| League Cup results | | Round 2 | | Manchester City | 4-1 | MK Dons | | 21 | Vinícius Júnior |
| 272 | Hugo Duro | | 201 | Pedri |
| | | | 431 | Vinícius Júnior |
| | | | 92 | Vinícius Júnior |
| | | | Gillingham | 2-1 | Southend United | | 11 | El Ouazzani |
| 362 | Adli | | 121 | El Ouazzani |
| | | | Everton | 0-1 | Wycombe Wanderers | | |
| 261 | Isak | | Manchester United | 1-2 | Colchester United | | 152 | Vlahovic |
| 41 | Igor Paixâo | | |
| 351 | Igor Paixâo | | Port Vale | 3-1 | Salford City | | 21 | Welbeck |
| 81 | Musa | | 331 | Gallagher |
| | | | 282 | Welbeck |
| | | | Swindon Town | 3-2 | Oldham Athletic | | 301 | Kovacic |
| 112 | Ajorque | | 431 | Kovacic |
| 402 | Suárez | | 63 | Damsgaard |
| | | | 144 |  Demirovic |
| | | | Tottenham Hotspur | 2-1 | Rotherham United | | 71 | Robertson |
| 211 | Yamal | | 62 | Kvaratskhelia |
| | | | WBA | 1-1 | Bolton Wanderers | | 342 | Burkardt |
| 242 | Núńez | | Leicester City | 4-1 | Fulham | | 101 | Watkins |
| 101 | Maeda | | 161 | Martínez |
| | | | 181 | Martínez |
| | | | 332 | Martínez |
| | | | Liverpool | 2-1 | Crewe Alexandra | | 31 | Thiago |
| 421 | Nketiah | | 262 | Rogers |
| | | | Charlton Athletic | 2-1 | Morecambe | | 81 | Mitrovic |
| 281 | Guruzeta | | 191(p) | De Jong |
| | | | Brighton & HA | 1-2 | Chelsea | | 351 | Kleindienst |
| 11 | Dembélé | | |
| 33(p) | Havertz | | Southampton | 2-1 | Sheffield Weds. | | 51 | Trincăo |
| 282(og) | Aitor Paredes | | 422 | Trincăo |
| | | | Forest Green | 2-1 | Crystal Palace | | 211 | Thuram |
| 291 | Otavio | | 202 | Dovbyk |
| 192 | Thiago Silva | | Newport County | 3-0 | Millwall | | 251 | Diego Rico |
| | | | 371 | Arnau Martínez |
| | | | 22 | Giroud |
| | | | West Ham United | 3-1 | Aston Villa | | 191 | Osimhen |
| 302 | Griezmann | | 182 | Upamecano |
| | | | 332 | Simons |
| | | | Cardiff City | 1-0 | Bournemouth | | 132 | Dybala |
| | | | Bristol City | 3-1 | Stoke City | | 281(og) | Glushenkov |
| 232 | Philippe Coutinho | | 252 | Immobile |
| | | | 292 | Immobile |
| | | | Portsmouth | 0-2 | Middlesbrough | | |
| 371(og) | Diogo Leite | | |
| 82 | Evanilson | | Huddersfield Town | 2-2 | Newcastle United | | 222 | ÁVila |
| 01 | Savinho | | 442 | Neymar |
| 92 | Brobbey | | Exeter City | 2-1 | Wigan Athletic | | 41(og) | Niakhaté |
| 32 | ÁLex Berenguer | | 114 | Souttar |
| | | | Arsenal | 3-2 | Preston North End | | 51 | Lewandowski |
| 381 | Belotti | | 112 | Lewandowski |
| 02 | Belotti | | 462 | Lewandowski |
| | | | Cambridge United | 2-2 | Wolves | | 151 | Sarr |
| 81 | Wahi | | 72 | Sarr |
| 422 | Elanga | | Birmingham City | 2-2 | Lincoln City | | 101 | Onana |
| 422 | Harrison | | 123 | Lázaro |
| 04 | Broja | | Brentford | 1-2 | Reading | | 71 | Ayoze |
| 81 | Guđmundsson | | |
| 141 | Lukaku | | Sunderland | 2-1 | Barnsley | | 171 | Beltrán |
| 442 | Ikoné | | 251 | Beltrán |
| | | | Wrexham | 0-2 | Leyton Orient | | |
| 12 | Arokodare | | |
| 352 | Arokodare | | Alfreton Town | 0-2 | Plymouth Argyle | | |
| 202 | Rothe | | 142 | Edmundson |
| 392 | Rothe | | Nottingham Forest | 2-1 | Watford | | 222 | Sřrloth |
| 241 | Alex Telles | | 292 | Gakpo |
| | | | Blackpool | 1-1 | Walsall | | 103 | Grealish |
| 74 | Kostic | | 54 | Gonçalo Ramos |
| | | | Oxford United | 1-0 | Sheffield United | | 151 | Diego |
| | | | Leeds United | 1-1 | Crawley Town | | 31 | Nkunku |
| 411 | Bakwa |
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