-3 | Arsenal | | |
| 31 | Martinelli | | |
| 441 | Martinelli | | |
| 272 | Saka | | Manchester United | 2-0 | Barnet | | 311 | Yéremy Pino |
| | | | 82 | Vinícius Júnior |
| | | | Burnley | 3-2 | Burton Albion | | 331(p) | Wood |
| 311 | Eze | | 192 | McNeil |
| 332 | Eze | | 24 | Wood |
| | | | Leyton Orient | 1-2 | Southend United | | 11 | Massimo |
| 191 | Dilrosun | | |
| 52 | Dilrosun | | Accrington Stan. | 1-2 | Middlesbrough | | 101 | Jonathan Viera |
| 241 | Reus | | |
| 381 | Reus | | Portsmouth | 2-1 | Torquay United | | 101 | Zeegelaar |
| 431 | Thiago | | 82 | Ferguson |
| | | | Fulham | 3-2 | Everton | | 292 | Williams |
| 151 | Digne | | 342 | ÓSkarsson |
| 452(og) | Williams | | 442 | Williams |
| | | | Nottingham Forest | 6-1 | Stevenage | | 51 | Johnson |
| 392(og) | Bruno Guimarães | | 151 | Romagnoli |
| | | | 171 | ÁLvarez |
| | | | 281 | Johnson |
| | | | 441 | Romagnoli |
| | | | 432 | ÁLvarez |
| | | | Stoke City | 1-2 | Hull City | | 121 | Cissé |
| 81 | Dogukan | | |
| 22 | Estupiñán | | Fleetwood Town | 4-2 | Peterborough Utd | | 31 | Hwang |
| 71 | Van Hecke | | 92 | Hwang |
| 391 | Toney | | 123 | ÁLex Moreno |
| | | | 74 | Hwang |
| | | | Brentford | 4-1 | Wolves | | 191 | Canós |
| 441 | Podence | | 331 | Wan-Bissaka |
| | | | 122 | Kalajdzic |
| | | | 252 | Wan-Bissaka |
| | | | Swindon Town | 1-2 | Watford | | 132 | Ayoze |
| 121 | Aubameyang | | |
| 371 | Marc Cucurella | | Cheltenham Town | 2-4 | MK Dons | | 251 | Heynen |
| 101 | James | | 152 | Joelinton |
| 311 | Krmencik | | |
| 401 | James | | |
| 212 | Penney | | Reading | 1-0 | Carlisle United | | 402 | Hendrick |
| | | | Rotherham United | 1-2 | Chelsea | | 331 | Kluivert |
| 271 | Lenglet | | |
| 222 | Isco | | Tottenham Hotspur | 4-4 | Barnsley | | 72 | Rafael Leão |
| 01 | Vidal | | 292 | Saliba |
| 191 | Semedo | | 432 | De Paul |
| 402 | Osayi-Samuel | | 83 | Kulusevski |
| 144 | Brandt | | |
| 52 |  Woodrow | | Scunthorpe United | 2-1 | Southampton | | 152 | Samir |
| 222 | Ballo | | 73 | Politano |
| | | | West Ham United | 2-0 | Port Vale | | 113 | Pablo Fornals |
| | | | 153 | Masuaku |
| 462 | Sinkgraven | | Bournemouth | 2-2 | Plymouth Argyle | | 332 | Käit |
| 41 | Awoniyi | | 402 | Solanke |
| 171 | Meyer | | Huddersfield Town | 3-0 | Brighton & HA | | 41 | Mounié |
| | | | 291 | Germain |
| | | | 292 | Bittencourt |
| | | | Liverpool | 2-0 | Leicester City | | 321(p) | Dolberg |
| | | | 381 | Alaba |
| | | | Bury | 4-0 | Aldershot Town | | 41 | Sané |
| | | | 91 | Gakpo |
| | | | 151 | Gakpo |
| | | | 62 | Gakpo |
| | | | Coventry City | 0-0 | Aston Villa | | Birmingham City | 1-0 | Ipswich Town | | 411 | Hinshelwood |
| | | | Leeds United | 2-3 | Bolton Wanderers | | 81 | Gnonto |
| 31 | Bowen | | 441 | Rodrigo |
| 32 | Martínez | | |
| 312 | Bowen | | Oldham Athletic | 1-0 | Charlton Athletic | | 64 | João Pedro |
| | | | Shrewsbury Town | 2-1 | Notts County | | 431(og) | Woolfenden |
| 461(p) | Beto | | 122 | Terrier |
| | | | Newcastle United | 1-2 | Colchester United | | 141 | Rots |
| 181 | Smith Rowe | | |
| 202 | Kostoulas | | Crystal Palace | 1-2 | Manchester City | | 251 | Doucouré |
| 171 | Fabián | | |
| 152 | André Silva | | WBA | 0-1 | Sheffield United | | |
| 182 | McBurnie |
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