| League Cup results | | Round 2 | | Bolton Wanderers | 2-1 | Scunthorpe United | | 61 | Kachunga |
| 11 | Elanga | | 241 | Samu Castillejo |
| | | | Brighton & HA | 3-0 | Leicester City | | 351 | Miguel |
| | | | 122(og) | Camavinga |
| | | | 352 | Wan-Bissaka |
| | | | QPR | 1-3 | Salford City | | 391 | Vázquez |
| 21 | Henry | | |
| 191 | Kessié | | |
| 332 | Henry | | Luton Town | 4-0 | Nottingham Forest | | 271 | Doku |
| | | | 341 | Mikel |
| | | | 451 | Mikel |
| | | | 42 | Mikel |
| | | | Southend United | 2-3 | Portsmouth | | 221 | Kramaric |
| 42 | Gordon | | 72 | Akliouche |
| 292 | Raphinha | | |
| 432 | Thuram | | Chelsea | 3-2 | Leeds United | | 301 | Joăo Pedro |
| 351 | Messi | | 52 | Joăo Pedro |
| 142 | Messi | | 92 | Kolo-Muani |
| | | | Arsenal | 2-1 | Wrexham | | 41 | Führich |
| 52 | Diogo Dalot | | 361(p) | Obi |
| 422 |  Diogo Dalot | | Gillingham | 1-2 | AFC Wimbledon | | 241 | Gündogan |
| 52 | McGregor | | |
| 402 | Osimhen | | Yeovil Town | 3-2 | Swansea City | | 91 | Zaroury |
| 221 | Mundle | | 181 | Dobbin |
| 142 | Mundle | | 34 | Anthony |
| | | | Bradford City | 2-1 | Oxford United | | 71 | Kean |
| 241 | Vardy | | 132 | Modric |
| | | | Ipswich Town | 1-2 | Grimsby Town | | 192 | Matheus Gonçalves |
| 71 | Gueye | | |
| 43 | Gueye | | Burnley | 2-4 | Wycombe Wanderers | | 181 | Hackney |
| 141 | Solanke | | 242 | Hackney |
| 261 | Mayulu | | |
| 212 | Solanke | | |
| 322 | Mayulu | | Preston North End | 3-0 | York City | | 51 | Wood |
| | | | 131 | Gonçalo Guedes |
| | | | 261 | Gonçalo Guedes |
| | | | Coventry City | 2-3 | Southampton | | 22 | Hernández |
| 141 | Reus | | 132(p) | Kalajdzic |
| 281 | Enes | | |
| 114 | Wijnaldum | | Notts County | 0-2 | Barnsley | | |
| 62 | O'Reilly | | |
| 112 | Suárez | | Torquay United | 2-2 | Bristol City | | 271 | Sancho |
| 381 | Rutter | | 282 | Stiller |
| 342(p) | Rutter | | 54 | Driussi |
| | | | Everton | 2-2 | MK Dons | | 241 | Gbamin |
| 11 | Estupińán | | 322(p) | Cenk |
| 271 | Clarke | | 103 | Whatmough |
| | | | Manchester United | 1-1 | Manchester City | | 12(p) | Lacazette |
| 312 | Pedro Neto | | Norwich City | 6-0 | Fulham | | 131 | Barella |
| | | | 351 | Barella |
| | | | 391 | Mateta |
| | | | 122 | Yildiz |
| | | | 302 | Yildiz |
| | | | 412 | Demirovic |
| | | | Lincoln City | 1-2 | Derby County | | 12 | Welbeck |
| 201 | Martínez | | |
| 122 | Martínez | | Tottenham Hotspur | 1-2 | Bristol Rovers | | 62 | Cherki |
| 242 | Leahy | | |
| 402 | Kanga | | Sunderland | 0-3 | Liverpool | | |
| 221 | Mac Allister | | |
| 351 | Mac Allister | | |
| 362 | Salah | | WBA | 1-0 | Middlesbrough | | 11 | Sugawara |
| | | | Aston Villa | 3-1 | Bournemouth | | 41 | Bamford |
| 51 | Füllkrug | | 162 | Pellegrini |
| | | | 342(og) | Ampadu |
| | | | Exeter City | 2-3 | Wealdstone | | 171 | Sarr |
| 12 | Smith Rowe | | 181 | Sarr |
| 332 | Watkins | | |
| 34 | Martinelli | | Port Vale | 1-2 | Wolves | | 302 | Sykes |
| 172 | Podence | | |
| 83 | Podence | | Chester | 1-3 | Newcastle United | | 92 | Calleri |
| 291 | Simons | | |
| 252 | Bowen | | |
| 322 | Joelinton | | Cardiff City | 0-3 | Brentford | | |
| 211 | Kulusevski | | |
| 372 | Broja | | |
| 412 | Son | | Rotherham United | 4-1 | Tranmere Rovers | | 21(og) | Meunier |
| 162 | Dilrosun | | 102 | Digne |
| | | | 302 | Cassierra |
| | | | 362 | Hudson-Odoi |
| | | | Reading | 2-0 | Crystal Palace | | 141 | Politano |
| | | | 351 | Politano |
| | | | Sutton United | 2-3 | Oldham Athletic | | 301 | Kalulu |
| 221 | Ayoze | | 62 | Godo |
| 381 | Ayoze | | |
| 162 | Kluivert | | Huddersfield Town | 2-1 | Blackburn Rovers | | 201 | Lolley |
| 21 | Maitland-Niles | | 332 | Rudoni |
| 42 | Phillips |
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